Abstract: Provided herein is a curable fluoroelastomer composition including at least one fluoroelastomer comprising copolymerized units of a nitrile group-containing cure site monomer; a cure system comprising at least two different dihydrazides; and optionally at least one additive. Further provided are pre-forms comprising the curable composition, methods of curing the fluoroelastomer composition, compositions that are the product of curing the curable fluoroelastomer composition, and articles comprising the cured fluoroelastomer composition.

Abstract: Curing fluoroelastomers using curing agents of formula, R1N?CR2R3, wherein R1 is H; R2 is selected from the group consisting of H, NH2, and NR4R5; R3 is selected from the group consisting of Ph, SO2H, NR6R7, 2-pyridine, and CH2CONH2; R4 is H; R5 is selected from the group consisting of Ph, NH2, and CN; R6 is selected from the group consisting of H, NHPh, CCONH2, C1 to C8 linear alkyl group, and C1 to C8 branched alkyl group; and R7 is selected from the group consisting of Ph, COOC(CH3)3, NH2, CH2COOH, CSNH2, CNHNH3+Cl?, p-phenylCN, COPh,

Abstract: Fluoroelastomer compositions comprising fluoroelastomers having copolymerized units of a nitrile-containing cure site monomer are cured with certain hydrazone or oxime curatives.

Abstract: The present invention is directed to perfluoroelastomer compounds comprising carbon black having a particle size of 100 nm or greater; a mineral filler selected from the group consisting of titanium dioxide, barium sulfate, or a combination of these; a cure site monomer; and a curing agent. These perfluoroelastomer compounds, when cured into articles, exhibit desirable compression stress relaxation properties.

Abstract: The present invention is directed to compounds comprising a perfluoroelastomer and a blend of two different particle size carbon blacks that, when cured with a curing agent, comprise a heterocyclic or perfluorinated crosslink. Such compounds comprise copolymerized units of unsaturated fluorinated olefins, a perfluoro(vinyl ether), and a cure site fluorinated monomer having a nitrile cure site, plus a blend of carbon blacks. Articles cured from these compounds exhibit improved sealing force.

Abstract: The present invention is directed to compounds comprising a perfluoroelastomer and a blend of two different particle size carbon blacks that, when cured with a curing agent, comprise a heterocyclic or perfluorinated crosslink. Such compounds comprise copolymerized units of unsaturated fluorinated olefins, a perfluoro(vinyl ether), and a cure site fluorinated monomer having a nitrile cure site, plus a blend of carbon blacks. Articles cured from these compounds exhibit improved sealing force.

Abstract: Fluoroelastomer compositions comprising fluoroelastomers having copolymerized units of a nitrile-containing cure site monomer are cured with certain hydrazone or oxime curatives.

Abstract: Fluoroelastomer compositions comprising fluoroelastomers having copolymerized units of a nitrile-containing cure site monomer are cured with certain hydrazone or oxime curatives.

Abstract: Curing fluoroelastomers using curing agents of formula, R1N?CR2R3, wherein R1 is H; R2 is selected from the group consisting of H, NH2, and NR4R5; R3 is selected from the group consisting of Ph, SO2H, NR6R7, 2-pyridine, and CH2CONH2; R4 is H; R5 is selected from the group consisting of Ph, NH2, and CN; R6 is selected from the group consisting of H, NHPh, CCONH2, C1 to C8 linear alkyl group, and C1 to C8 branched alkyl group; and R7 is selected from the group consisting of Ph, COOC(CH3)3, NH2, CH2COOH, CSNH2, CNHNH3+Cl?, p-phenylCN, COPh,

Abstract: Curing fluoroelastomers using curing agents of formula, R1N?CR2R3, wherein R1 is H; R2 is selected from the group consisting of H, NH2, and NR4R5; R3 is selected from the group consisting of Ph, SO2H, NR6R7, 2-pyridine, and CH2CONH2; R4 is H; R5 is selected from the group consisting of Ph, NH2, and CN; R6 is selected from the group consisting of H, NHPh, CCONH2, C1 to C8 linear alkyl group, and C1 to C8 branched alkyl group; and R7 is selected from the group consisting of Ph, COOC(CH3)3, NH2, CH2COOH, CSNH2, CNHNH3+Cl?, p-phenylCN, COPh,

Abstract: Fluoroelastomer compositions comprising fluoroelastomers having copolymerized units of a nitrile-containing cure site monomer are cured with certain hydrazone or oxime curatives.

