Patents by Inventor Daniel Joseph Tempel
Daniel Joseph Tempel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8206676Abstract: The method described herein provides a method for preparing a chlorinated silane at least one end product comprising SiH3Cl, SiH2Cl2, and combinations thereof in molar yields of 50% or greater with respect to silane in the feed stream. The method described herein therefore provides an end product comprising the one or more chlorinated silanes by contacting reaction mixture comprising silane and hydrogen chloride with a catalyst at a temperature and time sufficient to provide the end product.Type: GrantFiled: April 6, 2010Date of Patent: June 26, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Rajiv K. Agarwal, John Francis Lehmann, Charles Gardner Coe, Daniel Joseph Tempel
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Patent number: 8202446Abstract: A mixture and method for the storage and delivery of a gas are disclosed herein. In one aspect, there is provided a mixture comprising: an ionic liquid comprising an anion and a cation, at least a portion of the gas that is disposed within and reversibly chemically reacted with the ionic liquid, and optionally an unreacted gas. In another aspect, there is provided a method for delivering a gas from a mixture comprising an ionic liquid and one or more gases comprising: reacting at least a portion of the gas with the ionic liquid to provide the mixture comprising a chemically reacted gas and an ionic liquid and separating the chemically reacted gas from the mixture wherein the chemically reacted gas after the separating step has substantially the same chemical identity as the chemically reacted gas prior to the reacting step.Type: GrantFiled: June 29, 2009Date of Patent: June 19, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Daniel Joseph Tempel, Philip Bruce Henderson, Jeffrey Richard Brzozowski, Ronald Martin Pearlstein, Diwakar Garg
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Patent number: 8197914Abstract: The present invention discloses plasma enhanced chemical vapor deposition (PECVD) process for depositing n-type and p-type zinc oxide-based transparent conducting oxides (TCOs) at low temperatures with excellent optical and electrical properties on glass and temperature sensitive materials such as plastics and polymers. Specifically, it discloses PECVD process for depositing n-type ZnO by doping it with B or F and p-type ZnO by doping it with nitrogen excellent optical and electrical properties on glass and temperature sensitive materials such as plastics and polymers for TCO application. The process utilizes a mixture of volatile zinc compound, argon and/or helium as a diluent gas, carbon dioxide as an oxidant, and a dopant or reactant to deposit the desired ZnO-based TCOs.Type: GrantFiled: November 21, 2005Date of Patent: June 12, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Diwakar Garg, Philip Bruce Henderson, Daniel Joseph Tempel, Thomas N. Jackson, Jie Sun
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Publication number: 20110113628Abstract: The method described herein provides a method for preparing a chlorinated silane at least one end product comprising SiH3Cl, SiH2Cl2, and combinations thereof in molar yields of 50% or greater with respect to silane in the feed stream. The method described herein therefore provides an end product comprising the one or more chlorinated silanes by contacting reaction mixture comprising silane and hydrogen chloride with a catalyst at a temperature and time sufficient to provide the end product.Type: ApplicationFiled: April 6, 2010Publication date: May 19, 2011Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Rajiv K. Agarwal, John Francis Lehmann, Charles Gardner Coe, Daniel Joseph Tempel
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Patent number: 7736420Abstract: The invention relates to an improvement in apparatus and process for the formation of a complex of Lewis acidic or Lewis basic gases in a reactive liquid of opposite character and for the breaking (fragmentation) of said complex associated with the recovery of the Lewis gas therefrom. The improvement resides in forming finely divided droplets of reactive liquid and controlling the temperature, pressure and concentration of said Lewis gas of opposite character to provide for (a) the formation of said complex between said gas and reactive liquid or (b) the breaking of said complex and the recovery of the atomized droplets of reactive liquid.Type: GrantFiled: May 19, 2006Date of Patent: June 15, 2010Assignee: Air Products and Chemicals, Inc.Inventors: Wayne Thomas McDermott, Philip Bruce Henderson, Daniel Joseph Tempel, Ronald Martin Pearlstein, James Joseph Hart, Rosaleen Patricia Morris-Oskanian, Diwakar Garg
