Abstract: A 3D printing apparatus can include a base composite material channel configured to pass a base composite material therethrough, a fiber strand channel configured to pass a fiber strand therethrough, and a fiber feeding component configured to feed the fiber strand through the fiber channel. The fiber strand can be separate from the base composite material before entering the 3D printing apparatus, and the fiber feeding component can facilitate combining of the fiber strand with the base composite material to form a layer of a 3D printed building component with the fiber strand within the base composite material. An impregnation material channel may be included to pass an impregnation liquid or material to impregnate the fiber strand while the fiber strand is within the 3D printing apparatus.

Abstract: A photopolymerized prepolymer manufacturing system can create material suitable for 3D printing buildings or building components. The system can include a conveyor, a prepolymerization chamber, and one or more processors. The prepolymerization chamber can have multiple prepolymerization stations arranged in sequence and can convert untreated material into photopolymerized prepolymer material as the conveyor moves the prepolymer past the prepolymerization chamber. The processor(s) can control operations of the conveyor, the prepolymerization chamber, or both, to alter operations in response to a detected system event. Each polymerization station can include a light source, such as an LED array, that irradiates material. Each light source can be in a lid of the prepolymerization station. When operation of one polymerization station is halted, such as for maintenance, then the system can increase the light source intensity of the remaining polymerization stations, slow the conveyor speed, or both.

Abstract: An optical curing system for a large scale 3D printing system may include a light source housing, a light source, a mounting bracket, a light beam focusing subsystem, and a power source. The light source may be coupled to the light source housing. The mounting bracket may secure the light source housing to a rotary system on the 3D printer. The light beam focusing subsystem is attached to the light source housing. The power source may power the light source during its operation.

Abstract: An optical curing system for a large scale 3D printing system may include a light source housing, a light source, a mounting bracket, a light beam focusing subsystem, and a power source. The light source may be coupled to the light source housing. The mounting bracket may secure the light source housing to a rotary system on the 3D printer. The light beam focusing subsystem is attached to the light source housing. The power source may power the light source during its operation.

Abstract: A formulation for a photopolymer composite material for a 3D printing system includes an acrylate oligomer, an inorganic hydrate, a reinforcing filler, and an ultraviolet (UV) initiator. In the formulation the acrylate oligomer may be found in the range between about 20.0-60.0 w % of the formulation. The inorganic hydrate may be found in the range between about 20.0-50.0 w % of the formulation. The reinforcing filler may be found in the range between about 5.0-60.0 w % of the formulation, and the UV initiator may be found in the range between about 0.001-0.5 w % of the formulation. A method of generating a formulation of a photopolymer composite material for use in a 3D printing system includes using an acrylate oligomer, an inorganic hydrate, a reinforcing filler, and an ultraviolet (UV) initiator.

Abstract: A system for obtaining a photopolymerized prepolymer for use as a component of a material suitable for manufacturing buildings or building components by 3D printing processes. The system contains a flexible closed loop conveyor stretched between a precursor loading station and a prepolymerization material receiver from which the product is unloaded to a construction 3D printing machine. The conveyor carries a plurality of flexible trays capable of looping around the pulleys of the closed loop conveyor. The trays are shallow troughs that have open tops and carry dosed portions of the precursor, which is photopolymerized on its way from the loading station to the unloading station by sequentially passing under light sources of two photopolymerization stations. When the trays pass through the unloading position, they are turned upside-down and allow the precured material to fall into a receiver.

Abstract: A 3D printing apparatus can include a base composite material channel configured to pass a base composite material therethrough, a fiber strand channel configured to pass a fiber strand therethrough, and a fiber feeding component configured to feed the fiber strand through the fiber channel. The fiber strand can be separate from the base composite material before entering the 3D printing apparatus, and the fiber feeding component can facilitate combining of the fiber strand with the base composite material to form a layer of a 3D printed building component with the fiber strand within the base composite material. An impregnation material channel may be included to pass an impregnation liquid or material to impregnate the fiber strand while the fiber strand is within the 3D printing apparatus.

