Abstract: A method of preparation of olefin-functionalized fluorosilicones, the properties of which can be optimized, for example, as release liners for silicone adhesives, the method including subjecting a mixture of a hydride-functional polysiloxane, a first compound having a terminal monosubstituted olefin, and a second compound having both a terminal monosubstituted olefin and an internal disubstituted olefin to hydrosilylation conditions to provide a hydrosilylated fluorosilicone with internal olefins and reacting the hydrosilylated fluorosilicone with internal olefins with ethylene in the presence of an olefin metathesis catalyst to provide the olefin- functionalized fluorosilicone. Articles including such olefin-functionalized fluorosilicones.

Abstract: An orthodontic article is described comprising the reaction product of free-radically polymerizable resin comprising at least one dicarbonyl polymer comprising polymerized units of oxamate, oxalate, or a combination thereof and at least two free-radically polymerizable groups. Also described are dicarbonyl polymers, methods of making dicarbonyl polymers and method of use for the described polymerizable resin are also described.

Abstract: Silicone polyoxamide and silicone polyoxamide-hydrazide copolymers comprise at least two repeating units of formula (I). In this formula, each R1 is independently an alkyl, haloalkyl, aralkyl, alkenyl, aryl, or aryl substituted with an alkyl, alkoxy, or halo; each Y is independently an alkylene, aralkylene, or a combination thereof; each G is independently a bond or a divalent residue equal to a diamine of formula R3HN—G—HR3 minus the two —NHR3 groups; each R3 is independently hydrogen or alkyl or R3 taken together with G and with the nitrogen to which they are both attached form a heterocyclic group; each n is independently an integer of 0 to 300; each p is independently an integer of 1 to 25, and the average of p is 1.3 or greater; and each q is independently an integer of 1 to 2, and the average of q is no greater than 1.05.

Abstract: Silicone polyoxamide and silicone polyoxamide-hydrazide copolymers comprise at least two repeating units of formula (I). In this formula, each R1 is independently an alkyl, haloalkyl, aralkyl, alkenyl, aryl, or aryl substituted with an alkyl, alkoxy, or halo; each Y is independently an alkylene, aralkylene, or a combination thereof; each G is independently a bond or a divalent residue equal to a diamine of formula R3HN-G-NHR3 minus the two —NHR3 groups; each R3 is independently hydrogen or alkyl or R3 taken together with G and with the nitrogen to which they are both attached form a heterocyclic group; each n is independently an integer of 0 to 300; each p is independently an integer of 1 to 25, and the average of p is 1.3 or greater; and each q is independently an integer of 1 to 2, and the average of q is no greater than 1.05.

Abstract: Hollow fiber membranes, membrane contactors, and related production and use methods. The asymmetric hollow fiber membranes include a porous substrate having a multiplicity of pores and including at least one semi-crystalline thermoplastic polyolefin (co)polymer. A skin layer including at least one polydiorganosiloxane polyoxamide copolymer overlays the porous substrate. The skin layer is less porous than the porous substrate and forms an outer surface of the asymmetric hollow fiber membrane, while the porous substrate forms an inner surface of the hollow fiber membrane. The skin layer is preferably nonporous.

Abstract: Film forming gel compositions, useful in creating conformable and flexible gel bandages, can be formulate from a film-forming polymer, a tackifier, and a volatile solvent. The film forming gels can also include antiseptics, cationic polymer coagulants, fillers, and other additives. The gel compositions form relatively thick films when dried on tissue, and can exhibit enhanced breathability to promote wound healing.

Abstract: A core-sheath filament having a pressure-sensitive adhesive core and a non-tacky thermoplastic sheath that surrounds the core is provided. The pressure-sensitive adhesive core includes a) a silicone-containing block copolymer having multiple poly-diorganosiloxane segments plus b) a silicone tackifying resin. Additionally, methods of making the core-sheath filament and methods of using the core-sheath filament to print a pressure-sensitive adhesive are described.

Abstract: The present invention is an assembly layer for a flexible device. Within a temperature range of between about ?30° C. to about 90° C., the assembly layer has a shear storage modulus at a frequency of 1 Hz that does not exceed about 2 MPa, a shear creep compliance (J) of at least about 6×10?6 1/Pa measured at 5 seconds with an applied shear stress between about 50 kPa and about 500 kPa, and a strain recovery of at least about 50% at at least one point of applied shear stress within the range of about 5 kPa to about 500 kPa within about 1 minute after removing the applied shear stress. The assembly layer includes at least one of a polyisoprene, a polybutadiene, an olefin block copolymer, a polyisobutylene, and high alkyl polyolefin.

