Abstract: A catalyst layer including an electrocatalyst and an oxygen evolution catalyst, wherein the oxygen evolution catalyst includes a crystalline metal oxide including: (i) one of more first metals selected from the group consisting of yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, magnesium, calcium, strontium, barium, sodium, potassium, indium, thallium, tin, lead, antimony and bismuth; (ii) one or more second metals selected from the group consisting of Ru, Ir, Os and Rh; and (iii) oxygen characterised in that: (a) the atomic ratio of first metal(s):second metal(s) is from 1:1.5 to 1.5:1 (b) the atomic ratio of (first metal(s)+second metal(s)):oxygen is from 1:1 to 1:2 is disclosed.

Abstract: A platinum alloy catalyst PtXY, wherein X is a transition metal (other than platinum, palladium or iridium) and Y is a transition metal (other than platinum, palladium or iridium) which is less leachable than X in an acidic environment, has an atomic percentage in the alloy of platinum is from 20.5-40 at %, of X is from 40.5-78.5 at % X and of Y is from 1-19.5 at %.

Abstract: An MEA comprising: (i) a central first conductive gas diffusion substrate having a first face and a second face; (ii) first and second catalyst layers each having a first and second face and wherein the first face of the first catalyst layer is in contact with the first face of the gas diffusion substrate and the first face of the second catalyst layer is in contact with the second face of the gas diffusion substrate; (iii) first and second electrolyte layers each having a first and second face and wherein the first face of the first electrolyte layer is in contact with the second face of the first catalyst layer and the first face of the second electrolyte layer is in contact with the second face of the second catalyst layer; (iv) third and fourth catalyst layers each having a first and second face and wherein the first face of the third catalyst layer is in contact with the second face of the first electrolyte layer and the first face of the fourth catalyst layer is in contact with the second face of the se

Abstract: A catalyst layer includes (i) an electrocatalyst, and (ii) a water electrolysis catalyst, iridium or iridium oxide and one or more metals M or an oxide thereof, wherein M is selected from transition metals and/or Sn, with the exception of ruthenium. Such a catalyst layer has utility in fuel cells that experience high electrochemical potentials.

Abstract: A platinum alloy catalyst PtX, wherein the atomic percent of platinum in the bulk alloy is from 5 to 50 at %, the remaining being X, characterised in that the atomic percent of platinum at the surface of the alloy is from 10 to 80 at %, the remainder being X, provided that the at % of platinum at the surface of the alloy is at least 25% greater than the at % of platinum in the bulk alloy is disclosed.

Abstract: A platinum alloy catalyst PtXY, wherein X is nickel, cobalt, chromium, copper, titanium or manganese and Y is tantalum or niobium, characterised in that in the alloy the atomic percentage of platinum is 46-75 at %, of X is 1-49 at % and of Y is 1-35 at %; provided that the alloy is not 66 at % Pt20 at % Cr14 at % Ta or 50 at % Pt, 25 at % Co, 25 at % Ta is disclosed. The catalyst has particular use as an oxygen reduction catalyst in fuel cells, and in particular in phosphoric acid fuel cells.

Abstract: An electrocatalyst, suitable for use in a fuel cell, comprises an alloy having a single crystalline phase, wherein the alloy consists of 5-95 at % palladium, 5-95 at % ruthenium and less than 10 at % of other metals, provided that the alloy does not consist of 50 at % palladium and 50 at % ruthenium.

Abstract: A platinum alloy catalyst can be used as a fuel cell catalyst. The platinum alloy is a PtAuX alloy wherein X is one or more metals chosen from the group consisting of transition metals, and wherein the alloy contains 40-97% Pt, 1-40% Au and 2-20% X. Electrodes, catalysed membranes and membrane electrode assemblies comprising the catalyst are also disclosed.

Abstract: An anode structure for incorporation into a fuel cell includes a first region having one or more electrocatalysts, in which the first region is adjacent to the fuel inlet when the anode structure is incorporated into a fuel cell, and a second region having one or more electrocatalysts, in which the second region is adjacent to the fuel outlet when the anode structure is incorporated into a fuel cell. The first region is better at promoting the electrochemical oxidation of carbon monoxide than the second region.

