Patents by Inventor David M. Fiscus

David M. Fiscus has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20130289213
    Abstract: This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    Type: Application
    Filed: April 4, 2013
    Publication date: October 31, 2013
    Inventors: Donna J. Crowther, David M. Fiscus
  • Publication number: 20130231451
    Abstract: This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    Type: Application
    Filed: April 4, 2013
    Publication date: September 5, 2013
    Inventors: Donna J. Crowther, David M. Fiscus
  • Patent number: 8507103
    Abstract: This invention relates to blown films produced from copolymer made by a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    Type: Grant
    Filed: April 20, 2012
    Date of Patent: August 13, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Donna J. Crowther, David M. Fiscus
  • Patent number: 8436114
    Abstract: This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    Type: Grant
    Filed: October 18, 2011
    Date of Patent: May 7, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Donna J. Crowther, David M. Fiscus
  • Patent number: 8431661
    Abstract: This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 6 to 25 mole %, prior to use as an activator, where the mole % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the unknown species is the peak is identified in the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    Type: Grant
    Filed: October 21, 2010
    Date of Patent: April 30, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Donna J. Crowther, David M. Fiscus
  • Publication number: 20120200010
    Abstract: This invention relates to blown films produced from copolymer made by a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    Type: Application
    Filed: April 20, 2012
    Publication date: August 9, 2012
    Inventors: Donna J. Crowther, David M. Fiscus
  • Publication number: 20120101242
    Abstract: This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 6 to 25 mole %, prior to use as an activator, where the mole % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the unknown species is the peak is identified in the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    Type: Application
    Filed: October 21, 2010
    Publication date: April 26, 2012
    Inventors: Donna J. Crowther, David M. Fiscus
  • Publication number: 20120101235
    Abstract: This invention relates to a process for polymerizing olefins in which the amount of trimethylaluminum in a methylalumoxane solution is adjusted to be from 1 to 25 mol %, prior to use as an activator, where the mol % trimethylaluminum is determined by 1H NMR of the solution prior to combination with any support. This invention also relates to a process for polymerizing olefins in which the amount of an unknown species present in a methylalumoxane solution is adjusted to be from 0.10 to 0.65 integration units prior to use as an activator, where the amount of the unknown species is determined by the 1H NMR spectra of the solution performed prior to combination with any support. Preferably, the methylalumoxane solution is present in a catalyst system also comprising a metallocene transition metal compound.
    Type: Application
    Filed: October 18, 2011
    Publication date: April 26, 2012
    Inventors: Donna J. CROWTHER, David M. Fiscus
  • Publication number: 20090297810
    Abstract: This invention relates to a polyethylene film having a MD 1% Secant Modulus of 220 MPa or more and an MD Elmendorf Tear of Y g/micron, where Y??0.4515(Dart Drop in g/micron)+33.3 g/microns, wherein the MD Elmendorf tear is at least 11.8 g/micron.
    Type: Application
    Filed: May 30, 2008
    Publication date: December 3, 2009
    Inventors: David M. Fiscus, Danny Van Hoyweghen, X. Christinia Lu, Alan A. Galuska
  • Patent number: 6423420
    Abstract: An oriented multilayer film is provided, the film including in at least one outer layer an ethylene copolymer having a density of 0.900-0.935 g/cm3 and a CDBI of 50-95% the outer layer is in contact with a polypropylene core layer, and the film is made by coextrusion of the ethylene copolymer and the polypropylene layer and subsequent orientation. The coextruded layers can be uniaxially oriented or biaxially oriented without difficulties caused by presence of low molecular weight amorphous polymer fractions inherently present in traditional Ziegler-Natta linear low density polyethylene. The optical properties of oriented polypropylene films can be retained, while the sealing temperature is lowered and the heat seal strength and the hot tack performance properties are improved.
    Type: Grant
    Filed: August 20, 1999
    Date of Patent: July 23, 2002
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Patrick Brant, David M. Fiscus, Achiel Josephus Maria Van Loon