Abstract: A polyamide blend includes a polyamide polymer, a glass based reinforcing filler, and a hydrolysable silane grafted polypropylene. The polyamide blend is useful in appliances, consumer products, electronics, machine components, and automotive parts.

Abstract: The invention provides a composition comprising a polyolefin and a polyorganosiloxane in which at least 50 mole % of the siloxane units are D units as herein defined and which contains at least one unsaturated group, characterized in that the unsaturated group is group of the formula —X—CH?CH—R? (I) or —X—C?C—R? (II), in which X represents a divalent organic linkage having an electron withdrawing effect with respect to the —CH?CH— or —C?C— bond and/or containing an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic unsaturation of —X—CH?CH—R? or with the acetylenic unsaturation of —X—C?C—R? and R? represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the —CH?CH— or —C?C— bond.

Abstract: The invention provides a process for grafting silane or silicone functionality onto a polyolefin, comprising reacting the polyolefin with an unsaturated monomer (A) containing an olefinic —C?C— bond or acetylenic —C?C— bond and a reactive functional group X in the presence of means capable of generating free radical sites in the polyolefin and with an organosilicon compound (B) having a functional group Y which is reactive with the functional group X of the unsaturated monomer (A), characterized in that the unsaturated monomer (A) contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C?C— or acetylenic —C?C— unsaturation of the unsaturated monomer (A).

Abstract: The invention provides a polymer composition comprising a polyolefin or a diene elastomer, and an unsaturated compound (A) containing at least two groups each comprising an olefinic —C?C— bond or acetylenic —C?C— bond, characterized in that each group comprising an olefinic —C?C— bond or acetylenic —C?C— bond in the unsaturated compound (A) contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C?C— or acetylenic —C?C— unsaturation.

Abstract: This invention relates to hydrolysable silanes useful in the modification of elastomers, and as coupling agents for diene elastomer compositions containing a filler. In particular the invention relates to novel hydrolysable silanes containing a piperazine ring and an ether or thioether linkage.

Abstract: This invention relates to a process for modifying a polymeric material having a carbon backbone containing carbon-to-carbon unsaturation by reaction with a hydrolysable silane. The polymeric material can for example be a diene elastomer, and the invention relates to a composition comprising a diene elastomer, a hydrolysable silane and a curing agent for the diene elastomer, and also to the use of a hydrolysable silane as a coupling agent for a diene elastomer composition containing a filler.

Abstract: This invention relates to hydrolysable silanes useful in the modification of elastomers, and as coupling agents for diene elastomer compositions containing a filler. In particular the invention relates to novel hydrolysable silanes containing a piperazine ring and an ether or thioether linkage.

Abstract: The invention relates to a process for grafting hydrolysable silane groups to a polyolefin in which ethylene units, if present, form less than 50% by weight of the total polyolefin. The polyolefin is reacted with an unsaturated silane, having at least one hydrolysable group bonded to Si, or a hydrolysate thereof, in the presence of means capable of generating free radical sites in the polyolefin. The unsaturated silane has the formula R?—CH?CH—Z (I) or R?—C?C—Z (II) in which Z represents an electron-withdrawing moiety substituted by a —SiRaR?(3-a) group wherein R represents a hydrolysable group; R? represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; and R? represents hydrogen or a group having an electron withdrawing or any other activation effect with respect to the —CH?CH— or —C?C— bond.

Abstract: The invention relates to a process for grafting hydrolysable silane groups to a polyolefin, comprising reacting the polyolefin with an unsaturated silane, containing an olefinic —C?C— bond or acetylenic —C?C— bond and having at least one hydrolysable group bonded to Si, or a hydrolysate thereof, in the presence of means capable of generating free radical sites in the polymer. The silane contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C?C— or acetylenic —C?C— unsaturation of the silane. The unsaturated silane may also contains electron-withdrawing moiety with respect to the olefinic —C?C— or acetylenic —C?C— bond. The invention permits to provide a silane-modified polyolefin having a high grafting efficiency while limiting/preventing polymer degradation by chain scission.

