Abstract: A method of fabricating an ultra-small semiconductor structure comprising the following steps. A substrate having a lower dielectric layer and an overlying upper dielectric layer formed thereover is provided. Using a lithography process having a lithography limit, the upper dielectric layer is patterned to form a first opening exposing a portion of the lower dielectric layer. The first opening having exposed side walls and a width equal to the lithography limit. Sidewall spacers having a lower width are formed over the exposed side walls of the first opening. Using the sidewall spacers as masks, the lower dielectric layer is patterned to form a lower opening having a width less than the first opening width. The patterned upper dielectric layer is removed. An ultra-small semiconductor structure is formed within the lower opening. The ultra-small semiconductor structure having a width equal to the lithography limit minus twice the lower width of the sidewall spacer.

Abstract: A process of fabricating high dielectric constant MIM capacitors. The high dielectric constant MIM capacitors are for both RF and analog circuit applications. For the high dielectric constant MIM capacitors, the metal is comprised of copper electrodes in a dual damascene process. The dielectric constant versus the total thickness of super lattices is controlled by the number of artificial layers. Dielectric constants near 900 can be achieved for 250 Angstrom thick super lattices. MBE, molecular beam epitaxy or ALCVD, atomic layer CVD techniques are employed for the layer growth processes.

Abstract: A method of forming small features, comprising the following steps. A substrate having a dielectric layer formed thereover is provided. A spacing layer is formed over the dielectric layer. The spacing layer has a thickness equal to the thickness of the small feature to be formed. A patterned, re-flowable masking layer is formed over the spacing layer. The masking layer having a first opening with a width “L”. The patterned, re-flowable masking layer is re-flowed to form a patterned, re-flowed masking layer having a re-flowed first opening with a lower width “1”. The re-flowed first opening lower width “1” being less than the pre-reflowed first opening width “L”. The spacing layer is etched down to the dielectric layer using the patterned, re-flowed masking layer as a mask to form a second opening within the etched spacing layer having a width equal to the re-flowed first opening lower width “1”. Removing the patterned, re-flowed masking layer.

Abstract: A method of fabricating a CMOS device with reduced processing costs as a result of a reduction in photolithographic masking procedures, has been developed. The method features formation of L shaped silicon oxide spacers on the sides of gate structures, with a vertical spacer component located on the sides of the gate structure, and with horizontal spacer components located on the surface of the semiconductor substrate with a thick horizontal spacer component located adjacent to the gate structures, while a thinner horizontal spacer component is located adjacent to the thicker horizontal spacer component.

Abstract: A method of fabricating first and second gates comprising the following steps. A substrate having a gate dielectric layer formed thereover is provided. The substrate having a first gate region and a second gate region. A thin first gate layer is formed over the gate dielectric layer. The thin first gate layer within the second gate region is masked to expose a portion of the thin first gate layer within the first gate region. The exposed portion of the thin first gate layer is converted to a thin third gate layer portion. A second gate layer is formed over the thin first and third gate layer portions. The second gate layer and the first and third gate layer portions are patterned to form a first gate within first gate region and a second gate within second gate region.

Abstract: A process of fabricating a CMOS device comprised with super-steep retrograde (SSR), twin well regions, has been developed. The process features the use of two, selective epitaxial growth (SEG), procedures, with the first SEG procedure resulting in the growth of bottom silicon shapes in the PMOS, as well as in the NMOS region of the CMOS device. After implantation of the ions needed for the twin well regions, into the bottom silicon shapes, a second SEG procedure is employed resulting in growth of top silicon shapes on the underlying, implanted bottom silicon shapes. An anneal procedure then distributes the implanted ions resulting in an SSR N well region in the composite silicon shape located in the PMOS region, and resulting in an SSR P well region in the composite silicon shape located in the NMOS region of the CMOS device.

