Abstract: A catalyst nanoparticle covalently bonded to a surface ligand wherein the surface ligand has a peripheral functional group having a property suitable to ensure solubility in a fluid such as a hydroxylic solvent, water, lower molecular weight alcohol, methanol, ethanol, iso-propanol, or and mixtures thereof. The peripheral functional group can have an ability to couple the catalyst nanoparticle to a second catalyst nanoparticle or to a bridging material. The peripheral functional group can be capable of interacting with a surface functional group on a conductive electrode substrate. The covalently-bound ligand bearing a peripheral functional group can have a charge opposite to or chemical reactivity amenable with that of the surface functional group. A method of making a catalyst nanoparticle comprising bonding a surface ligand to a catalyst nanoparticle wherein the bonding is via a covalent bond and the surface ligand has a peripheral functional group.

Abstract: A method of making a nanostructured electrode comprising depositing a self-assembled monolayer on a substrate, depositing a catalyst nanoparticle covalently bonded to a ligand, and depositing a material capable of binding to the self-assembled monolayer. The method includes depositing on a conductive electrode substrate a catalytic nanoparticle stabilized by a covalently-bound ligand bearing a peripheral functional group and depositing a material capable of binding to the peripheral functional group, wherein the conductive electrode substrate is chemically modified to create a surface functional group capable of supporting multilayer deposition. The method can include covalent grafting of a functional group to create an initial layer of positive charge on the surface, depositing a platinum nanoparticle stabilized by negatively-charged ligands onto the functional group, and providing a polymer component.

Abstract: A nanostructured electrode comprising a conductive electrode substrate having a surface functional group, a catalytic nanoparticle stabilized by a covalently-bound ligand bearing a peripheral functional group capable of interacting to the surface functional group, and a material capable of binding to the peripheral functional group. The conductive electrode substrate can be chemically modified and the surface functional group can create a layer of charge or chemical reactivity. The conductive electrode substrate can be chemically or electrochemically modified to create a surface functional group via covalent grafting capable of supporting multilayer deposition to create a layer of charge or chemical reactivity on the surface. The nanoparticle can be a platinum nanoparticle with covalently bonded negatively-charged ligands and the bridging material can be a polyelectrolyte.

Abstract: A method of making a nanostructured electrode comprising depositing a self-assembled monolayer on a substrate, depositing a catalyst nanoparticle covalently bonded to a ligand, and depositing a material capable of binding to the self-assembled monolayer. The method includes depositing on a conductive electrode substrate a catalytic nanoparticle stabilized by a covalently-bound ligand bearing a peripheral functional group and depositing a material capable of binding to the peripheral functional group, wherein the conductive electrode substrate is chemically modified to create a surface functional group capable of supporting multilayer deposition. The method can include covalent grafting of a functional group to create an initial layer of positive charge on the surface, depositing a platinum nanoparticle stabilized by negatively-charged ligands onto the functional group, and providing a polymer component.

Abstract: A catalyst nanoparticle covalently bonded to a surface ligand wherein the surface ligand has a peripheral functional group having a property suitable to ensure solubility in a fluid such as a hydroxylic solvent, water, lower molecular weight alcohol, methanol, ethanol, iso-propanol, or and mixtures thereof. The peripheral functional group can have an ability to couple the catalyst nanoparticle to a second catalyst nanoparticle or to a bridging material. The peripheral functional group can be capable of interacting with a surface functional group on a conductive electrode substrate. The covalently-bound ligand bearing a peripheral functional group can have a charge opposite to or chemical reactivity amenable with that of the surface functional group. A method of making a catalyst nanoparticle comprising bonding a surface ligand to a catalyst nanoparticle wherein the bonding is via a covalent bond and the surface ligand has a peripheral functional group.

Abstract: A nanostructured electrode comprising a conductive electrode substrate having a surface functional group, a catalytic nanoparticle stabilized by a covalently-bound ligand bearing a peripheral functional group capable of interacting to the surface functional group, and a material capable of binding to the peripheral functional group. The conductive electrode substrate can be chemically modified and the surface functional group can create a layer of charge or chemical reactivity. The conductive electrode substrate can be chemically or electrochemically modified to create a surface functional group via covalent grafting capable of supporting multilayer deposition to create a layer of charge or chemical reactivity on the surface. The nanoparticle can be a platinum nanoparticle with covalently bonded negatively-charged ligands and the bridging material can be a polyelectrolyte.