Abstract: A polymerizable liquid crystal composition for obtaining a retardation film that has high front contrast; and a liquid crystal polymer. A polymerizable liquid crystal composition which is characterized by containing a compound represented by formula (1). Exemplified are embodiments wherein in formula (1), W1 represents an alkyl group having 1-5 carbon atoms, an alkoxy group having 1-5 carbon atoms, an alkoxycarbonyl group having 1-5 carbon atoms or an alkanoyl group having 1-5 carbon atoms; Z1 represents —CH2CH2COO—; Z2 represents —OCOCH2CH2—; each of Y1 and Y2 represents a linking group; each of Q1 and Q2 represents a spacer; and each of P1 and P2 represents a polymerizable functional group.

Abstract: A polymerizable liquid crystal compound represented by formula (1). In formula (1), A1 is 1,4-phenylene, 1,4-cyclohexylene, 1,4-cyclohexenylene, pyridine-2,5-diyl, 1,3-dioxane-2,5-diyl or naphthalene-2,6-diyl, Z1 is a connecting group, m and n are independently an integer from 0 to 5, in which an expression: 1?m+n?8 holds, X1 is alkylene having 1 to 5 carbons, in which an atom thereof may be replaced by a hetero atom, and at least one of R1 is a polymerizable functional group.

Abstract: An object is to provide a polymerizable liquid crystal compound, a polymerizable liquid crystal composition containing the compound and liquid crystal polymerization film-kind capable of controlling chromatic dispersion characteristics and having low positive chromatic dispersion characteristics. An aspect can be exemplified in which the polymerizable liquid crystal compound is represented by formula (1): in which, in formula (1), G is a group composed of a quinoline skeleton, an isoquinoline skeleton, a quinoxaline skeleton or a quinazoline skeleton, A1 is 1,4-phenylene or 1,4-cyclohexylene, Z1 is a connecting group, m is an integer from 0 to 3, and R1 is a group containing a polymerizable group.

Abstract: To provide a polymerizable liquid crystal compound in order to produce a retardation film having excellent front contrast. A polymerizable liquid crystal composition including a compound represented by Formula (1). In Formula (1), for example, W1 is an alkoxycarbonyl group having 1 to 10 carbon atoms, an alkanoyl group having 1 to 10 carbon atoms, or a polymerizable functional group, A1 is independently 1,4-phenylene or naphthalene-2,6-diyl, Z1 is a linking group, m and n are independently an integer of 0 to 7, and satisfy 3?m+n?8, and P1 is a polymerizable functional group.

Abstract: Provided is a polymerizable liquid crystal compound represented by formula (1). An aspect can be exemplified, in which, in formula (1), W1 is hydrogen or a substituent, A1 is 1,4-phenylene, 1,4-cyclohexylene or naphthalene-2,6-diyl, Z1 and Y1 are a connecting group, m and n each are an integer from 0 to 7, in which an expression: 3?m+n?8 holds, Q1 is a spacer, and PG is a polymerizable group.

Abstract: Provided are: a polymerizable liquid crystal composition for obtaining a retardation film that has high front contrast; and a liquid crystal polymer. A polymerizable liquid crystal composition which is characterized by containing a compound represented by formula (1). Exemplified are embodiments wherein in formula (1), W1 represents an alkyl group having 1-5 carbon atoms, an alkoxy group having 1-5 carbon atoms, an alkoxycarbonyl group having 1-5 carbon atoms or an alkanoyl group having 1-5 carbon atoms; Z1 represents —CH2CH2COO—; Z2 represents —OCOCH2CH2—; each of Y1 and Y2 represents a linking group; each of Q1 and Q2 represents a spacer; and each of P1 and P2 represents a polymerizable functional group.

Abstract: Provided is a polymerizable liquid crystal compound represented by formula (1). In formula (1), A1 is 1,4-phenylene, 1,4-cyclohexylene, 1,4-cyclohexenylene, pyridine-2,5-diyl, 1,3-dioxane-2,5-diyl or naphthalene-2,6-diyl, Z1 is a connecting group, m and n are independently an integer from 0 to 5, in which an expression: 1 m+n?8 holds, X1 is alkylene having 1 to 5 carbons, in which an atom thereof may be replaced by a hetero atom, and at least one of R1 is a polymerizable functional group.

