Patents by Inventor Christian Streicher
Christian Streicher has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9943775Abstract: The invention concerns a flexible process for purifying a solvent which inhibits the formation of hydrates during gas processing, in particular monoethylene glycol (MEG), said solvent having a boiling point which is higher than that of water and, at least at one point in time, being mixed with water and salts, the process operating in a different manner with the same facility as a function of the quantity of salts in the MEG to be treated. The process operates in accordance with a phase known as reclaiming (separation of salts under vacuum followed by vacuum distillation) when the salts content exceeds the precipitation threshold and if not, the process operates in a regeneration phase (absence of separation of salts and no operation under vacuum). Advantageously, the change is made under the control of means for testing the salts.Type: GrantFiled: November 19, 2014Date of Patent: April 17, 2018Assignee: PROSERNATInventors: Jeremie Esquier, Bernard Chambon, Christian Streicher
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Publication number: 20150144477Abstract: The invention concerns a flexible process for purifying a solvent which inhibits the formation of hydrates during gas processing, in particular monoethylene glycol (MEG), said solvent having a boiling point which is higher than that of water and, at least at one point in time, being mixed with water and salts, the process operating in a different manner with the same facility as a function of the quantity of salts in the MEG to be treated. The process operates in accordance with a phase known as reclaiming (separation of salts under vacuum followed by vacuum distillation) when the salts content exceeds the precipitation threshold and if not, the process operates in a regeneration phase (absence of separation of salts and no operation under vacuum). Advantageously, the change is made under the control of means for testing the salts.Type: ApplicationFiled: November 19, 2014Publication date: May 28, 2015Applicant: PROSERNATInventors: Jeremie ESQUIER, Bernard CHAMBON, Christian STREICHER
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Patent number: 7678344Abstract: Process and device for regeneration of a used absorbent from a desulfurization zone or from the desulfurization of a gas containing sulfur oxides, comprising regeneration simultaneously with filtering of the absorbent, in a reducing atmosphere, wherein partial combustion of a regeneration gas is also carried out upstream from regeneration, the products of the partial combustion being mixed with the used absorbent prior to the regeneration-filtration stage. The absorbent may be, e.g., solid absorbents based on magnesium oxide. The regeneration gas may be hydrogen sulfide and/or a hydrocarbon. For example, H2S can be partially combusted and the products of the partial combustion, including H2S, H2, SO2 and sulfur, mixed with the used absorbent prior to the regeneration-filtration stage.Type: GrantFiled: September 27, 2004Date of Patent: March 16, 2010Assignee: Institut Francais du PetroleInventors: Etienne Lebas, Gérard Martin, Christian Streicher
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Patent number: 6960548Abstract: Process and device for regeneration of a used absorbent from a desulfurization zone or from the desulfurization of a gas containing sulfur oxides, comprising regeneration simultaneously with filtering of the absorbent, in a reducing atmosphere, wherein partial combustion of a regeneration gas is also carried out upstream from regeneration, the products of the partial combustion being mixed with the used absorbent prior to the regeneration-filtration stage. The absorbent may be, e.g., solid absorbents based on magnesium oxide. The regeneration gas may be hydrogen sulfide and/or a hydrocarbon. For example, H2S can be partially combusted and the products of the partial combustion, including H2S, H2, SO2 and sulfur, mixed with the used absorbent prior to the regeneration-filtration stage.Type: GrantFiled: May 31, 2001Date of Patent: November 1, 2005Assignee: Institute Francais du PetroleInventors: Etienne Lebas, Gérard Martin, Christian Streicher
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Patent number: 6872368Abstract: A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone downstream of the contacting stage. In order to remove by-products resulting from degradation of the catalyst, a liquid fraction F containing at least solvent, catalyst, sulfur and the solid by-products resulting from degradation of the catalyst is extracted from after the contacting stage.Type: GrantFiled: July 11, 2001Date of Patent: March 29, 2005Assignee: Institut Francais du PetroleInventors: Fabrice Lecomte, Christian Streicher, Cécile Barrere-Tricca
