Abstract: The present disclosure generally relates to adhesive articles including a multilayer carrier between two peelable adhesive layers. The multilayer carrier provides enhanced conformability to the adhesive article, which under certain circumstances can increase or enhance the product performance on surfaces (e.g., rough or textured surfaces such as, for example, wallpaper, drywall, cinderblock, etc.).

Abstract: A film is described comprising a (meth)acrylic polymer and a polyvinyl acetal (e.g. butyral) resin. In some embodiments, the film has a glass transition temperature (i.e. Tg) ranging from 30° C. to 60° C. In some embodiments, the film has a gel content of at least 20% or greater. In some embodiments, the film has an elongation at break of at least 175%. The film typically comprises photoinitiator as a result of the method by which the film was made. The film may be a monolithic film or a layer of a multilayer film.

Abstract: An (meth)acrylate pressure-sensitive adhesive copolymer crosslinking by a vinyl silicon crosslinking agent is described.

Abstract: A halogen-free flame retardant adhesive comprises an acrylic copolymer preparable by polymerization of monomers comprising a first monomer which comprises a low glass transition temperature (Tg) monomer, a second monomer which comprises a high Tg monomer, wherein at least one of the first and second monomers comprises a (meth)acrylate, and a phosphate containing monomer.

Abstract: A film is described comprises a (meth)acrylic polymer and a polyvinyl acetal (e.g. butyral) resin. The film has a tensile elastic modulus of at least 1 MPa at 25° C. and 1 hertz and a glass transition temperature (i.e. Tg) less than 30 C. The film typically comprises photoinitiator as a result of the method by which the film was made. In one embodiment, the film is heat bondable and further comprising a backing.

Abstract: Pressure sensitive adhesive compositions are described comprising at least one low Tg ethylenically unsaturated monomer, and at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups. The low Tg ethylenically unsaturated monomer typically has a Tg no greater than 10° C. In some embodiments, the composition comprises at least 50, 55, 60, 65, or 70 wt-% of low Tg ethylenically unsaturated monomer. The low Tg ethylenically unsaturated monomer is typically an alkyl (meth)acrylate comprising 4 to 20 carbon atoms. In another embodiment, an adhesive composition is described comprising a syrup. The syrup comprising i) a free-radically polymerizable solvent monomer; ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers, and iii) at least one silsesquioxane polymer crosslinker comprising a plurality of ethylenically unsaturated groups.

Abstract: A pressure-sensitive adhesive is provided including an emulsion polymer containing a (meth)acrylate copolymer and nanocrystalline cellulose. The inclusion of the nanocrystalline cellulose results in an increase in the overlap shear properties of the adhesive while maintaining the peel adhesion. Articles and emulsions including the pressure-sensitive adhesive are also provided.

Abstract: An (meth)acrylate pressure-sensitive adhesive copolymer is described prepared by crosslinking with a (meth)acrylic crosslinking monomer containing an allyl group.

Abstract: An (meth)acrylate pressure-sensitive adhesive copolymer crosslinking by a vinyl silicon crosslinking agent is described

Abstract: Pressure sensitive adhesive compositions are described comprising polymerized units derived from alkyl (meth)acrylate monomer(s) and a crosslinking monomer comprising at least two terminal groups selected from allyl, methallyl, or combinations thereof. In one embodiment, the pressure sensitive adhesive composition is a syrup or the reaction product of a syrup comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic polymer The syrup or the (meth)acrylic solute polymer comprises polymerized units derived from the cross-linking monomer. Also described are pressure sensitive adhesive articles and methods.

Abstract: Optical devices include a light source and an optical article, where the optical article is an acid-free, non-yellowing pressure sensitive adhesive light guide. The light source is optically coupled to the light guide such that light emitted by the light source enters the light guide and is transported within the light guide by total internal reflection. The light guide includes a plurality of features oriented to extract light being transported within the light guide.

