Abstract: A waveguiding media of polymeric materials is disclosed and claimed. In a preferred embodiment both core and cladding include X.sup.(2) materials poled to a non-centrosymmetric structure. Materials are selected so that the index difference between core and cladding remains relatively constant before and after poling so as to allow for efficient fabrication.

Abstract: In one embodiment this invention provides a thin film waveguide electrooptic light modulator which consists of (1) a laminated assembly of a waveguiding thin film of an organic polymer which exhibits second order nonlinear optical response, and upper and lower organic polymer blend cladding layers, each of which has a lower index of refraction between about 0.002-0.02 lower than the waveguiding thin film and which exhibits second order nonlinear optical response; and (2) electrodes which are positioned to apply an electric field to the laminated assembly.

Abstract: In one embodiment this invention provides a polarization-insensitive interferometric waveguide electrooptic modulator device. In a Mach-Zehnder type of waveguide geometry, one of the divergent optical paths has two sets of electrodes, which apply a horizontal electric field and a vertical electric field, respectively, to a nonlinear optically responsive polymeric medium in the optical path. The polymer medium section between each set of electrodes has a noncentrosymmetric molecular orientation parallel to the respective electric fields.