Abstract: Al base - Si hypereutetic alloys can exhibit problems of variable and unwanted microstructure throughout the section of the article being cast. This problem is overcome by controlled cooling of the mold in critical areas, to remove or prevent excessive accumulation of heat energy and avoid the formation of intense convection currents in still molten alloy. Consequently, the necessary coupled growth of the Al-Si eutectic is promoted and the resultant microstructure is substantially free of primary Si. The 3HA and modified 3HA alloys of the applicant are considered on the basis of their wear resistance and improved machineability for automotive applications, such as engine blocks and cylinder heads. A first feature of the controlled cooling procedure is supply of coolant to regions in the mold, above and extending from the gate, such that solidification progresses uniformly from the remote regions of the mold spaces towards the gate to give a substantially uniform microstructure throughout the casting.

Abstract: A calcined microsphere of ultrafine bauxite particles having a mean particle size in the range 0.01 to 0.3 micrometers, said microsphere having a particle size less than 30 micrometers and being characterized by a substantially solid form having a pycnometric density substantially falling in the range 3.2-3.0 g/cm.sup.3, a BET surface area substantially falling in the range 0.05 to 0.5 m.sup.2 /g and a crystal grain size less than 4 micrometers, the surface chemistry of the microsphere being modified to enhance the wettability of the microsphere and to improve its ability to bond strongly with matrix materials in use.

Abstract: A cast hypereutectic Al-Si alloy with from 12-15% Si, having excellent wear resistance and machinability, improved fatigue strength and good levels of ambient and elevated temperature properties is provided, as well as a method of producing such alloy. The alloy and a melt used in the method contains Sr in excess of 0.10% and Ti in excess of 0.005%, the alloy further comprising: Cu 1.5 to 5.5%, Ni 1.0 to 3.00%, Mg 0.1 to 1.0%, Fe 0.1 to 1.0%, Mn 0.1 to 0.8%, Zr 0.01 to 0.1%, Zn 0 to 3.0%, Sn 0 to 0.2%, Pb 0 to 0.2%, Cr 0 to 0.1%, Na 0 to 0.01%, B (elemental) 0.05% maximum, Ca 0.003% maximum, P 0.003% maximum. Others 0.05 maximum each, the balance, apart from incidental impurities, being Al. The level of Sr in excess of 0.10% and Ti in excess of 0.

Abstract: A calcined microsphere of ultrafine bauxite particles having a mean particle size in the range 0.01 to 0.3 micrometers, said microsphere having a particle size less than 30 micrometers and being characterized by a substantially solid form having a pycnometric density substantially falling in the range 3.2-3.9 g/cm.sup.3, a BET surface area substantially falling in the range 0.05 to 0.5 m.sup.2 /g and a crystal grain size less than 4 micrometers, the surface chemistry of the microsphere being modified to enhance the wettability of the microsphere and to improve its ability to bond strongly with matrix materials in use.