Patents by Inventor Charles Raufast
Charles Raufast has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5545378Abstract: The present invention relates to a gas phase fluidized bed reactor (1) comprising an upright tubular portion (2) having a fluidization grid (4) in the lower part thereof. According to the invention the upright tubular portion (4) is provided with an external conduit (13) which connects a lower orifice (14) which is above the fluidization grid (4) and an upper orifice (15) which is a height above the lower orifice (14). The invention also relates to a gas phase polymerization process carried out in the reactor.Type: GrantFiled: April 4, 1995Date of Patent: August 13, 1996Assignee: BP Chemicals LimitedInventors: Frederic R. M. M. Morterol, Charles Raufast
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Patent number: 5534607Abstract: The present invention relates to a continuous process for the polymerization of an alpha-olefin having from 2 to 12 carbon atoms, which is carried out in a gas phase polymerization reactor by bringing a gaseous reaction mixture, containing the alpha-olefin to be polymerized, into contact with a catalyst system of the Ziegler-Natta type consisting of a solid catalyst comprising at least one compound of a transition metal belonging to groups IV, V or VI of the Periodic Table, of the elements, and of a cocatalyst comprising at least one organometallic compound of a metal belonging to groups II or III of the Periodic Table in which the polymerization reactor is fed with alpha-olefin at a constant rate.Type: GrantFiled: May 31, 1995Date of Patent: July 9, 1996Assignee: BP Chemicals LimitedInventors: Andre Martens, Frederic R. M. M. Morterol, Charles Raufast
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Patent number: 5434228Abstract: The present invention relates to a gas phase fluidized bed reactor (1) comprising an upright tubular portion (2) having a fluidization grid (4) in the lower part thereof. According to the invention the upright tubular portion (4) is provided with an external conduit (13) which connects a lower orifice (14) which is above the fluidization grid (4) and an upper orifice (15) which is a height above the lower orifice (14). The invention also relates to a gas phase polymerization process carried out in the reactor.Type: GrantFiled: July 16, 1993Date of Patent: July 18, 1995Assignee: BP Chemicals LimitedInventors: Frederic R. M. M. Morterol, Charles Raufast
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Patent number: 5241023Abstract: The present invention relates to a process and a device for polymerizing alpha-olefins such as ethylene or propylene in a gas phase. The device comprises a gas phase polymerization reactor (5) into which a suspension of prepolymer particles in liquid saturated hydrocarbon(s) is continuously introduced. The prepolymer suspension is prepared in one or more prepolymerization vessels (14) and is continuously passed to a post-treatment unit comprising a degassing means (10) wherein most of the dissolved unreacted olefinic monomer(s) is separated. Preferably, the post-treatment unit may comprise a particle separation means (11) for removing the finest and/or coarsest prepolymer particles from the suspension and/or a concentration means (11a) for concentrating the suspension.High activity catalyst can be used in the process with reduced amounts of prepolymer agglomerates. Prepolymer can be obtained with a constant quality and a desired size.Type: GrantFiled: March 4, 1991Date of Patent: August 31, 1993Assignee: BP Chemicals LimitedInventors: Daniel Brule, Jean-Marie Iffly, Charles Raufast
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Patent number: 5240683Abstract: The present invention relates to a process and a device for introducing a catalytically active powder into a reactor (20) for gas phase alpha-olefin polymerization. The device comprises a storage vessel (3) containing the powder, a metering valve (4) delivering metered quantities of the powder into an intermediate chamber (5) comprising at least one obstacle (6) separating an upper part (5a) of the chamber (5) comprising an auxiliary gas inlet (2a) from a lower part (5b) terminated by an outlet orifice (5c). A connecting pipe (18) connects the outlet orifice (5c) to a mixing device (8) situated on a conveying pipework (15) communicating with the reactor (20). The powder is introduced into the reactor in a dilute suspension form and in a more uniform rate.Type: GrantFiled: June 28, 1991Date of Patent: August 31, 1993Assignee: BP Chemicals LimitedInventors: Jean A. Maurel, Charles Raufast
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Patent number: 5213768Abstract: A fluidized bed apparatus (1) having a fluidization grid (2) below which is positioned a tuyere (5) for guiding fluidization gas to the fluidization grid (2). The tuyere (5) comprises a widening pipe the wider end (6) of which is positioned towards the fluidization grid (2) and has an area which is substantially the same as the cross-sectional area of the fluidized bed apparatus (1) and is 2 to 30 times that of the area of the narrower end (7) of the widening pipe. The process for feeding fluidization gas to a fluidized bed using such apparatus enables a good gas distribution across the bed to be achieved with a modest additional pressure drop. The invention is particularly useful for apparatus e.g. greater than 3 m in diameter.Type: GrantFiled: April 7, 1992Date of Patent: May 25, 1993Assignee: BP Chemicals Ltd.Inventors: Jean A. Maurel, Frederic R. M. M. Morterol, Charles Raufast