Abstract: A formulation for a photopolymer composite material for a 3D printing system includes an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator. In the formulation the acrylate monomer or the acrylate oligomer may be between about 10.0-30.0 w % of the formulation. The thermal initiator may be between about 0.001-0.05 w %, the co-initiator may be between about 0.001-0.05 w %, and the UV initiator may be between about 0.001-0.2 w % of the formulation. A method of generating a formulation of a photopolymer composite material for use in a 3D printing system includes using an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator.

Abstract: A formulation for a photopolymer composite material for a 3D printing system includes an acrylate oligomer, an inorganic hydrate, a reinforcing filler, and an ultraviolet (UV) initiator. In the formulation the acrylate oligomer may be found in the range between about 20.0-60.0 w % of the formulation. The inorganic hydrate may be found in the range between about 20.0-50.0 w % of the formulation. The reinforcing filler may be found in the range between about 5.0-60.0 w % of the formulation, and the UV initiator may be found in the range between about 0.001-0.5 w % of the formulation. A method of generating a formulation of a photopolymer composite material for use in a 3D printing system includes using an acrylate oligomer, an inorganic hydrate, a reinforcing filler, and an ultraviolet (UV) initiator.

Abstract: A formulation for a photopolymer composite material for a 3D printing system includes an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator. In the formulation the acrylate monomer or the acrylate oligomer may be between about 10.0-30.0 w % of the formulation. The thermal initiator may be between about 0.001-0.05 w %, the co-initiator may be between about 0.001-0.05 w %, and the UV initiator may be between about 0.001-0.2 w % of the formulation. A method of generating a formulation of a photopolymer composite material for use in a 3D printing system includes using an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator.

Abstract: A formulation for a photopolymer composite material for a 3D printing system includes an acrylate oligomer, an inorganic hydrate, a reinforcing filler, and an ultraviolet (UV) initiator. In the formulation the acrylate oligomer may be found in the range between about 20.0-60.0 w % of the formulation. The inorganic hydrate may be found in the range between about 20.0-50.0 w % of the formulation. The reinforcing filler may be found in the range between about 5.0-60.0 w % of the formulation, and the UV initiator may be found in the range between about 0.001-0.5 w % of the formulation. A method of generating a formulation of a photopolymer composite material for use in a 3D printing system includes using an acrylate oligomer, an inorganic hydrate, a reinforcing filler, and an ultraviolet (UV) initiator.

Abstract: An optical curing system for a large scale 3D printing system may include a light source housing, a light source, a mounting bracket, a light beam focusing subsystem, and a power source. The light source may be coupled to the light source housing. The mounting bracket may secure the light source housing to a rotary system on the 3D printer. The light beam focusing subsystem is attached to the light source housing. The power source may power the light source during its operation.

Abstract: A photopolymerized prepolymer manufacturing system can create material suitable for 3D printing buildings or building components. The system can include a conveyor, a prepolymerization chamber, and one or more processors. The prepolymerization chamber can have multiple prepolymerization stations arranged in sequence and can convert untreated material into photopolymerized prepolymer material as the conveyor moves the prepolymer past the prepolymerization chamber. The processor(s) can control operations of the conveyor, the prepolymerization chamber, or both, to alter operations in response to a detected system event. Each polymerization station can include a light source, such as an LED array, that irradiates material. Each light source can be in a lid of the prepolymerization station. When operation of one polymerization station is halted, such as for maintenance, then the system can increase the light source intensity of the remaining polymerization stations, slow the conveyor speed, or both.

Abstract: A system for obtaining a photopolymerized prepolymer for use as a component of a material suitable for manufacturing buildings or building components by 3D printing processes. The system contains a flexible closed loop conveyor stretched between a precursor loading station and a prepolymerization material receiver from which the product is unloaded to a construction 3D printing machine. The conveyor carries a plurality of flexible trays capable of looping around the pulleys of the dosed loop conveyor. The trays are shallow troughs that have open tops and carry dosed portions of the precursor, which is photopolymerized on its way from the loading station to the unloading station by sequentially passing under light sources of two photopolymerization stations. When the trays pass through the unloading position, they are turned upside-down and allow the precured material to fall into a receiver.