Abstract: A process for forming a shallow trench isolation (STI), structure in a semiconductor substrate, featuring a group of insulator liner layers located on the surfaces of the shallow trench shape used to accommodate the STI structure, has been developed. After defining a shallow trench shape featuring rounded corners, a group of thin insulator liner layers, each comprised of either silicon oxide or silicon nitride, is deposited on the exposed surfaces of the shallow trench shape via atomic layer depositing (ALD), procedures. A high density plasma procedure is used for deposition of silicon oxide, filling the shallow trench shape which is lined with the group of thin insulator liner layers. The silicon nitride component of the insulator liner layers, prevents diffusion or segregation of P type dopants from an adjacent P well region to the silicon oxide of the STI structure.

Abstract: An improved and new process of fabricating high dielectric constant MIM capacitors. These high dielectric constant MIM capacitor met all of the stringent requirements needed for both for both RF and analog circuit applications. For the high dielectric constant MIM capacitor, the metal is comprised of copper electrodes in a dual damascene process. The dielectric constant versus the total thickness of super lattices is controlled by the number of layers either 4/4 , 2/2, and 1/1 artificial layers. Hence thickness of the film can be easily controlled. Enhancement of dielectric constant is because of interface. Dielectric constants near 900 can be easily achieved for 250 Angstrom thick super lattices.

Abstract: A method of fabricating a CMOS device with reduced processing costs as a result of a reduction in photolithographic masking procedures, has been developed. The method features formation of L shaped silicon oxide spacers on the sides of gate structures, with a vertical spacer component located on the sides of the gate structure, and with horizontal spacer components located on the surface of the semiconductor substrate with a thick horizontal spacer component located adjacent to the gate structures, while a thinner horizontal spacer component is located adjacent to the thicker horizontal spacer component.

Abstract: A method for forming a dual Si—Ge poly-gates having different Ge concentrations is described. An NMOS active area and a PMOS active area are provided on a semiconductor substrate separated by an isolation region. A gate oxide layer is grown overlying the semiconductor substrate in each of the active areas. A polycrystalline silicon-germanium (Si—Ge) layer is deposited overlying the gate oxide layer wherein the polycrystalline Si—Ge layer has a first Ge concentration. The NMOS active area is blocked while the PMOS active area is exposed. Successive cycles of Ge plasma doping and laser annealing into the PMOS active area are performed to achieve a second Ge concentration higher than the first Ge concentration.

Abstract: A method of forming a dielectric layer on a semiconductor substrate, comprised with multiple dielectric constants and multiple equivalent oxide thicknesses (EOT), has been developed. After formation of a high dielectric constant (high k), layer, on a semiconductor substrate, a first region of the high k layer is subjected to a process directed at incorporating elements into a top portion of the high k layer, while a second region of the high k layer remains protected during this procedure. An anneal treatment results in the processed high k layer now exhibiting a different dielectric constant, as well as a different EOT, than the unprocessed, second region of the high k layer, not exposed to the above procedures.

Abstract: A process for forming a shallow trench isolation (STI), structure in a semiconductor substrate, featuring a group of insulator liner layers located on the surfaces of the shallow trench shape used to accommodate the STI structure, has been developed. After defining a shallow trench shape featuring rounded corners, a group of thin insulator liner layers, each comprised of either silicon oxide or silicon nitride, is deposited on the exposed surfaces of the shallow trench shape via atomic layer depositing (ALD), procedures. A high density plasma procedure is used for deposition of silicon oxide, filling the shallow trench shape which is lined with the group of thin insulator liner layers. The silicon nitride component of the insulator liner layers, prevents diffusion or segregation of P type dopants from an adjacent P well region to the silicon oxide of the STI structure.

Abstract: A method of forming a silicon nitride-silicon dioxide, composite gate dielectric layer, offering reduced risk of boron penetration from an overlying boron doped polysilicon gate structure, has been developed. A porous, silicon rich silicon nitride layer is first deposited on a semiconductor substrate, allowing a subsequent thermal oxidation procedure to grow a thin silicon dioxide layer on the semiconductor substrate, underlying the porous, silicon rich silicon nitride layer. A two step anneal procedure is then employed with a first step performed in a nitrogen containing ambient to densify the porous, silicon rich silicon nitride layer, while a second step of the anneal procedure, performed in an inert ambient at a high temperature, reduces the foxed charge at the silicon dioxide-semiconductor interface.

