Patents by Inventor Christian Schade

Christian Schade has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6146707
    Abstract: An aqueous coating composition which comprises as one binder component an aqueous polymer dispersion comprisingi) an acrylate polymer based on from 30 to 60% by weight of C.sub.1 -C.sub.8 -alkyl (meth)acrylate monomers, from 30 to 60% by weight of vinylaromatic monomers and from 0.5 to 10% by weight of (meth)acrylic acid,(ii) a nonassociative rheology stabilizer comprising an acrylate copolymer based on C.sub.1 -C.sub.6 -alkyl (meth)acrylate and (meth)acrylic acid, and(iii) as crosslinker, tris(alkoxycarbonylamino)-triazine or a mixture of tris(alkoxycarbonylamino)-triazines.
    Type: Grant
    Filed: September 27, 1999
    Date of Patent: November 14, 2000
    Assignee: BASF Coatings AG
    Inventors: Eckchard Sapper, Christian Schade, Kurt Wendel, Hubert Baumgart
  • Patent number: 6132705
    Abstract: A cosmetic or pharmaceutical composition which comprises at least one polymer or copolymer which is obtainable by free-radical emulsion or suspension polymerization in the presence of at least one chain-transfer reagent, has a glass transition temperature above -35.degree. C. and a content of organic volatile constituents .ltoreq.0.5% by weight, and is at least 20% by weight composed of a (meth)acrylic ester.
    Type: Grant
    Filed: June 26, 1997
    Date of Patent: October 17, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Schehlmann, Christian Schade, Axel Sanner, Karin Sperling, Hans-Ulrich Wekel
  • Patent number: 6025317
    Abstract: Porous polymers which are in powder form and contain N-vinylimidazole units and which are obtainable by free-radical precipitation polymerization ofa) 5-100% by weight of at least one N-vinylimidazole of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and are H, C.sub.1 -C.sub.4 -alkyl, N-vinylaxazolidone, N-vinyltriazole, 4-vinylpyridine N-oxide or mixtures of said monomers,b) 0-95% by weight of other copolymerizable monoethylenically unsaturated monomers andc) 0-50% by weight of at least one monomer with at least two non-conjugated ethylenic double bonds in aqueous solution which contains 0.5-30% by weight of at least one electrolyte and, based on the monomers employed, 0.5-80% by weight of at least one surfactant, a process of the preparation thereof, and the use of the porous polymers.
    Type: Grant
    Filed: March 3, 1998
    Date of Patent: February 15, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Stein, Dieter Boeckh, Christian Schade, Gerhard Rossler
  • Patent number: 6015551
    Abstract: The disclosure relates to a copolymer obtainable by radically initiated polymerization of the following: A) 70-99.9 wt. % an olefinically unsaturated C.sub.3 -C.sub.5 monocarboxylic acid, an olefinically unsaturated C.sub.4 -C.sub.8 dicarboxylic acid or its anhydride, or a mixture of such carboxylic acids; with B) 0.1-30 wt. % one or more multiply olefinically unsaturated carboxylic acid derivatives of formula (I)Z--Y--(CHR.sup.3 --CH.sub.2 --X).sub.n --R.sup.4 (I)in which Z is a vinyl or allyl group or structure (a), ##STR1## R.sup.1, R.sup.2 are hydrogen or methyl, R.sup.3 is hydrogen, methyl or ethyl, R.sup.4 is a singly or multiply olefinically unsaturated alkenyl or cycloalkenyl group or a singly or doubly olefinically unsaturated arylalkylene group, X is oxygen or NH, Y is oxygen, NH or N-alkyl, n is a number between 0 and 50; and C) 0-29.9 wt. % other copolymerizable monomers. The proposed copolymer can be used as a thickener or dispergent for aqueous systems.
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: January 18, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Schade, Hans-Ulrich Wekel, Axel Sanner, Karin Sperling
  • Patent number: 5962613
    Abstract: Water-soluble copolymers which are obtainable by free-radical solution polymerization ofa) 10-99.5% by weight of at least one vinylimidazole of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and are H, C.sub.1 -C.sub.4 -alkyl, monomers of the formula ##STR2## where R.sup.4 and R.sup.5 are identical or different and are H, C.sub.1 -C.sub.4 -alkyl or together form a ring of 3 to 5 methylene groups,N-vinyloxazolidone, N-vinyltriazole, 4-vinylpyridine N-oxide or mixtures of said monomers,b) 0-89.5% by weight of other copolymerizable monoethylenically unsaturated monomers andc) 0.5-30% by weight of at least one monomer which acts as crosslinker and has at least two non-conjugated ethylenic double bondsin water and/or polar organic solvents in the presence of polymerization regulators, using from 0.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: October 5, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Schade, Jurgen Detering, Stefan Stein, Dieter Boeckh, Hans-Ulrich Jager
  • Patent number: 5912294
    Abstract: Aqueous polymer emulsions are obtained by polymerizing a mixture of hydrophobic and hydrophilic ethylenically unsaturated monomers by the free radical aqueous emulsion polymerization method and using, as the dispersing medium, a mixture of water and an organic solvent which is not completely soluble in water, the amount of solvent accounting for more than 20% by weight of the total amount of monomers to be polymerized.