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Patent number: 7648682Abstract: The invention relates to an improvement in apparatus and process for effecting storage and delivery of a gas. The storage and delivery apparatus is comprised of a storage and dispensing vessel containing a medium capable of storing a gas and permitting delivery of the gas stored in the medium from the vessel, the improvement comprising: (a) a reactive liquid having Lewis acidity or basicity; (b) a gas liquid complex in a reversible reacted state formed under conditions of pressure and temperature by contacting the gas having Lewis acidity with the reactive liquid having Lewis basicity or the gas having Lewis basicity with the reactive liquid having Lewis acidity; (c) a non-reactive wick medium holding and dispersing the reactive liquid and the gas liquid complex therein.Type: GrantFiled: May 3, 2007Date of Patent: January 19, 2010Assignee: Air Products and Chemicals, Inc.Inventors: Wayne Thomas McDermott, Daniel Joseph Tempel, Philip Bruce Henderson, Ronald Martin Pearlstein
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Publication number: 20090272938Abstract: A mixture and method for the storage and delivery of a gas are disclosed herein. In one aspect, there is provided a mixture comprising: an ionic liquid comprising an anion and a cation, at least a portion of the gas that is disposed within and reversibly chemically reacted with the ionic liquid, and optionally an unreacted gas. In another aspect, there is provided a method for delivering a gas from a mixture comprising an ionic liquid and one or more gases comprising: reacting at least a portion of the gas with the ionic liquid to provide the mixture comprising a chemically reacted gas and an ionic liquid and separating the chemically reacted gas from the mixture wherein the chemically reacted gas after the separating step has substantially the same chemical identity as the chemically reacted gas prior to the reacting step.Type: ApplicationFiled: June 29, 2009Publication date: November 5, 2009Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Daniel Joseph Tempel, Philip Bruce Henderson, Jeffrey Richard Brzozowski, Ronald Martin Pearlstein, Diwakar Garg
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Patent number: 7563308Abstract: A mixture and method for the storage and delivery of a gas are disclosed herein. In one aspect, there is provided a mixture comprising: an ionic liquid comprising an anion and a cation, at least a portion of the gas that is disposed within and reversibly chemically reacted with the ionic liquid, and optionally an unreacted gas. In another aspect, there is provided a method for delivering a gas from a mixture comprising an ionic liquid and one or more gases comprising: reacting at least a portion of the gas with the ionic liquid to provide the mixture comprising a chemically reacted gas and an ionic liquid and separating the chemically reacted gas from the mixture wherein the chemically reacted gas after the separating step has substantially the same chemical identity as the chemically reacted gas prior to the reacting step.Type: GrantFiled: August 23, 2005Date of Patent: July 21, 2009Assignee: Air Products and Chemicals, Inc.Inventors: Daniel Joseph Tempel, Philip Bruce Henderson, Jeffrey Richard Brzozowski, Ronald Martin Pearlstein, Diwakar Garg
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Patent number: 7404845Abstract: A mixture and method for the storage and delivery of at least one gas are disclosed herein. In one aspect, there is provided a mixture for the storage and delivery of at least one gas comprising: an ionic liquid comprising an anion and a cation; and at least one gas that is disposed within and is reversibly chemically reacted with the ionic liquid. In another aspect, there is provided a method for delivering at least one gas from a mixture comprising an ionic liquid and at least one gas comprising: reacting the at least one gas and the ionic liquid to provide the mixture and separating the at least one gas from the mixture wherein the at least one gas after the separating step is substantially the same as the at least one gas prior to the reacting step.Type: GrantFiled: September 23, 2004Date of Patent: July 29, 2008Assignee: Air Products and Chemicals, Inc.Inventors: Daniel Joseph Tempel, Philip Bruce Henderson, Jeffrey Richard Brzozowski