Abstract: A platinum alloy catalyst PtX, wherein the atomic percent of platinum in the bulk alloy is from 5 to 50 at %, the remaining being X, characterised in that the atomic percent of platinum at the surface of the alloy is from 10 to 80 at %, the remainder being X, provided that the at % of platinum at the surface of the alloy is at least 25% greater than the at % of platinum in the bulk alloy is disclosed.

Abstract: A compound of formula (Na0.33A0.66)2B2O7-? wherein A is one or more metals chosen from the lanthanide metals; B is one or more metals chosen from Ti, Sn, Ge, Ru, Mn, Ir, Os and Pb; and ? is a number in the range 0-1 is disclosed. Water gas shift catalysts comprising precious metals such as gold dispersed on the (Na0.33A0.66)2B2O7-? compound are also disclosed.

Abstract: An electrocatalyst, suitable for use in a fuel cell, comprises an alloy having a single crystalline phase, wherein the alloy consists of 5-95 at % palladium, 5-95 at % ruthenium and less than 10 at % of other metals, provided that the alloy does not consist of 50 at % palladium and 50 at % ruthenium.

Abstract: An electrically conducting gas diffusion substrate, capable of removing oxidisable impurities from an impure gas stream, which comprises an electrically conducting porous structure and a first catalytic component, wherein the first catalytic component comprises a first catalyst supported on an electrically non-conducting support is disclosed. In addition, an electrode, a membrane electrode assembly and a fuel cell each comprising said electrically conducting gas diffusion substrate is disclosed.

Abstract: An ion-conducting membrane comprising a polymer component and a macrocyclic compound, wherein the macro-cyclic compound is functionalised with one or more ion-conducting groups is disclosed. The membrane is suitable for use in a fuel cell.

Abstract: An MEA comprising: (i) a central first conductive gas diffusion substrate having a first face and a second face; (ii) first and second catalyst layers each having a first and second face and wherein the first face of the first catalyst layer is in contact with the first face of the gas diffusion substrate and the first face of the second catalyst layer is in contact with the second face of the gas diffusion substrate; (iii) first and second electrolyte layers each having a first and second face and wherein the first face of the first electrolyte layer is in contact with the second face of the first catalyst layer and the first face of the second electrolyte layer is in contact with the second face of the second catalyst layer; (iv) third and fourth catalyst layers each having a first and second face and wherein the first face of the third catalyst layer is in contact with the second face of the first electrolyte layer and the first face of the fourth catalyst layer is in contact with the second face of the se

Abstract: A platinum alloy catalyst can be used as a fuel cell catalyst. The platinum alloy is a PtAuX alloy wherein X is one or more metals chosen from the group consisting of transition metals, and wherein the alloy contains 40-97% Pt, 1-40% Au and 2-20% X. Electrodes, catalysed membranes and membrane electrode assemblies comprising the catalyst are also disclosed.

Abstract: An electrically conducting gas diffusion substrate, capable of removing oxidisable impurities from an impure gas stream, which comprises an electrically conducting porous structure and a first catalytic component, wherein the first catalytic component comprises a first catalyst supported on an electrically non-conducting support is disclosed. In addition, an electrode, a membrane electrode assembly and a fuel cell each comprising said electrically conducting gas diffusion substrate is disclosed.

Abstract: A three-way catalyst (TWC) composition comprises a manganese-containing oxygen storage component (OSC) and at least one optionally doped alumina wherein where the at least one alumina is gamma-alumina it is doped with at least one of a rare earth metal, silicon, germanium, phosphorus, arsenic, calcium, strontium or barium.

Abstract: An electrically conducting gas diffusion substrate, capable of removing oxidizable impurities from an impure gas stream, which comprises an electrically conducting porous structure and a first catalytic component, wherein the first catalytic component comprises a first catalyst supported on an electrically non-conducting support is disclosed. In addition, an electrode, a membrane electrode assembly and a fuel cell each comprising said electrically conducting gas diffusion substrate is disclosed.

Abstract: A sol includes metal oxide nanoparticles and stabiliser ions dispersed in an aqueous liquid. The nanoparticles include a metal selected from the group of platinum, palladium, rhodium, iridium, ruthenium and osmium and the molar ratio of metal: stabiliser ions is at least 0.7. A method of preparing supported catalyst materials includes contacting the sols with support materials.