    Type: Grant
    Filed: April 2, 1996
    Date of Patent: June 15, 1999
    Assignee: BASF Aktiengesellschaft
    Inventor: Christian Schade
  • Patent number: 5869032
    Abstract: Quaternized copolymers suitable as active ingredients in hair styling compositions are obtainable from N-vinylimidazoles, N-vinylcaprolactam, N-vinylpyrrolidone and, if required, further monomers.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: February 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Jurgen Tropsch, Axel Sanner, Peter Hossel, Hans-Jurgen Raubenheimer, Christian Schade
  • Patent number: 5849853
    Abstract: Water-insoluble polymers are prepared by free radical polymerization of ethylenically unsaturated monomers by a process in which the polymerization is carried out in an aqueous gel phase having a viscosity of at least 800 mPa.s and the gel former has a molecular weight of more than 20,000. The dispersions obtained have a long shelf life and the polymer can be readily precipitated.
    Type: Grant
    Filed: December 24, 1996
    Date of Patent: December 15, 1998
    Assignee: BASF Aktiengesellschaft
    Inventor: Christian Schade
  • Patent number: 5846924
    Abstract: There are described the use of copolymers obtainable by free-radically initiated copolymerization of monomer mixtures comprising (a) 60-99% by weight of 1-vinylpyrrolidone, 1-vinyl-imidazole or mixtures thereof, (b) 1-40% by weight of nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of salts or in quaternized form, and optionally (c) up to 20% by weight of other monoethylenically unsaturated monomers, as detergent additives for inhibiting dye transfer during the wash, detergents which contain such polymers, and polymers which are obtainable by free-radically initiated polymerization of (a) 1-vinylpyrrolidone, 1-vinylimidazole, 1-vinylimidazolium compounds, or mixtures thereof, and optionally (b) other nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of the salts or in quaternized form, and/or (c) other monoethylenically unsaturated monomers, in an aqueous medium in the presence of water-soluble prot
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: December 8, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Detering, Christian Schade, Wolfgang Trieselt, Juergen Tropsch
  • Patent number: 5830844
    Abstract: Water-insoluble, crosslinked polymers containing polymerized units of 1-vinylpyrrolidone and/or 1-vinylimidazoles of the formula ##STR1## where R, R.sup.1 and R.sup.2 are identical or different and each is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl, or of 4-vinylpyridine N-oxide, in finely divided form, at least 90% by weight of the polymers having a particle size from 0.1 to 500 .mu.m, are useful as detergent additives for inhibiting the transfer of dye during the wash.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: November 3, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Jurgen Detering, Christian Schade, Johannes Perner, Hans-Ulrich Jager
  • Patent number: 5804662
    Abstract: Agglomerated, finely divided, crosslinked vinylimidazole copolymers obtainable by free-radically initiated polymerization of N-vinylimidazoles of the formula ##STR1## where R, R.sup.1 and R.sup.2 are identical or different and each is H, C.sub.1 -C.sub.
    Type: Grant
    Filed: August 19, 1997
    Date of Patent: September 8, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Schade, Karl-Heinrich Schneider
  • Patent number: 5773545
    Abstract: Polymers of alkyl-1-vinylimidazoles, a process for preparing polymers of alkyl-1-vinylimidazoles by free-radical polymerization of a monomer mixture comprising(a) 10-100% by weight of at least one alkyl-1-vinylimidazole and(b) 0-90% by weight of 1-vinylpyrrolidone, 1-vinylcaprolactam, 1-vinyltriazole, 1-vinylimidazole, 1-vinyloxazolidinone or mixtures thereof,(c) 0-30% by weight of other monoethylenically unsaturated monomers and(d) 0-10% by weight of a monomer containing at least 2 monoethylenic double bondsin water, at least one C.sub.1 -C.sub.4 -alcohol or mixtures thereof, and the use of polymers which comprise at least 10% by weight of an alkyl-1-vinylimidazole as copolymerized unit as additive to detergents to inhibit transfer of dyes during the washing process.
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: June 30, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Schade, Hans-Ulrich Jager, Jurgen Detering
  • Patent number: 5677384
    Abstract: Grafted polyamidoamines and grafted polyethyleneimines obtainable by free-radically initiated polymerization of(a) 1-vinylpyrrolidone, 1-vinyltriazole, 1-vinylimidazoles, mixtures of said monomers or mixtures of at least one of said monomers with up to 20% by weight of other monoethylenically unsaturated monomers in the presence of(b) water-soluble or -dispersible polyamidoamines, polyethyleneimines or mixtures thereof in a weight ratio of (a):(b) from 5:95 to 95:5, are useful as dye transfer inhibitors in surfactant-based detergents when included therein in an amount from 0.05 to 10% by weight.