Abstract: A formulation for a photopolymer composite material for a 3D printing system includes an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator. In the formulation the acrylate monomer or the acrylate oligomer may be between about 10.0-30.0 w % of the formulation. The thermal initiator may be between about 0.001-0.05 w %, the co-initiator may be between about 0.001-0.05 w %, and the UV initiator may be between about 0.001-0.2 w % of the formulation. A method of generating a formulation of a photopolymer composite material for use in a 3D printing system includes using an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator.

Abstract: A formulation for a photopolymer composite material for a 3D printing system includes an acrylate oligomer, an inorganic hydrate, a reinforcing filler, and an ultraviolet (UV) initiator. In the formulation the acrylate oligomer may be found in the range between about 20.0-60.0 w % of the formulation. The inorganic hydrate may be found in the range between about 20.0-50.0 w % of the formulation. The reinforcing filler may be found in the range between about 5.0-60.0 w % of the formulation, and the UV initiator may be found in the range between about 0.001-0.5 w % of the formulation. A method of generating a formulation of a photopolymer composite material for use in a 3D printing system includes using an acrylate oligomer, an inorganic hydrate, a reinforcing filler, and an ultraviolet (UV) initiator.

Abstract: The present invention relates to polymer compositions suitable for 3D printing. The composition comprises 60 to 80 mass % of oligoester acrylate; 10 to 30 mass % of a liquid polyethylene glycol; 7 to 9 mass % of a non-liquid polyethylene glycol; and 0.1 to 1 mass % of a system of photopolymerization initiators. A distinguishing feature of the composition is that after being extruded at an environment temperature of 22° C. with the extrusion rate of 2.5 to 3.5 cm/sec through a nozzle of a hand-held 3D printing device having an output orifice with a diameter in the range of 0.6 to 1.5 mm and after being irradiated after extrusion with a light having a wavelength in the range of 390 to 410 nm by LEDs having a total power of 2 Wt, the composition maintained its shape without a support.

Abstract: Provided is a method of 3D printing with the use of a heater-free, hand-held 3D printing device such as a 3D printing pen. The method consists of adjusting the extrusion feed rate of the substance through the orifice with the use of a substance feed mechanism to provide curing conditions at which the extruded substance maintains a shape-sustaining state; extruding the substance; and curing the extruded substance to the shape-sustaining state by irradiating the extruded substance outside the device with light-radiation elements such as LEDs. The feed rate of the extrusion is carried out once, experimentally, before multiple practical use of the heater-free 3D printing device. The extrudable substance is a photopolymerizable polymer composition that has kinematic viscosity in the range of 7.00 to 10.00 MM2/C when measured at room temperature by the capillarity method.

Abstract: Provided is a method of 3D printing with the use of a heater-free, hand-held 3D printing device such as a 3D printing pen. The method consists of adjusting the extrusion feed rate of the substance through the orifice with the use of a substance feed mechanism to provide curing conditions at which the extruded substance maintains a shape-sustaining state; extruding the substance; and curing the extruded substance to the shape-sustaining state by irradiating the extruded substance outside the device with light-radiation elements such as LEDs. The feed rate of the extrusion is carried out once, experimentally, before multiple practical use of the heater-free 3D printing device. The extrudable substance is a photopolymerizable polymer composition that has kinematic viscosity in the range of 7.00 to 10.00 MM2/C when measured at room temperature by the capillarity method.

Abstract: The present invention relates to polymer compositions suitable for 3D printing. The composition comprises 60 to 80 mass % of oligoester acrylate; 10 to 30 mass % of a liquid polyethylene glycol; 7 to 9 mass % of a non-liquid polyethylene glycol; and 0.1 to 1 mass % of a system of photopolymerization initiators. A distinguishing feature of the composition is that after being extruded at an environment temperature of 22° C. with the extrusion rate of 2.5 to 3.5 cm/sec through a nozzle of a hand-held 3D printing device having an output orifice with a diameter in the range of 0.6 to 1.5 mm and after being irradiated after extrusion with a light having a wavelength in the range of 390 to 410 nm by LEDs having a total power of 2 Wt, the composition maintained its shape without a support.