Abstract: The present disclosure provides a polymeric membrane. The polymeric membrane includes a first thermoplastic elastomer layer. The thermoplastic elastomer is a styrenic thermoplastic. The polymeric membrane can further include an optional second thermoplastic elastomer layer in contact with the first polyolefin layer.

Abstract: The present disclosure provides a polymeric membrane. The polymeric membrane includes a first thermoplastic elastomer layer that comprises a styrenic thermoplastic. The thermoplastic elastomer layer has a foam structure. The polymeric membrane can further include an optional second thermoplastic elastomer layer in contact with the first polyolefin layer.

Abstract: The present disclosure provides a polymeric membrane. The polymeric membrane includes a first thermoplastic elastomer layer. The thermoplastic elastomer layer includes a filler component that is at least about 30 wt % of the thermoplastic elastomer layer. The polymeric membrane can further include an optional second thermoplastic elastomer layer in contact with the first polyolefin layer.

Abstract: Presently describes are articles, such as liquid reservoirs, comprising a liquid repellent surface. The liquid repellent surface comprises a surface layer comprising a silane or siloxane material, wherein the liquid repellent surface is not a lubricant impregnated surface. In one embodiment, the liquid repellent surface (e.g. layer) comprise a silicone melt additive and a thermoplastic polymeric material component. In some embodiments, the article (e.g. liquid reservoir) comprise a thermoplastic polymeric material.

Abstract: The disclosure provides partially fluorinated piperazine carboxamide compounds having terminal fluoroaliphatic groups and polysiloxane groups. This invention also relates to polymer compositions comprising the fluorochemical composition and shaped articles made from the thermoplastic composition. See Formula (I).

Abstract: Segmented silicone polyamide block copolymers that comprise dimer acid residues and articles containing the same.

Abstract: The present invention is an assembly layer for a flexible device. Within a temperature range of between about ?30° C. to about 90° C., the assembly layer has a shear storage modulus at a frequency of 1 Hz that does not exceed about 2 MPa, a shear creep compliance (J) of at least about 6×10?6 1 /Pa measured at 5 seconds with an applied shear stress between about 50 kPa and about 500 kPa, and a strain recovery of at least about 50% at at least one point of applied shear stress within the range of about 5 kPa to about 500 kPa within about 1 minute after removing the applied shear stress. The assembly layer includes at least one of a polyisoprene, a polybutadiene, an olefin block copolymer, a polyisobutylene, and high alkyl polyolefin.

Abstract: The disclosure provides partially fluorinated piperazine carboxamide compounds having terminal fluoroaliphatic groups and polysiloxane groups. This invention also relates to polymer compositions comprising the fluorochemical composition and shaped articles made from the thermoplastic composition. See Formula (I).

Abstract: The present invention is an assembly layer for a flexible device. Within a temperature range of between about ?30° C. to about 90° C., the assembly layer has a shear storage modulus at a frequency of 1 Hz that does not exceed about 2 MPa, a shear creep compliance (J) of at least about 6×10?6 l/Pa measured at 5 seconds with an applied shear stress between about 50 kPa and about 500 kPa, and a strain recovery of at least about 50% at at least one point of applied shear stress within the range of about 5 kPa to about 500 kPa within about 1 minute after removing the applied shear stress.

Abstract: Film forming gel compositions, useful in creating conformable and flexible gel bandages, can be formulate from a film forming polymer, a tackifier, and a volatile solvent. The film forming gels can also include antiseptics, cationic polymer coagulants, fillers, and other additives. The gel compositions form relatively thick films when dried on tissue, and can exhibit enhanced breathability to promote wound healing.

Abstract: The present invention provides a novel partially fluorinated piperazine carboxamide compound, and polymer composition comprising the fluorinated compound and a thermoplastic or thermoset polymer. The polymer composition is useful in preparing shaped articles such as fibers and films which have desirable oil- and water repellency properties.

Abstract: Segmented silicone polyamide block copolymers that comprise dimer acid residues and articles containing the same.