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Patent number: 5171541Abstract: Process for discharging solid particulate products present in a fluidized bed reactor in which the polymerization or copolymerization of alpha-olefins is carried out, in a system consisting of a vessel connected to the reactor by way of a pipe provided with a first valve and connected to a reservoir situated downstream by way of a pipe provided with a second valve, the said method being characterized in that:the two valves consist of continuously rotating plug, valves, these valves being moved in such a way that the two valves are not open at the same time, even partly, and the volume of the vessel comprises between 1/10 and 1/000, and preferably between 1/100 and 1/500 of the volume of fluidized solid contained in the reactor.Type: GrantFiled: May 14, 1991Date of Patent: December 15, 1992Assignee: BP Chemicals LimitedInventor: Charles Raufast
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Patent number: 5082634Abstract: The present invention relates to a fluidized bed apparatus comprising a fluidization grid arranged in the lower part of this apparatus, this grid being provided at its center with a circular aperture communicating with a discharge chamber and occurring in the form of a surface of revolution consisting of the joined lateral surfaces of at least two coaxial truncated cones of revolution, virtual vertices of which are oriented downwards.Type: GrantFiled: July 10, 1990Date of Patent: January 21, 1992Assignee: BP Chemicals LimitedInventor: Charles Raufast
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Patent number: 4921678Abstract: The invention relates to a process and a device for degassing and converting into pellets polyolefins from a gas-phase reactor.A device according to the invention comprises, in combination (FIG. 1):a reactor (1) for the catalytic polymerization in the gas phase of alpha-olefins, equipped with a polyolefin outlet (9);A device (12) for primary degassing by separation of the solid and gas phases, connected to the said outlet;A device for secondary degassing (14) to substantially free the particles of the gases accompanying them and which is connected to the outlet of the primary degassing (12) and which comprises a mechanical stirrer (14a) making it possible to raise the temperature of the particles to a temperature close to the minimum sintering temperature by conversion of the mechanical energy into heat;and a device (15) for pelleting the particles by extrusion through a die, this device being connected to the outlet of the said secondary degassing device.Type: GrantFiled: November 21, 1988Date of Patent: May 1, 1990Assignee: BP Chemicals LimitedInventor: Charles Raufast
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Patent number: 4902483Abstract: Apparatus for the production of polyolefins by the polymerization of alpha-olefins in the gas phase, in several stages, in at least two polymerization reactors interconnected by a transfer device making it possible to transfer the polyolefins resulting from the first reactor into the second reactor, in which the polymerization is continued under conditions identical to or different from those of the first reactor.Type: GrantFiled: July 2, 1987Date of Patent: February 20, 1990Assignee: BP Chemicals LimitedInventor: Charles Raufast
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Patent number: 4882400Abstract: Process for gas phase polymerization of olefins using a highly active catalyst in a fluidized bed reactor (1), comprising a recator body (2) partially occupied by the fluidized bed and surmounted by a disengagement chamber (3). The gas mixture withdrawn from the disengagement chamber (3) is fed to a dust separator (6) e.g. a clycone, to separate the fine particles entrained by the gas. The gas is cooled, compressed and recycled to the base of the reactor. The particles are withdrawn from the dust separator (6) by a mixing device (8) which mixes the particles with a carrier gas. The carrier gas and particles are recycled to the reactor where they are introduced into the reactor body (2) through an opening in the side wall thereof at a position above the fluidized bed, but below the disengagement chamber (3). The velocity of the particles introduced into the reactor is insufficient to cause them to be blown directly into the bed.Type: GrantFiled: July 27, 1988Date of Patent: November 21, 1989Assignee: BP Chemicals LimitedInventors: Andre Dumain, Charles Raufast
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Patent number: 4858144Abstract: A process for detecting anomalies in a fluidized bed, e.g. the incidence of agglomeration in gas-fluidized bed polymerization, comprises sensing and converting into electrical signals the pressure at one level, or the pressure difference between two or more levels in the reactor, processing these signals by computer to produce a pressure spectrum and comparing with a reference spectrum obtained in the absence of anomalies. The device comprises one or more pressure sensors 11,12,13, which measure the pressure at various levels in the reactor 1, and a computer 27.Type: GrantFiled: February 12, 1987Date of Patent: August 15, 1989Assignee: BP Chemicals LimitedInventors: Alain Marsaly, Andre Martens, Frederic R. M. M. Morterol, Charles Raufast