Abstract: A process of fabricating a CMOS device comprised with super-steep retrograde (SSR), twin well regions, has been developed. The process features the use of two, selective epitaxial growth (SEG), procedures, with the first SEG procedure resulting in the growth of bottom silicon shapes in the PMOS, as well as in the NMOS region of the CMOS device. After implantation of the ions needed for the twin well regions, into the bottom silicon shapes, a second SEG procedure is employed resulting in growth of top silicon shapes on the underlying, implanted bottom silicon shapes. An anneal procedure then distributes the implanted ions resulting in an SSR N well region in the composite silicon shape located in the PMOS region, and resulting in an SSR P well region in the composite silicon shape located in the NMOS region of the CMOS device.

Abstract: A method for forming, on a semiconductor substrate, a dielectric layer having a variable thickness and composition. The dielectric layer so formed can be used to form electronic devices such as MOSFETS and CMOSFETS that require gate dielectrics of different thicknesses. On a silicon substrate in accord with the preferred embodiment, the method requires the formation of three regions, two with SiO2 layers of different thicknesses and a third region of substrate with no oxide. A final thin layer of high-k dielectric is formed covering the three regions, so that the region with no oxide has the thinnest dielectric layer of only high-k material and the other two regions have the high-k dielectric over SiO2 layers of different thickness. A final layer of gate electrode material can be formed and patterned to form the required device structure.

Abstract: A method of fabrication of L-shaped spacers in a semiconductor device. A gate structure is provided over a substrate. We form a first dielectric layer over the gate dielectric layer and the substrate. Next, a second dielectric layer is formed over the first dielectric layer. Then, we form a third dielectric layer over the second dielectric layer. The third dielectric layer is anisotropically etched to form a disposable spacer on the second dielectric layer. The second dielectric layer and the first dielectric layer are anisotropically etched using the disposable spacer as a mask to form a top and a bottom L-shaped spacer. The disposable spacer is removed. In preferred embodiments, the first, second and third dielectric layers are formed by atomic layer deposition (ALD) or ALCVD processes.

Abstract: A method for forming a single gate having a dual work-function is described. A gate electrode is formed overlying a gate dielectric layer on a substrate. Sidewalls of the gate electrode are selectively doped whereby the doped sidewalls have a first work-function and whereby a central portion of the gate electrode not doped has a second work-function to complete formation of a single gate having multiple work-functions in the fabrication of integrated circuits.

Abstract: A process for fabricating vertical CMOS devices, featuring variable channel lengths, has been developed. Channel region openings are defined in composite insulator stacks, with the channel length of specific devices determined by the thickness of the composite insulator stack. Selective removal of specific components of the composite insulator stack, in a specific region, allows the depth of the channel openings to be varied. A subsequent epitaxial silicon growth procedure fills the variable depth channel openings, providing the variable length, channel regions for the vertical CMOS devices.

Abstract: DPN (decoupled plasma nitridation) is used to improve robustness of ultra thin gate oxides. Conventionally, this is followed by an anneal in pure helium to remove structural defects in the oxide. However, annealing under these conditions has been found to cause a deterioration of the electrical performance of devices. This problem has been overcome by annealing, in a 1:4 oxygen-nitrogen mixture (1,050° C. at about 10 torr) instead of in helium or nitrogen oxide. This results in a gate oxide that is resistant to boron contamination without suffering any loss in its electrical properties.

Abstract: A method of structures having dual gate oxide thicknesses, comprising the following steps. A substrate having first and second pillars is provided. The first and second pillars each having an outer side wall and an inner side wall. At least one of the outer or inner side walls of at least one of the first and second pillars is/are masked leaving at least one of the outer or inner side walls of at least one of the first and second pillars exposed. Dopants are then implanted through the at least one of the exposed outer or inner side walls modifying the surface of the at least one of the doped exposed outer or inner side walls. The at least one of the masked outer or inner side walls of at least one of the first and second pillars is/are unmasked.