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Patent number: 6872367Abstract: A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the following stages: contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering a gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide, and a mixture containing liquid sulfur, liquid solvent and solid by-products resulting from the degradation of the catalyst, separating the liquid sulfur from the liquid solvent in a decantation zone, extracting a liquid fraction F containing at least the solid by-products from a layer between the liquid solvent and the liquid sulfur in the decantation zone, sending the liquid fraction F to a processing stage distinct from the contacting stage, and recovering at least a stream F1 comprising most of the solid by-products and a stream F2 mostly comprising solvent nearly free of the solid by-products from the processing stage.Type: GrantFiled: July 3, 2001Date of Patent: March 29, 2005Assignee: Institut Francais du PetroleInventors: Fabrice Lecomte, Christian Streicher, Daniel Benayoun, Cécile Barrere-Tricca
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Publication number: 20050063886Abstract: Process and device for regeneration of a used absorbent from a desulfurization zone or from the desulfurization of a gas containing sulfur oxides, comprising regeneration simultaneously with filtering of the absorbent, in a reducing atmosphere, wherein partial combustion of a regeneration gas is also carried out upstream from regeneration, the products of the partial combustion being mixed with the used absorbent prior to the regeneration-filtration stage. The absorbent may be, e.g., solid absorbents based on magnesium oxide. The regeneration gas may be hydrogen sulfide and/or a hydrocarbon. For example, H2S can be partially combusted and the products of the partial combustion, including H2S, H2, SO2 and sulfur, mixed with the used absorbent prior to the regeneration-filtration stage.Type: ApplicationFiled: September 27, 2004Publication date: March 24, 2005Inventors: Etienne Lebas, Gerard Martin, Christian Streicher
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Patent number: 6780396Abstract: A process for the production of hydrogen from a hydrogen sulfide feedstock, comprising a stage for heating feedstock (1) in a heating zone (2, 5) to a suitable temperature so as to produce a hot gas (6) that contains hydrogen and elementary sulfur, whereby this heating is carried out at least in part by an external heat source and a stage for rapid cooling of the hot gas thus obtained, by mixing with a fluid (8) by means of at least one mixer (7), preferably an ejector, so as to obtain a gaseous effluent (9). The mixing time is less than 20 milliseconds. Elementary sulfur (11) is separated from this effluent and the hydrogen is recovered. Application for the elimination of hydrogen sulfide and the production of hydrogen.Type: GrantFiled: April 30, 2002Date of Patent: August 24, 2004Assignee: Institut Francais du PetroleInventor: Christian Streicher
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Patent number: 6706250Abstract: A process for the purification of sulfur that contains impurities is described. In a contact zone (1), solid sulfur (2) is brought into contact with at least one organic solvent (16) that is selected from the group that is formed by monohydric alcohols with 8 to 40 carbon atoms, polyols that comprise 2 to 8 hydroxyl groups and that have 8 to 40 carbon atoms, polyalkylene glycols and polyalkylene glycol ethers under suitable conditions for carrying out the melting of sulfur. The supply of sulfur is halted, and the mixture that is obtained is allowed to decant so as to produce the segregation or liquid/liquid separation of the purified liquid sulfur that is obtained and organic solvent that contains impurities. At least a portion of the purified liquid sulfur is drawn off (8) from the lower portion of the contact zone. The solvent can be used until it is saturated with products that are dissolved and/or in suspension, no longer allowing the separation of the liquid sulfur and the solvent.Type: GrantFiled: December 21, 2001Date of Patent: March 16, 2004Assignee: Institut Francais du PetroleInventors: Pierre-Louis Carrette, Thierry Huard, Christian Streicher
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Patent number: 6669921Abstract: The present invention relates to a process for regenerating an at least partly reduced catalytic redox solution. The solution includes at least one polyvalent metal chelated by a chelating agent and is circulated in at least one regeneration zone while an oxygen-containing gas is injected into the regeneration zone. The process includes measuring a concentration of oxygen dissolved in a regeneration zone effluent. The process also includes adjusting a flow rate of the at least partly reduce catalytic redox solution entering the at least one regeneration zone and/or an oxygen-containing gas entering the regeneration zone in response to a measured concentration of oxygen, until a concentration of oxygen in the regeneration zone effluent is less than 20% of an amount of oxygen dissolved in water saturated with oxygen. Thus, degradation of the chelating agent in the catalytic redox solution is minimized.Type: GrantFiled: December 21, 2001Date of Patent: December 30, 2003Assignee: Institute Francais du PetroleInventors: Thierry Huard, Christian Streicher