Abstract: Liquid crystal polymerization films, prepared by applying a polymerizable liquid crystal composition containing a polymerizable liquid crystal compound represented by formula (2) on an alignment film prepared by calcinating a composition containing a polymer represented by a repeating unit of formula (1), and subsequently polymerizing the polymerizable liquid crystal composition. In formula (1), R1 is independently a tetravalent group, R2 is independently a divalent functional group and R3 is independently a hydrogen atom or a monovalent functional group. PG1-Sp1-R4-Sp2-PG2??(2) In formula (2), R4 represents a divalent group formed by combining five or more and nine or less of alicycles and/or aromatic rings, SP1 and SP2 represent a spacer group, and PG1 and PG2 represents an alkyl group, an alkoxyl group, a cyano group, fluorine or a polymerizable functional group, in which either group is the polymerizable functional group.

Abstract: To provide a polymerizable liquid crystal compound in order to produce a retardation film having excellent front contrast. A polymerizable liquid crystal composition including a compound represented by Formula (1). In Formula (1), for example, W1 is an alkoxycarbonyl group having 1 to 10 carbon atoms, an alkanoyl group having 1 to 10 carbon atoms, or a polymerizable functional group, A1 is independently 1,4-phenylene or naphthalene-2,6-diyl, Z1 is a linking group, m and n are independently an integer of 0 to 7, and satisfy 3?m+n?8, and P1 is a polymerizable functional group.

Abstract: Provided is a polymerizable liquid crystal compound represented by formula (1). An aspect can be exemplified, in which, in formula (1), W1 is hydrogen or a substituent, A1 is 1,4-phenylene, 1,4-cyclohexylene or naphthalene-2,6-diyl, Z1 and Y1 are a connecting group, m and n each are an integer from 0 to 7, in which an expression: 3?m+n?8 holds, Q1 is a spacer, and PG is a polymerizable group.

Abstract: An object is to provide a polymerizable liquid crystal compound, a polymerizable liquid crystal composition containing the compound and liquid crystal polymerization film-kind capable of controlling chromatic dispersion characteristics and having low positive chromatic dispersion characteristics. An aspect can be exemplified in which the polymerizable liquid crystal compound is represented by formula (1): in which, in formula (1), G is a group composed of a quinoline skeleton, an isoquinoline skeleton, a quinoxaline skeleton or a quinazoline skeleton, A1 is 1,4-phenylene or 1,4-cyclohexylene, Z1 is a connecting group, m is an integer from 0 to 3, and R1 is a group containing a polymerizable group.

Abstract: A subject is to provide a polymerizable liquid crystal composition from which an optically anisotropic substance having twist alignment that is excellent in chemical strength (chemical resistance) and has only a small amount of alignment defects can be obtained. A solution is a polymerizable liquid crystal composition containing an optically active compound having a binaphthol moiety, an achiral polymerizable liquid crystal compound and a photopolymerization initiator having oxime ester.

Abstract: To provide an optically anisotropic substance having a negative uniaxial phase difference film and a positive uniaxial phase difference film, and excellent heat resistance and sputtering resistance. The positive uniaxial phase difference film is formed in combination with a bifunctional polymerizable liquid crystal compound, the negative uniaxial phase difference film is formed in combination of the bifunctional polymerizable liquid crystal compound with an optically active compound having a polymerizable binaphthol moiety, and additional thermosetting treatment (postcure) is applied after the negative uniaxial phase difference film is photocured, and when glass transition temperature after the negative uniaxial phase difference film is cured is 85° C. or higher and 115° C. or lower, additional thermosetting treatment temperature is adjusted to 220° C. or higher and 250° C. or lower, and when the glass transition temperature is higher than 115° C.

