Abstract: A preparation method of Cu—Pd—CeO2/?-Al2O3@NP catalyst and a synthesis method of benzopyrazine compounds. The preparation method of the Cu—Pd—CeO2/?-Al2O3@NP catalyst comprises the following steps: (1) preparing a CeO2/?-Al2O3 carrier; (2) preparing a CeO2/?-Al2O3@NP carrier; (3) preparing the Cu—Pd—CeO2/?-Al2O3@NP catalyst by impregnation method. A one-pot method for synthesizing benzopyrazine compounds of formula (III) includes using an o-nitroaniline compound of formula (I) and an aliphatic diol compound of formula (II) as raw materials, carrying out the one-pot synthesis of the benzopyrazine compound of formula (III) under solvent-free condition and under the combined action of the Cu—Pd—CeO2/?-Al2O3@NP catalyst prepared by the method and an alkali. The Cu—Pd—CeO2/?-Al2O3@NP catalyst increases the number of basic sites by doping N and P, and meanwhile loads CeO2 to assist in the extraction of protons, thereby improving the dehydrogenation activity and product selectivity.

Abstract: Provided are a nitrogen-phosphorus-modified granular carbon-supported bimetallic catalyst, a preparation method thereof and the use thereof. The catalyst comprises a nitrogen-phosphorus-modified carbon carrier and metal particles supported on the carbon carrier. The metal particles include first metal elementary substance particles, second metal elementary substance particles and bimetallic alloy phase particles. The percentage of the bimetallic alloy phase particles in the metal particles is ?80%, and at least 90% of the alloy phase particles have a size of 1 nm to 20 nm. The catalyst has advantages such as a high proportion of alloy phase particles, a uniform particle size distribution, a high metal utilization rate, low costs, high stability and a high catalytic activity.

Abstract: A sulfur-containing palladium-carbon catalyst prepared by loading palladium on an active carbon, mixing the palladium-carbon catalyst with a solvent to form a slurry, adding a sulfide to the slurry to treat the loaded palladium under a predetermined temperature, and removing liquid and drying to obtain the catalyst. The sulfur-containing palladium-carbon catalyst is suitable for making phenylene diamine rubber antioxidant with improved productivity and selectivity.

Abstract: A manufacturing method of a resistive random access storage unit, includes: forming a resistance layer on a first metal layer having a flat surface; forming a passivation layer on the resistance layer; performing an etching process to obtain a plurality of basic units, a basic unit comprising a first metal layer, a resistance layer, and a passivation layer, which are laminated sequentially; depositing a insulating dielectric layer, and flattening the insulating dielectric layer; etching the insulating dielectric layer and the passivation layer to form contacting holes corresponded to the basic units; filling metal wires in the contacting holes; forming a second metal layer. According to the above method, a uniformly distributed resistance can be formed on a whole wafer.

Abstract: A manufacturing method of a resistive random access storage unit, includes: forming a resistance layer on a first metal layer having a flat surface; forming a passivation layer on the resistance layer; performing an etching process to obtain a plurality of basic units, a basic unit comprising a first metal layer, a resistance layer, and a passivation layer, which are laminated sequentially; depositing a insulating dielectric layer, and flattening the insulating dielectric layer; etching the insulating dielectric layer and the passivation layer to form contacting holes corresponded to the basic units; filling metal wires in the contacting holes; forming a second metal layer. According to the above method, a uniformly distributed resistance can be formed on a whole wafer.

Abstract: A sulfur-containing palladium-carbon catalyst prepared by loading palladium on an active carbon, mixing the palladium-carbon catalyst with a solvent to form a slurry, adding a sulfide to the slurry to treat the loaded palladium under a predetermined temperature, and removing liquid and drying to obtain the catalyst. The sulfur-containing palladium-carbon catalyst is suitable for making phenylene diamine rubber antioxidant with improved productivity and selectivity.