Abstract: The invention provides a polymer composition comprising a polyolefin or a diene elastomer, and an unsaturated compound (A) containing at least two groups each comprising an olefinic —C?C— bond or acetylenic —C?C— bond, characterized in that each group comprising an olefinic —C?C— bond or acetylenic —C?C— bond in the unsaturated compound (A) contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C?C— or acetylenic —C?C— unsaturation.

Abstract: The invention provides a process for grafting silicone onto a polyolefin comprising reacting the polyolefin with a silicon compound containing an unsaturated group in the presence of means capable of generating free radical sites in the polyolefin, characterized in that the silicon compound is a branched silicone resin containing at least one group of the formula —X—CH?CH—R? (I) or —X—C?C—R? (II), in which X represents a divalent organic linkage having an electron withdrawing effect with respect to the —CH?CH— or —C?C-bond and/or containing an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic unsaturation of —X—CH?CH—R? or with the acetylenic unsaturation of —X—C?C—R?, X being bonded to the branched silicone resin by a C—Si bond, and R? represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the —CH?CH— or —C?C

Abstract: The invention provides a process for grafting silane or silicone functionality onto a polyolefin, comprising reacting the polyolefin with an unsaturated monomer (A) containing an olefinic —C?C— bond or acetylenic —C?C— bond and a reactive functional group X in the presence of means capable of generating free radical sites in the polyolefin and with an organosilicon compound (B) having a functional group Y which is reactive with the functional group X of the unsaturated monomer (A), characterized in that the unsaturated monomer (A) contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C?C— or acetylenic —C?C— unsaturation of the unsaturated monomer (A).

Abstract: The invention provides a composition comprising a polyolefin and a polyorganosiloxane in which at least 50 mole % of the siloxane units are D units as herein defined and which contains at least one unsaturated group, characterized in that the unsaturated group is group of the formula —X—CH?CH—R? (I) or —X—C?C—R? (II), in which X represents a divalent organic linkage having an electron withdrawing effect with respect to the —CH?CH— or —C?C— bond and/or containing an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic unsaturation of —X—CH?CH—R? or with the acetylenic unsaturation of —X—C?C—R? and R? represents hydrogen or a group having an electron withdrawing effect or any other activation effect with respect to the —CH?CH— or —C?C— bond.

Abstract: The invention relates to a process for grafting hydrolysable silane groups to a polyolefin in which ethylene units, if present, form less than 50% by weight of the total polyolefin. The polyolefin is reacted with an unsaturated silane, having at least one hydrolysable group bonded to Si, or a hydrolysate thereof, in the presence of means capable of generating free radical sites in the polyolefin. The unsaturated silane has the formula R?—CH?CH—Z (I) or R?—C?C—Z (II) in which Z represents an electron-withdrawing moiety substituted by a —SiRaR?(3-a) group wherein R represents a hydrolysable group; R? represents a hydrocarbyl group having 1 to 6 carbon atoms; a has a value in the range 1 to 3 inclusive; and R? represents hydrogen or a group having an electron withdrawing or any other activation effect with respect to the —CH?CH— or —C?C— bond.

Abstract: The invention relates to a process for grafting hydrolysable silane groups to a polyolefin, comprising reacting the polyolefin with an unsaturated silane, containing an olefinic —C?C— bond or acetylenic —C?C— bond and having at least one hydrolysable group bonded to Si, or a hydrolysate thereof, in the presence of means capable of generating free radical sites in the polymer. The silane contains an aromatic ring or a further olefinic double bond or acetylenic unsaturation, the aromatic ring or the further olefinic double bond or acetylenic unsaturation being conjugated with the olefinic —C?C— or acetylenic —C?C— unsaturation of the silane. The unsaturated silane may also contains electron-withdrawing moiety with respect to the olefinic —C?C— or acetylenic —C?C— bond. The invention permits to provide a silane-modified polyolefin having a high grafting efficiency while limiting/preventing polymer degradation by chain scission.