Abstract: Curing fluoroelastomers using curing agents of formula, R1N?CR2R3 , wherein R1 is H; R2 is selected from the group consisting of H, NH2, and NR4R5; R3 is selected from the group consisting of Ph, SO2H, NR6R7, 2-pyridine, and CH2CONH2; R4 is H; R5 is selected from the group consisting of Ph, NH2, and CN; R6 is selected from the group consisting of H, NHPh, CCONH2, C1 to C8 linear alkyl group, and C1 to C8 branched alkyl group; and R7 is selected from the group consisting of Ph, COOC(CH3)3, NH2, CH2COOH, CSNH2, CNHNH3+Cl31 , p-phenylCN, COPh,

Abstract: This invention pertains to a novel perfluoroalkyl-crosslinked fluoropolymer with perfluoroether pendant groups. The perfluoroalkyl-crosslinked fluoropolymer hereof is particularly well-suited for use in chemically and thermally aggressive environments, in part by virtue of the highly stable perfluoroalkyl crosslink. The perfluroalkyl-crosslinked fluoropolymer hereof can be prepared by crosslinking in situ a crosslinkable precursor in the form of a shaped article. A crosslinkable precursor is a fluoropolymer having a dichloroamino-functionalized functionalized perfluoroether pendant group.

Abstract: Compounds comprising a fluoroelastomer cured with peroxide curing agents and a metal sulfide, wherein the compounds comprise copolymerized units of unsaturated fluorinated olefins, a perfluoro(vinyl ether), and a cure site fluorinated monomer comprising one or more bromine atoms and/or one or more iodine atoms. Articles cured from these compounds; and processes of curing these compounds to result in articles.

Abstract: This invention pertains to a novel fluoropolymer characterized by a dichloroamino-functionalized perfluoroether pendant group that terminates in —CF2NCl2. The polymer so formed is crosslinkable and useful for the preparation of shaped articles and photo-imaged coatings. The novel fluoropolymer can be thermally treated to form crosslinked fluoropolymers with highly stable perfluoroalkylene crosslinks. The novel fluoropolymer is conveniently prepared by treating a cyano-functionalized fluoropolymer with Cl—F.

Abstract: This invention pertains to a novel thermal process for converting a fluoropolymer having cyano-functionalized perfluoroether pendant groups into a novel perfluoroalkyl-crosslinked fluoropolymer having perfluoroether pendant groups. The process comprises heating the fluoropolymer having cyano-functionalized perfluoroether pendant groups in the presence of Cl—F to a temperature in the range of 200 to 300° C. The fluoropolymer having cyano-functionalized perfluoroether pendant groups can first be formed into a shaped article, and the shaped article then subject to treatment in situ with Cl—F.

Abstract: Disclosed herein is a process for the manufacture of a fluoroelastomer composition containing fluoropolymer fibrils. The process comprises applying shear to a fluoroelastomer gum in a mixer while adding a liquid dispersion of fibrillatable fluoropolymer.

Abstract: This invention pertains to a novel thermal process for converting a fluoropolymer having cyano-functionalized perfluoroether pendant groups into a novel perfluoroalkyl-crosslinked fluoropolymer having perfluoroether pendant groups. The process comprises heating the fluoropolymer having cyano-functionalized perfluoroether pendant groups in the presence of Cl—F to a temperature in the range of 200 to 300° C. The fluoropolymer having cyano-functionalized perfluoroether pendant groups can first be formed into a shaped article, and the shaped article then subject to treatment in situ with Cl—F.

Abstract: This invention pertains to a novel fluoropolymer characterized by a dichloroamino-functionalized perfluoroether pendant group that terminates in —CF2NCl2. The polymer so formed is crosslinkable and useful for the preparation of shaped articles and photo-imaged coatings. The novel fluoropolymer can be thermally treated to form crosslinked fluoropolymers with highly stable perfluoroalkylene crosslinks. The novel fluoropolymer is conveniently prepared by treating a cyano-functionalized fluoropolymer with Cl—F.

Abstract: This invention pertains to a novel perfluoroalkyl-crosslinked fluoropolymer with perfluoroether pendant groups. The perfluoroalkyl-crosslinked fluoropolymer hereof is particularly well-suited for use in chemically and thermally aggressive environments, in part by virtue of the highly stable perfluoroalkyl crosslink. The perfluroalkyl-crosslinked fluoropolymer hereof can be prepared by crosslinking in situ a crosslinkable precursor in the form of a shaped article. A crosslinkable precursor is a fluoropolymer having a dichloroamino-functionalized functionalized perfluoroether pendant group.