    Type: Grant
    Filed: September 7, 1995
    Date of Patent: October 14, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Detering, Christian Schade, Knut Oppenlaender, Michael Zirnstein, Guenter Scherr, Wolfgang Trieselt, Volker Schwendemann
  • Patent number: 5639832
    Abstract: Process for the preparation of products of the reaction of polyaspartimides and amino acids by reaction of amino acids with polyaspartimides in aqueous medium at pH values at which at least 5% of the amino groups in the amino acids are in non-protonated form in equilibrium with the protonated form, and use of the reaction products obtainable in this way and of products of the reaction of polyaspartimides with alkanolamines or aminated C.sub.1 -C.sub.30 -fatty alcohol alkoxylates which contain as copolymerized units up to 50 mol % of ethylene oxide and/or propylene oxide per mol of fatty alcohol, as additive to detergents and cleaners, as scale inhibitor and as dispersant.
    Type: Grant
    Filed: September 6, 1995
    Date of Patent: June 17, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Kroner, Gunnar Schornick, Dieter Boeckh, Richard Baur, Birgit Potthoff-Karl, Volker Schwendemann, Christian Schade, Alexander Kud
  • Patent number: 5637664
    Abstract: Polymeric, catalytically-active compounds having imidazole groups linked terminally and/or laterally to the polymer chain through reactive groups on the polymer chain are disclosed. The polymer chain is selected from the group consisting of polyether ketones; acidic, basic, or neutral ion exchange resins; polymeric isocyanates; polymers or copolymers containing maleic acid or maleic anhydride; and polymers containing benzyl halide groups.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: June 10, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Bruchmann, Roland Minges, Christian Schade, Konrad Stiefenhoefer
  • Patent number: 5627151
    Abstract: There are described the use of copolymers obtainable by free-radically initiated copolymerization of monomer mixtures comprising(a) 60-99% by weight of 1-vinylpyrrolidone, 1-vinylimidazole or mixtures thereof,(b) 1-40% by weight of nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of salts or in quaternized form, and optionally(c) up to 20% by weight of other monoethylenically unsaturated monomers,as detergent additives for inhibiting dye transfer during the wash, detergents which contain such polymers, and polymers which are obtainable by free-radically initiated polymerization of(a) 1-vinylpyrrolidone, 1-vinylimidazole, 1-vinylimidazolium compounds, or mixtures thereof, and optionally(b) other nitrogen-containing, basic ethylenically unsaturated monomers in the form of the free bases, in the form of the salts or in quaternized form, and/or(c) other monoethylenically unsaturated monomers,in an aqueous medium in the presence of water-soluble proteins and
    Type: Grant
    Filed: April 21, 1995
    Date of Patent: May 6, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Detering, Christian Schade, Wolfgang Trieselt, Juergen Tropsch
  • Patent number: 5622926
    Abstract: Copolymers which are obtainable by free radical copolymerization of a mixture of(a) from 20 to 95% by weight of 1-vinylpyrrolidone, a 1-vinylimidazole or a mixture of 1-vinylpyrrolidone and/or 1-vinylimidazoles which may contain up to 20% by weight of other monoethylenically unsaturated monomers and(b) from 5 to 80% by weight of water-insoluble polymers which contain at least one ethylenically unsaturated double bond and/or one mercapto group in the molecule, processes for the preparation of the copolymers by copolymerization of the compounds of groups (a) and (b) in the abovementioned amounts in water, an alcohol, an ester or a ketone in the presence of free radical initiators, and the use of the copolymers thus obtainable and of copolymers of from 20 to 95% by weight of 1-vinylpyrrolidone or a mixture of 1-vinylpyrrolidone with up to 20% by weight of other monoethylenically unsaturated monomers andfrom 10 to 80% by weight of styrene as additives for detergents for inhibiting the dye transfer during the wash
    Type: Grant
    Filed: June 21, 1995
    Date of Patent: April 22, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Schade, Juergen Detering, Wolfgang Trieselt
  • Patent number: 5578684
    Abstract: Polyvinylpyridine N-oxides are prepared by oxidizing polyvinyl-pyridines with aqueous solutions of hydrogen peroxide in the presence of acids and oxides or acids of elements of Groups 5b, 6b, 7b and 8 of the Periodic Table or of salts of these acids as catalyst, it also being possible for the oxidation to take place in the absence of the catalysts when from 40 to 80% strength aqueous solutions of at least dibasic carboxylic acids or of polymers of monoethylenically unsaturated carboxylic acids are used as solvent.
    Type: Grant
    Filed: August 24, 1995
    Date of Patent: November 26, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Christian Schade, Dieter Boeckh, Juergen Detering
  • Patent number: 5565527
    Abstract: Polymeric, catalytically active compounds comprising polymer chains to which imidazole groups are linked terminally or laterally are used as catalysts for the dimerization of isocyanates.
    Type: Grant
    Filed: June 1, 1995
    Date of Patent: October 15, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Bruchmann, Roland Minges, Christian Schade, Konrad Stiefenhoefer
  • Patent number: 5484916
    Abstract: In a process for the preparation of polyisocyanates containing uretdione groups by catalytic dimerization of monomeric isocyanates, the catalysts employed are polymers carrying imidazole groups.
    Type: Grant
    Filed: May 10, 1993
    Date of Patent: January 16, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Bruchmann, Roland Minges, Christian Schade