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Patent number: 7396381Abstract: The present invention is directed to improvements in storage and delivery systems that allow for rapid fill and delivery of gases reversibly stored in a nonvolatile liquid medium, improvements in delivery and purity of the delivered gas. The low pressure storage and delivery system for gas which comprises: a container having an interior portion containing a reactive Lewis basic or Lewis acidic reactive liquid medium that is reversibly reacted with a gas having opposing Lewis acidity or basicity; a system for transferring energy into or out of the reactive liquid medium; or, a product gas purifier (e.g. a gas/liquid separator); or both.Type: GrantFiled: July 8, 2004Date of Patent: July 8, 2008Assignee: Air Products and Chemicals, Inc.Inventors: David Ross Graham, Daniel Joseph Tempel, Bernard Allen Toseland, Philip Bruce Henderson, James Joseph Hart, John Bruce Appleby, Jeffrey Richard Brzozowski, Pushpinder Singh Puri
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Publication number: 20070287812Abstract: The invention relates to an improvement in apparatus and process for the formation of a complex of Lewis acidic or Lewis basic gases in a reactive liquid of opposite character and for the breaking (fragmentation) of said complex associated with the recovery of the Lewis gas therefrom. The improvement resides in forming finely divided droplets of reactive liquid and controlling the temperature, pressure and concentration of said Lewis gas of opposite character to provide for (a) the formation of said complex between said gas and reactive liquid or (b) the breaking of said complex and the recovery of the atomized droplets of reactive liquid.Type: ApplicationFiled: May 19, 2006Publication date: December 13, 2007Inventors: Wayne Thomas McDermott, Philip Bruce Henderson, Daniel Joseph Tempel, Ronald Martin Pearlstein, James Joseph Hart, Rosaleen Patricia Morris-Oskanian, Diwakar Garg
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Patent number: 7303607Abstract: This invention relates to an improvement in a low-pressure storage and delivery system for gases having Lewis basicity, particularly hazardous specialty gases such as phosphine and arsine, which are utilized in the electronics industry. The improvement resides in storing the gases in a liquid incorporating a reactive compound having Lewis acidity capable of effecting a reversible reaction between a gas having Lewis basicity. The reactive compound comprises a reactive species that is dissolved, suspended, dispersed, or otherwise mixed with a nonvolatile liquid.Type: GrantFiled: June 14, 2004Date of Patent: December 4, 2007Assignee: Air Products and Chemicals, Inc.Inventors: Daniel Joseph Tempel, Philip Bruce Henderson, Jeffrey Richard Brzozowski, Ronald Martin Pearlstein, Thomas Richard Gaffney
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Patent number: 7282084Abstract: This invention relates to an improvement in a low-pressure storage and delivery system for gases having Lewis acidity, particularly hazardous specialty gases such as BF3 and diborane, which are utilized in the electronics industry. The improvement resides in storing the gases in a liquid incorporating a reactive compound having Lewis basicity capable of effecting a reversible reaction between a gas having Lewis acidity. The reactive compound comprises a reactive species that is dissolved, suspended, dispersed, or otherwise mixed with a nonvolatile liquid.Type: GrantFiled: October 15, 2004Date of Patent: October 16, 2007Assignee: Air Products and Chemicals, Inc.Inventors: Daniel Joseph Tempel, Philip Bruce Henderson, Jeffrey Richard Brzozowski, Ronald Martin Pearlstein
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Patent number: 7172646Abstract: This invention relates generally to an improvement in low pressure storage and dispensing systems for the selective storing of gases having Lewis acidity or basicity, and the subsequent dispensing of said gases at pressures, e.g., generally below 5 psig and typically below atmospheric pressure, by modest heating, pressure reduction or both. The improvement resides in storing the gases in a reversibly reacted state within a reactive liquid having opposing Lewis basicity or acidity.Type: GrantFiled: April 15, 2003Date of Patent: February 6, 2007Assignee: Air Products and Chemicals, Inc.Inventors: Daniel Joseph Tempel, Philip Bruce Henderson, Jeffrey Richard Brzozowski