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Patent number: 6596253Abstract: In the desulfurization of a gaseous feed containing hydrogen sulfide, comprising contacting the gaseous feed with a catalytic solution containing a chelated polyvalent metal under suitable conditions for oxidation of the hydrogen sulfide to elementary sulfur and concomitant reduction of the chelated polyvalent metal from a higher oxidation level to a lower oxidation level, recovering a gaseous effluent substantially freed from hydrogen sulfide, and a catalytic solution at least partly reduced and containing elementary sulfur, separating the solid elementary sulfur from the reduced catalytic solution, and regenerating the reduced catalytic solution by contacting the catalytic solution with a gas containing oxygen by means of an ejector.Type: GrantFiled: June 12, 2000Date of Patent: July 22, 2003Assignee: Institut Francais du PetroleInventors: Cécile Barrere-Tricca, Christian Streicher, Jean-Charles Viltard
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Patent number: 6589498Abstract: A process intended for desulfurization of a gaseous feed containing hydrogen sulfide, includes at least the following stages: a) contacting the gaseous feed with a catalytic solution containing at least one polyvalent metal chelated by at least one chelating agent, under suitable conditions for oxidation of the hydrogen sulfide to elemental sulfur and concomitant reduction of the polyvalent metal from a higher oxidation level to a lower oxidation level, b) recovering on the one hand a gaseous effluent substantially freed from hydrogen sulfide and, on the other hand, the catalytic solution at least reduced and containing elemental sulfur, and c) recycling at least a fraction F1 of the catalytic solution at least reduced and containing solid elemental sulfur to absorption stage a) so as to reduce the number of sulfur grains of very small size.Type: GrantFiled: June 9, 2000Date of Patent: July 8, 2003Assignee: Institut Francais du PetroleInventors: Cécile Barrere-Tricca, Thierry Huard, Christian Streicher
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Publication number: 20030031607Abstract: A process for the production of hydrogen from a hydrogen sulfide feedstock, comprising a stage for heating feedstock (1) in a heating zone (2, 5) to a suitable temperature so as to produce a hot gas (6) that contains hydrogen and elementary sulfur, whereby this heating is carried out at least in part by an external heat source and a stage for rapid cooling of the hot gas thus obtained, by mixing with a fluid (8) by means of at least one mixer (7), preferably an ejector, so as to obtain a gaseous effluent (9). The mixing time is less than 20 milliseconds. Elementary sulfur (11) is separated from this effluent and the hydrogen is recovered.Type: ApplicationFiled: April 30, 2002Publication date: February 13, 2003Applicant: Institut Francais du PetroleInventor: Christian Streicher
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Method and device for regenerating used absorbents derived from treatment of thermal generator fumes
Publication number: 20020136673Abstract: The invention concerns a method and a device for regenerating used absorbent derived from a desulphurizing zone or from a gas containing sulphur oxides, comprising regeneration simultaneous with filtering of said absorbent, in reducing atmosphere, and which further consists in partial combustion of a regenerating gas upstream of the regeneration process, and in mixing the products of said partial combustion with the used absorbent before the regeneration-filtering step.Type: ApplicationFiled: April 18, 2002Publication date: September 26, 2002Inventors: Etienne Lebas, Gerard Martin, Christian Streicher -
Publication number: 20020119086Abstract: A process is described for regenerating an at least partly reduced catalytic redox solution, whereby said process includes at least one complexing agent of a polyvalent metal that is associated with the solution in which the solution is circulated in a regeneration zone in the presence of an oxygen-containing gas under appropriate regeneration conditions, and a regeneration effluent is recovered that is at least partly oxidized. The concentration of the oxygen that is dissolved in the regeneration effluent is measured, and the operating parameters are adjusted so as to minimize the degradation of the complexing agent and to regenerate the catalytic solution, at least in part.Type: ApplicationFiled: December 21, 2001Publication date: August 29, 2002Applicant: Institut Francais du PetroleInventors: Thierry Huard, Christian Streicher
