Abstract: A soil and groundwater decontamination system (10) and associated process are provided for soil and groundwater remediation. The system (10) and process utilizes both a physical or chemical reaction with the contaminants in a contaminated subsurface zone and extraction of the reaction end products and any remaining contaminants from the contaminated subsurface zone (100). In architecture, the soil and groundwater decontamination system (10) comprises an chemical product (12) that is introduced into an injection well (18). The injection well (18) is disposed into a passage provided in or adjacent to the contaminated subsurface zone (100) and allows the introduction of the chemical product (12) (and catalyst (24) if necessary) into the contaminated subsurface zone (100). The chemical product (12) reacts (physically or chemically) with contamination in the soil and groundwater and creates a reaction end product.