Abstract: The present invention relates to a polycaprolactone resin irradiated by ionizing radiation in order to adjust gel fraction to 0.01-90%, a polycaprolactone-contained resin composition containing at least any one of other biodegradable resins such as an aliphatic polyester resin and an additive for resins, and an molded article therefrom. The molded article includes a thin-walled molded article such as a film, a bag for garbages, a mulch film for agriculture, a shrink film, a sheet-like molded article, and a thick-walled vessel such as a blister pack, a tape, fiber materials such as fibers, woven fabrics, non-woven fabrics, and materials for filtration, a net, and a foam, etc.

Abstract: Polycaprolactone (PCL) is melted at a temperature of 60.degree. C. or higher and subsequently cooled down to a non-crystallizing temperature and exposed to radiation so that it is crosslinked and a network structure is introduced to impart heat resistance to the PCL. Because of the high degrees of its crosslinking, heat resistance and transparency, the PCL product can be used as a heat-resistant tape or a heat-shrinkable film.