Abstract: A spiral spring intended to equip a balance of a horological movement, wherein the spiral spring is made of an alloy consisting of Nb, Ti and at least one element selected from Zr and Hf, optionally at least one element selected from W and Mo, possible traces of other elements selected from O, H, Ta, C, Fe, N, Ni, Si, Cu, Al, with the following weight percentages: a content of Nb comprised between 40 and 84%, a total content of Ti, Zr and Hf comprised between 16 and 55%, a content for W and Mo respectively comprised between 0 and 2.5%, a content for each of said elements selected from O, H, Ta, C, Fe, N, Ni, Si, Cu, Al comprised between 0 and 1600 ppm with the sum of said traces less than or equal to 0.3% by weight. The method for manufacturing the spiral spring is also disclosed.

Abstract: A spiral spring is configured to equip a balance of a horological movement. The spiral spring is made of an alloy consisting of: Nb, Ti and at least one element selected from V and Ta, optionally at least one element selected from Zr and Hf, optionally at least one element selected from W and Mo, possible traces of other elements selected from O, H, C, Fe, N, Ni, Si, Cu, Al, with the following weight percentages: a total content of Nb, V and Ta comprised between 40 and 85%, a total content of Ti, Zr and Hf comprised between 15 and 55%, a content for W and Mo respectively comprised between 0 and 2.5%, a content for each of the elements selected from 0, H, C, Fe, N, Ni, Si, Cu, Al between 0 and 1600 ppm with the sum of the traces less than or equal to 0.3% by weight.

Abstract: A zinc-free gold alloy containing by weight between 37% and 38.5% of gold, between 4 and 32% of palladium and/or silver, between 25% and 54% of copper and between 0% and 10% of gallium. A timepiece or piece of jewellery or gemstone jewellery made of this alloy.

Abstract: A mainspring includes a spiral metal strip and a hooking area formed in an inner face of an inner end of the strip, the hooking area including at least one shaped portion and at least one cavity in the inner face of the inner end.

Abstract: A method for manufacturing a balance spring intended to equip a balance of a horological movement, including a step of producing a blank made of a Nb—Zr alloy including between 10 and 30 wt % Zr, a step of annealing and cooling the blank, at least one step of deforming the annealed blank in order to form a wire, wherein, before the deformation step, a step of depositing, on the blank, a layer of a ductile material chosen from copper, nickel, cupronickel, cupro-manganese, gold, silver, nickel-phosphorus Ni—P and nickel-boron Ni—B, in order to facilitate the wire shaping operation, the thickness of the ductile material layer deposited being chosen such that the ratio of the area of ductile material to the area of the alloy for a given wire cross-section is less than 1, preferably less than 0.5, and more preferably lies in the range 0.01 to 0.4.

Abstract: A timepiece mainspring including, in the manufactured state, an eye and a portion formed of coils with an outer coil of radius R, the eye and the portion formed of coils being connected by a neck portion having substantially zero curvature, the timepiece mainspring wherein the neck portion has a length LC comprised between 1.5 and 10 times, and preferably between 2 and 8 times, the radius R. The mainspring having this specific geometry reduces the risk of premature breakage during use, typically for an application with a k factor lower than 10.

Abstract: A timepiece assembly including a first component and a second component assembled under stress, wherein at least one part of the surface of the assembly is coated with a protective layer intended to cover defects such as cracks or incipient cracks after assembly. It also relates to the method for manufacturing this assembly.

Abstract: A pivot arbor for a timepiece movement includes a pivot made of a first non-magnetic metal material at at least one end in order to limit the sensitivity to magnetic fields. An outer surface of the pivot is coated with a first layer of a second material such as Ni, NiB, and/or NiP. The first layer of the second material is partially coated with a second layer of a third material selected from gold, silver, copper, platinum, rhodium, palladium and their alloys.

Abstract: The invention concerns a method for heat treatment of an austenitic steel of the High Nitrogen Steel or austenitic HNS type, or of an austenitic steel of the High Interstitial Steel or austenitic HIS type, said austenitic HNS or austenitic HIS containing precipitates of nitrides, carbides or carbonitrides of chromium and/or of molybdenum, this method comprising the step which consists, after machining the austenitic HNS or austenitic HIS containing the precipitates, in redissolving the precipitates by bringing the austenitic HNS or austenitic HIS to its austenitizing temperature, then cooling the austenitic HNS or austenitic HIS sufficiently rapidly to avoid the re-formation of precipitates. The invention also concerns different heat treatment methods allowing chromium and/or molybdenum nitride, carbide or carbonitride type precipitates to appear in an austenitic HNS or austenitic HIS.