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Publication number: 20020081261Abstract: A process for the purification of sulfur that contains impurities is described. In a contact zone (1), solid sulfur (2) is brought into contact with at least one organic solvent (16) that is selected from the group that is formed by monohydric alcohols with 8 to 40 carbon atoms, polyols that comprise 2 to 8 hydroxyl groups and that have 8 to 40 carbon atoms, polyalkylene glycols and polyalkylene glycol ethers under suitable conditions for carrying out the melting of sulfur. The supply of sulfur is halted, and the mixture that is obtained is allowed to decant so as to produce the segregation or liquid/liquid separation of the purified liquid sulfur that is obtained and organic solvent that contains impurities. At least a portion of the purified liquid sulfur is drawn off (8) from the lower portion of the contact zone. The solvent can be used until it is saturated with products that are dissolved and/or in suspension, no longer allowing the separation of the liquid sulfur and the solvent.Type: ApplicationFiled: December 21, 2001Publication date: June 27, 2002Applicant: Institut Francais du PetroleInventors: Pierre-Louis Carrette, Thierry Huard, Christian Streicher
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Publication number: 20020012617Abstract: A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the following stages: contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering a gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide, and a mixture containing liquid sulfur, liquid solvent and solid by-products resulting from the degradation of the catalyst, separating the liquid sulfur from the liquid solvent in a decantation zone, extracting a liquid fraction F containing at least the solid by-products from a layer between the liquid solvent and the liquid sulfur in the decantation zone, sending the liquid fraction F to a processing stage distinct from the contacting stage, and recovering at least a stream F1 comprising most of the solid by-products and a stream F2 mostly comprising solvent nearly free of the solid by-products from the processing stage.Type: ApplicationFiled: July 3, 2001Publication date: January 31, 2002Inventors: Fabrice Lecomte, Christian Streicher, Daniel Benayoun, Cecile Barrere-Tricca
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Publication number: 20010055549Abstract: A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent containing at least one catalyst in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone downstream of the contacting stage. In order to remove by-products resulting from degradation of the catalyst, a liquid fraction F containing at least solvent, catalyst, sulfur and the solid by-products resulting from degradation of the catalyst is extracted from after the contacting stage.Type: ApplicationFiled: July 11, 2001Publication date: December 27, 2001Inventors: Fabrice Lecomte, Christian Streicher, Cesile Barrere-Tricca
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Removal of by-products in method for processing a gas containing hydrogen sulfide and sulfur dioxide
Patent number: 6280698Abstract: A method for processing a gas, such as a Claus tail gas, containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the steps of contacting the gas with a liquid solvent, such as polyethylene glycol, containing at least one catalyst, such as sodium salicylate, in a contacting stage, recovering gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide from the contacting stage, and separating liquid sulfur from liquid solvent in a decantation zone beneath the contacting stage.Type: GrantFiled: November 22, 1999Date of Patent: August 28, 2001Assignee: Institut Francais du PetroleInventors: Fabrice Lecomte, Christian Streicher, Cécile Barrere-Tricca -
Patent number: 6277352Abstract: A method for processing a gas containing at least hydrogen sulfide (H2S) and at least sulfur dioxide (SO2), includes the following stages: contacting the gas with a liquid solvent, such as polyethylene glycol, containing at least one catalyst, such as sodium salicylate, in a contacting stage, recovering a gaseous effluent substantially containing no hydrogen sulfide and no sulfur dioxide, and a mixture containing liquid sulfur, liquid solvent and solid by-products such as alkali metal or alkaline earth metal sulfates or thiosulfates, resulting from the degradation of the catalyst, separating the liquid sulfur from the liquid solvent in a decantation zone, extracting a liquid fraction F containing at least the solid by-products from a layer between the liquid solvent and the liquid sulfur in the decantation zone, sending the liquid fraction F to a processing stage distinct from the contacting stage, and recovering at least a stream F, comprising most of the solid by-products and a stream F2 mostly comprising sType: GrantFiled: October 7, 1999Date of Patent: August 21, 2001Assignee: Institut Francais du PetroleInventors: Fabrice Lecomte, Christian Streicher, Daniel Benayoun, Cecile Barrere-Tricca