Patents by Inventor Charles L. Sims

Charles L. Sims has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9938400
    Abstract: Thermoplastic polyolefins (TPOs) and/or thermoplastic vulcanizates (TPVs) are blended with low molecular weight propylene-dominated copolymers to provide polymeric compositions with an improved balance between processability and toughness. The compositions have improved processability by facilitating the ease with which a TPO or TPV, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into articles.
    Type: Grant
    Filed: April 23, 2008
    Date of Patent: April 10, 2018
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Abdelhadi Sahnoune, Sudhin Datta, Mun Fu Tse, Charles L. Sims, James N. Coffey, Peijun Jiang
  • Patent number: 9096747
    Abstract: Low molecular weight semicrystalline propylene-alpha olefin copolymers containing propylene crystallinity are used as a nucleating agent in crystalline polypropylene and polypropylene copolymers. The nucleating copolymers are propylene-alpha olefin copolymers having a percent crystallinity of 5-75%, a melting point of 45° C.-105° C., and an MFR between 300 and 5000 g/10 min. Nucleated polypropylene compositions comprise a nucleating amount of the copolymer blended in a matrix of polypropylene homopolymer, or 0.01 to 9 wt % ?-olefin copolymer, having a melting point greater than 110° C. The nucleating copolymer improves processing time with little or no effect on the crystallinity-associated characteristics of the matrix. The invention also provides methods of crystallizing polypropylene with the nucleating agent and of forming articles with the composition, and also provides articles formed from the composition and/or by the method.
    Type: Grant
    Filed: January 11, 2008
    Date of Patent: August 4, 2015
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Derek Thurman, Sudhin Datta, Wen Li, Charles L. Sims
  • Patent number: 8653169
    Abstract: Disclosed herein are adhesives comprising a copolymer comprising at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C10 alpha-olefin. The copolymer has a molecular weight of less than 100,000 and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer preferably exhibits at least 50% fiber tear at ?18° C. and at least 50% fiber tear at +25° C. using Inland paper board as a substrate; a viscosity of less than 50,000 mPa sec at 190° C., a set time of less than 4 seconds and a toughness of at least 3.4 megajoule/m3.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: February 18, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Patrick Brant, Chad E. Bernard, David R. Johnsrud, Charles L. Sims
  • Patent number: 8618219
    Abstract: Disclosed herein is an in-reactor produced multi-component copolymer comprises a semi-crystalline component having a crystallinity of 20% or more, and an amorphous component having a crystallinity of 5% or less. The copolymer comprises at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C12 alpha-olefin. The copolymer has a viscosity at 190° C. of at least 530 mPa sec and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer exhibits a good balance of adhesive properties and mechanical strength.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: December 31, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Patrick Brant, David Aaron Henning, David R. Johnsrud, Charles L. Sims
  • Patent number: 8431643
    Abstract: The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and/or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time. Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 mol % polypropylene, at least one wax and at least one wax modifier.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: April 30, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: George Rodriguez, Fran A. Shipley, Peijun Jiang, Charles L. Sims, Kenneth Lewtas
  • Patent number: 8263707
    Abstract: The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Grant
    Filed: April 3, 2008
    Date of Patent: September 11, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Charles L. Sims, Peijun Jiang, Abdelhadi Sahnoune, Derek W. Thurman
  • Patent number: 8052822
    Abstract: Styrenic block copolymers are blended with propylene copolymers to provide polymeric compositions with an improved balance between processability and elasticity. The compositions have improved processability by facilitating the ease with which a rubbery material, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into films or other articles, assisted by a desired level of melt elasticity, i.e., a high elastic extension and recovery.
    Type: Grant
    Filed: February 15, 2008
    Date of Patent: November 8, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Mun Fu Tse, Abdelhadi Sahnoune, Charles L. Sims, James N. Coffey
  • Patent number: 7906588
    Abstract: Provided are heterogeneous blend compositions comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230 C) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Grant
    Filed: October 6, 2008
    Date of Patent: March 15, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Charles L. Sims, James Norris Coffey
  • Patent number: 7858701
    Abstract: The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Grant
    Filed: April 3, 2008
    Date of Patent: December 28, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Charles L. Sims, Peijun Jiang, Abdelhadi Sahnoune, Derek W. Thurman
  • Publication number: 20100305259
    Abstract: The packaging industry desires adhesive compositions having a fast set time, such as those setting in less than five seconds from a molten state at conventional packaging operating temperatures to a solid or quasi solid having favorable Dot T-Peel, set time, and/or fiber tear adhesion properties. Polymer based adhesives performing within this window are a favorable alternative to conventional formulated adhesives. The provided adhesive compositions exhibit a favorable balance of properties such as high adhesive strength, wide temperature operating window, and fast set time. Provided are adhesive compositions composed of a polyolefin composition comprising at least about 50 mol % polypropylene, at least one wax and at least one wax modifier.
    Type: Application
    Filed: April 16, 2010
    Publication date: December 2, 2010
    Inventors: George Rodriguez, Fran A. Shipley, Peijun Jiang, Charles L. Sims, Kenneth Lewtas
  • Publication number: 20100179268
    Abstract: Disclosed herein are adhesives comprising a copolymer comprising at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C10 alpha-olefin. The copolymer has a molecular weight of less than 100,000 and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer preferably exhibits at least 50% fiber tear at ?18° C. and at least 50% fiber tear at +25° C. using Inland paper board as a substrate; a viscosity of less than 50,000 mPa sec at 190° C., a set time of less than 4 seconds and a toughness of at least 3.4 megajoule/m3.