Abstract: To provide a photosensitive polymer, a phase difference film using the photosensitive polymer, and an optical film using the phase difference film. A solution is a photosensitive polymer having a constitutional unit represented by formula (1): wherein, in formula (1), for example, R1 is hydrogen or methyl; a is 2 or 3; p is an integer from 1 to 12; X1 is —O—, —COO— or —OCO—; b is an integer from 0 to 3; A1 is a divalent group selected from 1,4-phenylene or naphthalene-2,6-diyl, and in the divalent group, at least one of hydrogen may be replaced by fluorine or chlorine; Z1 is a single bond, —COO—, —CH?CH—COO—, —CH2CH2—COO—, —CH2O— or —CONH—; W1 and W2 are hydrogen, fluorine or 1-5C alkyl or alkoxy; Y1 is —O—; and R2 is 1-20C alkyl, and at least one of —CH2— in the alkyl may be replaced by —O—.

Abstract: To provide an optically anisotropic substance having a negative uniaxial phase difference film and a positive uniaxial phase difference film, and excellent heat resistance and sputtering resistance. The positive uniaxial phase difference film is formed in combination with a bifunctional polymerizable liquid crystal compound, the negative uniaxial phase difference film is formed in combination of the bifunctional polymerizable liquid crystal compound with an optically active compound having a polymerizable binaphthol moiety, and additional thermosetting treatment (postcure) is applied after the negative uniaxial phase difference film is photocured, and when glass transition temperature after the negative uniaxial phase difference film is cured is 85° C. or higher and 115° C. or lower, additional thermosetting treatment temperature is adjusted to 220° C. or higher and 250° C. or lower, and when the glass transition temperature is higher than 115° C.

Abstract: A subject is to provide a polymerizable liquid crystal composition from which an optically anisotropic substance having twist alignment that is excellent in chemical strength (chemical resistance) and has only a small amount of alignment defects can be obtained. A solution is a polymerizable liquid crystal composition containing an optically active compound having a binaphthol moiety, an achiral polymerizable liquid crystal compound and a photopolymerization initiator having oxime ester.

Abstract: To provide a photoalignable material that can yield a photoalignable film having a high optical uniformity and no alignment defect, and allows photoalignment with exposure in a short period of time. A photoalignable polymer composition containing a specific photoalignable polymer having a silicone group or a fluorine-substituted alkyl group, and a photoalignable group, and a specific non-photoalignable polymer is manufactured, and the photoalignable film is manufactured by applying the polymer composition onto a base material or the like, drying an applied surface thereon, and irradiating the applied surface with light.

Abstract: To provide a photoalignable material that can yield a photoalignable film having a high optical uniformity and no alignment defect, and allows photoalignment with exposure in a short period of time. A photoalignable polymer composition containing a specific photoalignable polymer having a silicone group or a fluorine-substituted alkyl group, and a photoalignable group, and a specific non-photoalignable polymer is manufactured, and the photoalignable film is manufactured by applying the polymer composition onto a base material or the like, drying an applied surface thereon, and irradiating the applied surface with light.

Abstract: To provide a photoalignable material that can yield a photoalignable film having a high optical uniformity and no alignment defect, and allows photoalignment with exposure in a short period of time. A photoalignable polymer composition containing a specific photoalignable polymer having a silicone group or a fluorine-substituted alkyl group, and a photoalignable group, and a specific non-photoalignable polymer is manufactured, and the photoalignable film is manufactured by applying the polymer composition onto a base material or the like, drying an applied surface thereon, and irradiating the applied surface with light.

Abstract: To provide a photosensitive polymer, a phase difference film using the photosensitive polymer, and an optical film using the phase difference film. A solution is a photosensitive polymer having a constitutional unit represented by formula (1): wherein, in formula (1), for example, R1 is hydrogen or methyl; a is 2 or 3; p is an integer from 1 to 12; X1 is —O—, —COO— or —OCO—; b is an integer from 0 to 3; A1 is a divalent group selected from 1,4-phenylene or naphthalene-2,6-diyl, and in the divalent group, at least one of hydrogen may be replaced by fluorine or chlorine; Z1 is a single bond, —COO—, —CH?CH—COO—, —CH2CH2—COO—, —CH2O— or —CONH—; W1 and W2 are hydrogen, fluorine or 1-5C alkyl or alkoxy; Y1 is —O—; and R2 is 1-20C alkyl, and at least one of —CH2— in the alkyl may be replaced by —O—.