Abstract: A balance spring for a balance with a blank containing: niobium: the remainder to 100 wt %, titanium: between 40 and 60 wt %, traces of elements selected from the group formed of O, H, C, Fe, Ta, N, Ni, Si, Cu, Al, between 0 and 1600 ppm by weight individually, and less than 0.

Abstract: A non-magnetic watch component (1) comprising a substrate (4) made of a copper alloy, wherein at least one part of the substrate (4) has a surface layer (5) including CuxTiy intermetallics, and a method for manufacturing this watch component.

Abstract: The invention relates to a pivot arbor comprising a metal pivot (3) at each of its ends. The metal is a non-magnetic aluminium alloy in order to limit its sensitivity to magnetic fields, and at least the outer surface (5) of one of the two pivots (3) is deep-hardened to a predetermined depth with respect to the rest of the arbor to harden the pivot or pivots (3). The invention concerns the field of timepiece movements.

Abstract: The invention concerns a timepiece component containing a high-entropy alloy, the high-entropy alloy containing between 4 and 13 main alloying elements forming a single solid solution, the high-entropy alloy having a concentration of each main alloying element comprised between 1 and 55 at. %.

Abstract: The invention relates to a pivot arbor (1) for a timepiece movement comprising at least one pivot (3) made of a first non-magnetic metal material (4) at one of the ends thereof in order to limit the sensitivity thereof to magnetic fields. At least the outer surface of said pivot (3) is coated with a layer (5) of a second material selected from the group comprising Ni and NiP, and preferably chemical NiP. The invention concerns the field of timepiece movements.

Abstract: A micromechanical component for a timepiece movement including a metal body formed using a single material. The single material is of high-interstitial austenitic steel type including at least one non-metal as the interstitial atom in a proportion between 0.15% and 1.2% with respect to total mass of the material.

Abstract: A balance-spring intended to equip a balance of an horological movement, comprising a core made of Nb—Ti made from an alloy consisting of: niobium: balance to 100% by weight, titanium: between 5 and 95% by weight, traces of elements chosen from the group consisting of O, H, C, Fe, Ta, N, Ni, Si, Cu, Al, each of said elements being present in a quantity between 0 and 1600 ppm by weight, the total quantity formed by all of said elements being between 0% and 0.3% by weight, wherein the core made of Nb—Ti is coated with a layer of niobium, said layer of niobium having a thickness between 20 nm and 10 ?m.

Abstract: A flexible timepiece component, in particular for an oscillator mechanism or for a barrel of a horological movement, the component extending along a main plane (P) and including at least a part made of a composite material (1), the composite material (1) including a matrix (2) and a multitude of nanowires (3) distributed in the matrix (2), the nanowires (3) being juxtaposed, the matrix (2) including a material (4) for filling the interstices between the nanowires (3) to join them to each other, each nanowire (3) forming a solid one-piece tube, the nanowires (3) being disposed substantially parallel to an axis (A) substantially perpendicular to the main plane (P) of the component (6, 7).

Abstract: A rigid horological component (6, 7, 8) for an oscillator mechanism or for an escapement mechanism of a horological movement, the component extending along a principal plane (P) and including at least a part made of a composite material (1), the composite material (1) including a matrix (2) and a multitude of nanotubes or nanowires (3) distributed in the matrix (2), the nanotubes or nanowires (3) being juxtaposed and disposed substantially parallel with an axis (A) substantially perpendicular to the plane (P) of the component, the matrix (2) includes a rigid material (4) to fill the interstices and join the nanotubes or nanowires (3) to one another, the material (4) having rigid mechanical properties to block the elastic deformation of the component, the rigid material (4) comprised in the component having a Young's modulus greater than 2 GPa.

Abstract: A flexible horological component for an oscillator mechanism of a horological movement, the component extending along a principal plane (P) and including at least a part made of a composite material (1), the composite material (1) including a matrix (2) and a multitude of nanotubes or nanowires (3) distributed in the matrix (2), the nanotubes or nanowires (3) being juxtaposed and disposed substantially parallel with an axis (A) substantially perpendicular to the plane (P) of the component, the matrix including a flexible filling material (4) to fill the interstices between the nanotubes or nanowires (3), the filling material (4) comprising at least in part a thermal compensation material wherein the thermoelastic coefficient (TEC) is of the opposite sign to that of the other materials of the composite material (1).

Abstract: The invention concerns a timepiece component containing a high-entropy alloy, the high-entropy alloy containing between 4 and 13 main alloying elements forming a single solid solution, the high-entropy alloy having a concentration of each main alloying element comprised between 1 and 55 at. %.