Abstract: A pressure sensitive adhesive composition is described comprising at least 50 wt-% of polymerized units derived from alkyl meth(acrylate) monomer(s); and 0.2 to 15 wt-% of at least one cross-linking monomers comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In another embodiment, an adhesive composition is described comprising a syrup comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl (meth)acrylate monomers; wherein the syrup comprises at least one crosslinking monomer or the (meth)acrylic solute polymer comprises polymerized units derived from at least one crosslinking monomer, the crosslinking monomer comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In yet other embodiments, methods of preparing adhesive compositions are described.

Abstract: A film is described comprising a (meth)acrylic polymer and a polyvinyl acetal (e.g. butyral) resin. In some embodiments, the film has a glass transition temperature (i.e. Tg) ranging from 30° C. to 60° C. In some embodiments, the film has a gel content of at least 20% or greater. In some embodiments, the film has an elongation at break of at least 175%. The film typically comprises photoinitiator as a result of the method by which the film was made. The film may be a monolithic film or a layer of a multilayer film.

Abstract: Curable and cured compositions are provided that can contain a significant amount of a renewable material based on vegetable oil. More particularly, the curable compositions contain an acid-modified epoxidized vegetable oil (acid-modified EVO) and a (meth)acrylic copolymer having pendant carboxylic acid groups. When the curable composition is reacted to form a cured composition, the acid-modified EVO, which contains greater than one epoxide group per molecule, functions to crosslink the (meth)acrylic copolymer by reacting with the pendant carboxylic acid groups. If the (meth)acrylic copolymer is elastomeric, the cured composition can be a pressure-sensitive adhesive.

Abstract: Pressure-sensitive adhesives that have good performance characteristics under typical use conditions and that later can be degraded and/or removed readily under basic conditions are provided. More specifically, the pressure-sensitive adhesives contain a copolymeric (meth)acrylic-based elastomeric material prepared from a polymerizable material that contains a (meth)acrylate monomer having both a (meth)acryloyl group plus an ester linkage that is not part of a (meth)acryloyl group.

Abstract: A pressure sensitive adhesive composition is described comprising at least 50 wt-% of polymerized units derived from alkyl meth(acrylate) monomer(s); and 0.2 to 15 wt-% of at least one crosslinking monomers comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In another embodiment, an adhesive composition is described comprising a syrup comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl(meth)acrylate monomers; wherein the syrup comprises at least one crosslinking monomer or the (meth)acrylic solute polymer comprises polymerized units derived from at least one crosslinking monomer, the crosslinking monomer comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted.

Abstract: Pressure-sensitive adhesives that have good performance characteristics under typical use conditions and that later can be degraded and/or removed readily under basic conditions are provided. More specifically, the pressure-sensitive adhesives contain a copolymeric (meth)acrylic-based elastomeric material prepared from a polymerizable material that contains a (meth)acrylate monomer having both a (meth)acryloyl group plus an ester linkage that is not part of a (meth)acryloyl group.

Abstract: Optical devices include a light source and an optical article, where the optical article is an acid-free, non-yellowing pressure sensitive adhesive light guide. The light source is optically coupled to the light guide such that light emitted by the light source enters the light guide and is transported within the light guide by total internal reflection. The light guide includes a plurality of features oriented to extract light being transported within the light guide.

Abstract: There is provided an article having a release liner and a pressure sensitive adhesive composition disposed along a major surface of the release liner, where the pressure sensitive adhesive composition has at least 50 wt-% of polymerized units derived from alkyl meth(acrylate) monomer(s); and 0.2 to 15 wt-% of at least one crosslinking monomers comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted. In another embodiment, an adhesive composition is described comprising a syrup comprising i) a free-radically polymerizable solvent monomer; and ii) a solute (meth)acrylic polymer comprising polymerized units derived from one or more alkyl(meth)acrylate monomers; wherein the syrup comprises at least one crosslinking monomer or the (meth)acrylic solute polymer comprises polymerized units derived from at least one crosslinking monomer, the crosslinking monomer comprising a (meth)acrylate group and a C6-C20 olefin group, the olefin group being optionally substituted.