    Type: Application
    Filed: September 29, 2006
    Publication date: July 15, 2010
    Inventors: Peijun Jiang, Patrick Brant, Chad E. Bernard, David R. Johnsrud, Charles L. Sims
  • Publication number: 20100029851
    Abstract: Disclosed herein is an in-reactor produced multi-component copolymer comprises a semi-crystalline component having a crystallinity of 20% or more, and an amorphous component having a crystallinity of 5% or less. The copolymer comprises at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C12 alpha-olefin. The copolymer has a viscosity at 190° C. of at least 530 mPa sec and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer exhibits a good balance of adhesive properties and mechanical strength.
    Type: Application
    Filed: September 29, 2006
    Publication date: February 4, 2010
    Inventors: Peijun Jiang, Patrick Brant, David Aaron Henning, David R. Johnsrud, Charles L. Sims
  • Publication number: 20100029829
    Abstract: Disclosed herein are adhesives comprising a copolymer comprising at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C10 alpha-olefin. The copolymer has a molecular weight of less than 100,000 and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer preferably exhibits at least 50% fiber tear at ?18° C. and at least 50% fiber tear at +25° C. using Inland paper board as a substrate; a viscosity of less than 50,000 mPa sec at 190° C., a set time of less than 4 seconds and a toughness of at least 3.4 megajoule/m3.
    Type: Application
    Filed: September 29, 2006
    Publication date: February 4, 2010
    Inventors: Peijun Jiang, Patrick Brant, Chad E. Bernard, David R. Johnsrud, Charles L. Sims
  • Publication number: 20090270545
    Abstract: Thermoplastic polyolefins (TPOs) and/or thermoplastic vulcanizates (TPVs) are blended with low molecular weight propylene-dominated copolymers to provide polymeric compositions with an improved balance between processability and toughness. The compositions have improved processability by facilitating the ease with which a TPO or TPV, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into articles.
    Type: Application
    Filed: April 23, 2008
    Publication date: October 29, 2009
    Inventors: Abdelhadi Sahnoune, Sudhin Datta, Mun Fu Tse, Charles L. Sims, James N. Coffey, Peijun Jiang
  • Publication number: 20090205776
    Abstract: Styrenic block copolymers are blended with propylene copolymers to provide polymeric compositions with an improved balance between processability and elasticity. The compositions have improved processability by facilitating the ease with which a rubbery material, usually difficult to melt process, can be processed at high line speeds, which in turn improves the formation of the composition into films or other articles, assisted by a desired level of melt elasticity, i.e., a high elastic extension and recovery.
    Type: Application
    Filed: February 15, 2008
    Publication date: August 20, 2009
    Inventors: Sudhun Datta, Mun Fu Tse, Abdelhadi Sahnoune, Charles L. Sims, James N. Coffey
  • Publication number: 20090111946
    Abstract: Provided are heterogeneous blend compositions comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230 C) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Application
    Filed: October 6, 2008
    Publication date: April 30, 2009
    Inventors: SUDHIN DATTA, CHARLES L. SIMS, JAMES NORRIS COFFEY
  • Publication number: 20090111945
    Abstract: Provided are homogeneous blend compositions comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230C) of the first polymer component is between 300 g/10 min to 5000 g/1 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Application
    Filed: October 6, 2008
    Publication date: April 30, 2009
    Inventors: Sudhin Datta, Charles L. Sims, James Norris Coffey
  • Publication number: 20080249231
    Abstract: The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Application
    Filed: April 3, 2008
    Publication date: October 9, 2008
    Inventors: Sudhin Datta, Charles L. Sims, Peijun Jiang, Abdelhadi Sahnoune, Derek W. Thurman
  • Publication number: 20080249248
    Abstract: Low molecular weight semicrystalline propylene-alpha olefin copolymers containing propylene crystallinity are used as a nucleating agent in crystalline polypropylene and polypropylene copolymers. The nucleating copolymers are propylene-alpha olefin copolymers having a percent crystallinity of 5-75%, a melting point of 45° C.-105° C., and an MFR between 300 and 5000 g/10 min. Nucleated polypropylene compositions comprise a nucleating amount of the copolymer blended in a matrix of polypropylene homopolymer, or 0.01 to 9 wt % ?-olefin copolymer, having a melting point greater than 110° C. The nucleating copolymer improves processing time with little or no effect on the crystallinity-associated characteristics of the matrix. The invention also provides methods of crystallizing polypropylene with the nucleating agent and of forming articles with the composition, and also provides articles formed from the composition and/or by the method.
    Type: Application
    Filed: January 11, 2008
    Publication date: October 9, 2008
    Inventors: Derek Thurman, Sudhin Datta, Wen Li, Charles L. Sims
  • Publication number: 20080249232
    Abstract: The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Application
    Filed: April 3, 2008
    Publication date: October 9, 2008
    Inventors: Sudhin Datta, Charles L. Sims, Peijun Jiang, Abdelhadi Sahnoune, Derek W. Thurman