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Publication number: 20050276733Abstract: This invention relates to an improvement in a low-pressure storage and delivery system for gases having Lewis basicity, particularly hazardous specialty gases such as phosphine and arsine, which are utilized in the electronics industry. The improvement resides in storing the gases in a liquid incorporating a reactive compound having Lewis acidity capable of effecting a reversible reaction between a gas having Lewis basicity. The reactive compound comprises a reactive species that is dissolved, suspended, dispersed, or otherwise mixed with a nonvolatile liquid.Type: ApplicationFiled: June 14, 2004Publication date: December 15, 2005Inventors: Daniel Joseph Tempel, Philip Henderson, Jeffrey Brzozowski, Ronald Martin Pearlstein, Thomas Richard Gaffney
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Publication number: 20040206241Abstract: This invention relates generally to an improvement in low pressure storage and dispensing systems for the selective storing of gases having Lewis acidity or basicity, and the subsequent dispensing of said gases at pressures, e.g., generally below 5 psig and typically below atmospheric pressure, by modest heating, pressure reduction or both. The improvement resides in storing the gases in a reversibly reacted state within a reactive liquid having opposing Lewis basicity or acidity.Type: ApplicationFiled: April 15, 2003Publication date: October 21, 2004Inventors: Daniel Joseph Tempel, Philip Bruce Henderson, Jeffrey Richard Brzozowski
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Publication number: 20030171508Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: ApplicationFiled: June 22, 2001Publication date: September 11, 2003Inventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Samuel David Arthur, Jerald Feldman, Elizabeth Forrester McCord, Stephan James McLain, Kristina Ann Kreutzer, Alison Margaret Anne Bennett, Edward Bryan Coughlin, Steven Dale Ittel, Anju Parthasarathy, Daniel Joseph Tempel
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Patent number: 6573353Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: September 12, 2000Date of Patent: June 3, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Elizabeth Forrester McCord, Stephan James McLain, Daniel Joseph Tempel
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Patent number: 6310163Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc.Type: GrantFiled: July 10, 1997Date of Patent: October 30, 2001Assignee: E. I. du Pont de Nemours and CompanyInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Samuel David Arthur, Jerald Feldman, Elizabeth Forrester McCord, Stephan James McLain, Kristina Ann Kreutzer, Alison Margaret Anne Bennett, Edward Bryan Coughlin, Steven Dale Ittel, Anju Parthasarathy, Daniel Joseph Tempel
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Patent number: 6034259Abstract: Disclosed herein are processes for polymerizing ethylene, acyclic olefins, and/or selected cyclic olefins, and optionally selected olefinic esters or carboxylic acids, and other monomers. The polymerizations are catalyzed by selected transition metal compounds, and sometimes other co-catalysts. Since some of the polymerizations exhibit some characteristics of living polymerizations, block copolymers can be readily made. Many of the polymers produced are often novel, particularly in regard to their microstructure, which gives some of them unusual properties. Numerous novel catalysts are disclosed, as well as some novel processes for making them. The polymers made are useful as elastomers, molding resins, in adhesives, etc. Also described herein is the synthesis of linear .alpha.-olefins by the oligomerization of ethylene using as a catalyst system a combination a nickel compound having a selected .alpha.-diimine ligand and a selected Lewis or Bronsted acid, or by contacting selected .alpha.Type: GrantFiled: July 10, 1997Date of Patent: March 7, 2000Assignees: E. I. du Pont de Nemours and Company, University of North Carolina Chapel HillInventors: Maurice S. Brookhart, Lynda Kaye Johnson, Christopher Moore Killian, Samuel David Arthur, Jerald Feldman, Stephan James McLain, Kristina Ann Kreutzer, Alison Margaret Anne Bennett, Edward Bryan Coughlin, Steven Dale Ittel, Anju Parthasarathy, Daniel Joseph Tempel