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Patent number: 4828145Abstract: The present invention relates to a rotary-type metering device making it possible to dispense granular substances consisting of fine particles which are difficult to handle. The metering device consists of a spherical core rotating around a horizontal axis inside a casing comprising a feed orifice and an outlet orifice. The spherical core comprises at least one cavity having an opening at the surface of the core, and sides and bottom within the core. This cavity has the shape of a volume consisting of two volumes of revolution, contiguous and coaxial, V.sub.1 and V.sub.2, with an axis perpendicular to the axis of rotation of the spherical core. The volume V.sub.1 is a truncated cone of revolution or a cylinder of revolution.Type: GrantFiled: June 8, 1988Date of Patent: May 9, 1989Assignee: BP Chemicals LimitedInventor: Charles Raufast
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Patent number: 4820463Abstract: The invention relates to a process for degassing and pelletizing polyolefin particles produced by a gas phase polymerization. The polyolefin particles are submitted to a primary degassing, preferably at the outlet of a reactor for catalytic polymerization in the gas phase. Then the polyolefin particles are subjected to a secondary degassing step comprising agitating the particles by a mechanical stirrer and converting the mechanical energy therefrom into heat such that the temperature of the particles is brought to between 80.degree. and 120.degree. C. which is close to minimum sintering temperature Ts so that the polyolefin particles are substantially freed from the gases accompanying them. The heated degassed polyolefin particles are then pelletized in an extruder of a pelleting unit.Type: GrantFiled: April 30, 1987Date of Patent: April 11, 1989Assignee: BP Chemicals LimitedInventor: Charles Raufast
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Process for introducing a powder with catalytic activity into a fluidized-bed polymerization reactor
Patent number: 4774299Abstract: Device and process for introducing a powder with catalytic activity into a fluidized bed polymerization reactor (1), the said device comprising:a storage enclosure (2) for powder with catalytic activity, provided with a feed line (3) for powder with catalytic activity and a shut-off valve (26), this enclosure being connected to a metering device (4) making it possible to deliver periodically a given volume of powder with catalytic activity,an intermediate chamber (5), placed below the metering device to receive direct the powder delivered by the latter, this intermediate chamber comprising in its upper part a tube (6) bringing in an inert carrier gas, provided with a shut-off valve,piping for conveying the powder (8) connecting the bottom part of the intermediate chamber to the fluidized-bed reactor, this piping having a portion which is more or less horizontal, the said powder conveying piping being provided with a full-bore rapid-opening valve (10).Type: GrantFiled: April 8, 1987Date of Patent: September 27, 1988Assignee: BP Chemicals LimitedInventors: Andre Dumain, Charles Raufast -
Patent number: 4703094Abstract: A process and apparatus as shown in FIG. 1 for the production of polyolefins by the polymerization of alpha-olefins in the gas phase, in several stages, in at least two polymerization reactors interconnected by a transfer device making it possible to transfer the polyolefins resulting from the first reactor into the second reactor, in which the polymerization is continued under conditions identical to or different from those of the first reactor.Type: GrantFiled: February 12, 1986Date of Patent: October 27, 1987Assignee: BP Chemicals LimitedInventor: Charles Raufast
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Patent number: 4687381Abstract: Device and process for introducing a powder with catalytic activity into a fluidized bed polymerization reactor (1), the said device comprising:a storage enclosure (2) for powder with catalytic activity, provided with a feed line (3) for powder with catalytic activity and a shut-off valve (26), this enclosure being connected to a metering device (4) making it possible to deliver periodically a given volume of powder with catalytic activity,an intermediate chamber (5), placed below the metering device to receive direct the powder delivered by the latter, this intermediate chamber comprising in its upper part a tube (6) bringing in a inert carrier gas, provided with a shut-off valve,piping for conveying the powder (8) connecting the bottom part of the intermediate chamber to the fluidized-bed reactor, this piping having a portion which is more or less horizontal, the said powder conveying piping being provided with a full-bore rapid-opening valve (10).Type: GrantFiled: March 26, 1985Date of Patent: August 18, 1987Assignee: BP Chemicals LimitedInventors: Andre Dumain, Charles Raufast
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Patent number: 4495337Abstract: The invention relates to a device and process permitting of the bottom drainage of a fluid-bed polymerization reactor (1) comprising a fluidization plate (2), a gas inlet (3) located between the said plate and the bottom of the reactor and a side pipe (4) located above the said plate and permitting of the evacuation of the fluidized particles, the said device consisting:of a vertical pipe (5) having a top opening at the level of the plate and a bottom end located outside and underneath the bottom of the reactor, which is occluded by a cock (6),and a gas intake tube (7) in the said vertical piping, leading out into the immediate vicinity of the said cock (6).Type: GrantFiled: February 24, 1983Date of Patent: January 22, 1985Assignee: BP Chimie Societe AnonymeInventor: Charles Raufast