Abstract: Provided herein are copolymers that comprise copolymerized residues of a perfluorotrivinyltriazine monomer of Formula 1. Preferred Rf groups include, without limitation, —(CF2)n— (n=1-6); —(CF2)m—[OCF(CF3)CF2]p— (m=1-4, p=1-4); and —[(CF(CF3)—O)x—(CF2)k]— (x=1-3, k=1-5). Preferred comonomers for copolymerization with the perfluorotrivinyltriazine monomer (1) include, without limitation, tetrafluoroethylene (TFE); vinylidene fluoride (VF2); hexafluoropropylene (HFP); vinyl fluoride (VF); EVE; PSEPVE; perfluoro-(long chain vinyl ethers); E; P; PFBE; PEVE; EVE-OH; EVE-P; PDD; and the cure-site monomers BTFB, ITFB, 8-CNVE, 8-SAVE, and the like. Also provided are methods of synthesizing the copolymers and articles comprising the copolymers.

Abstract: Provided herein are copolymers that comprise copolymerized residues of a perfluorotrivinyltriazine monomer of Formula 1. Preferred Rf groups include, without limitation, —(CF2)n— (n=1-6); —(CF2)m—[OCF(CF3)CF2]p— (m=1-4, p=1-4); and —[(CF(CF3)—O)x—(CF2)k]— (x=1-3, k=1-5). Preferred comonomers for copolymerization with the perfluorotrivinyltriazine monomer (1) include, without limitation, tetrafluoroethylene (TFE); vinylidene fluoride (VF2); hexafluoropropylene (HFP); vinyl fluoride (VF); EVE; PSEPVE; perfluoro-(long chain vinyl ethers); E; P; PFBE; PEVE; EVE-OH; EVE-P; PDD; and the cure-site monomers BTFB, ITFB, 8-CNVE, 8-SAVE, and the like. Also provided are methods of synthesizing the copolymers and articles comprising the copolymers.

Abstract: A printable substrate transfer device for a printing machine which includes a platen that has openings therein in fluid communication with a vacuum source. A transport belt is movable over the platen in a process direction. The transport belt allows air to pass there through. A hold down plate is disposed above the transport belt. A stationary porous vacuum substrate is disposed between the hold down plate and the transport belt. The vacuum substrate and transport belt form a path there between through which a printable substrate travels. The hold down plate exerts a force toward the transport belt upon operation of vacuum passing through the platen. The vacuum substrate limits the negative pressure between the hold down plate and the transport belt, such that a force exerted by the hold down plate onto the substrate is limited.

Abstract: A printable substrate transfer device for a printing machine which includes a platen that has openings therein in fluid communication with a vacuum source. A transport belt is movable over the platen in a process direction. The transport belt allows air to pass there through. A hold down plate is disposed above the transport belt. A stationary porous vacuum substrate is disposed between the hold down plate and the transport belt. The vacuum substrate and transport belt form a path there between through which a printable substrate travels. The hold down plate exerts a force toward the transport belt upon operation of vacuum passing through the platen. The vacuum substrate limits the negative pressure between the hold down plate and the transport belt, such that a force exerted by the hold down plate onto the substrate is limited.

Abstract: This invention pertains to a novel fluoropolymer characterized by a dichloroamino-functionalized perfluoroether pendant group that terminates in —CF2NCl2. The polymer so formed is crosslinkable and useful for the preparation of shaped articles and photo-imaged coatings. The novel fluoropolymer can be thermally treated to form crosslinked fluoropolymers with highly stable perfluoroalkylene crosslinks. The novel fluoropolymer is conveniently prepared by treating a cyano-functionalized fluoropolymer with Cl—F.

Abstract: This invention pertains to a novel fluoropolymer characterized by a dichloroamino-functionalized perfluoroether pendant group that terminates in —CF2NCl2. The polymer so formed is crosslinkable and useful for the preparation of shaped articles and photo-imaged coatings. The novel fluoropolymer can be thermally treated to form crosslinked fluoropolymers with highly stable perfluoroalkylene crosslinks. The novel fluoropolymer is conveniently prepared by treating a cyano-functionalized fluoropolymer with Cl—F.

Abstract: Disclosed herein is a curable composition comprising a polyhydroxy curable fluoroelastomer, a polyhydroxy curative, a cure accelerator and an unsaturated metal compound process aid comprising a siloxane having at least one vinyl or allyl group bonded to a silicon atom. Such curable compositions have a lower Mooney viscosity than do similar compositions absent the process aid.

Abstract: An emulsion polymerization process for the production of fluoroelastomers is disclosed wherein the aqueous polymerization medium comprises a dispersed fluoroionomer particulate and is substantially free of dispersing agent.

Abstract: Disclosed herein is a curable composition comprising a polyhydroxy curable fluoroelastomer, a polyhydroxy curative, a cure accelerator and an unsaturated metal compound process aid. Such curable compositions have a lower Mooney viscosity than do similar compositions absent the process aid.

Abstract: Disclosed herein are curable compositions comprising a free radical curable fluoroelastomer, a free radical generating compound and an unsaturated metal compound coagent. Such compositions cure well, exhibit good (i.e. low) compression set resistance and process well (i.e. have reduced polymer viscosity compared to similar compositions not containing the unsaturated metal compound coagent).

Abstract: Disclosed herein is a curable composition comprising a peroxide curable fluoroelastomer, an organic peroxide, a multifunctional coagent and an acid acceptor selected from the group consisting of carboxylic acid salts of bismuth and a bismuth oxycarboxylate. Cured articles made therefrom are resistant to volume swell in acids and in biodiesel fuel and said cured articles exhibit good heat resistance.

Abstract: Disclosed herein is a curable composition comprising a curable fluoroelastomer, a curative and an acid acceptor selected from the group consisting of a hydrous bismuth oxide nitrate compound and bismuth oxide. Cured articles made therefrom are resistant to volume swell in acids, coolant and in biofuel.

Abstract: Disclosed herein is a curable composition comprising a curable fluoroelastomer, a curative and an acid acceptor selected from the group consisting of a hydrous bismuth oxide nitrate compound and bismuth oxide. Cured articles made therefrom are resistant to volume swell in acids, coolant and in biofuel.

Abstract: In a process for the manufacture of fluoroelastomers, a water-soluble polymeric coagulant is employed that is an aqueous solution of polyethyleneimine or its copolymers.

Abstract: Fluoroelastomer gum or crumb is isolated from fluoroelastomer dispersions by the addition of a water-soluble polymeric coagulating agent to the dispersion. This coagulating agent comprises either a homopolymer of ethylene oxide (CH2CH2O—) or a copolymer of ethylene oxide. Specific examples of such copolymers include, but are not limited to ethylene oxide-propylene oxide copolymers and ethylene oxide-butylene oxide copolymers. The viscosity average molecular weight (Mv), determined by rheology, of the coagulant polymer must be at least 500,000 and preferably greater than 2,000,000.

Abstract: In a process for the manufacture of fluoroelastomers, a water-soluble polymeric coagulant is employed that is an aqueous solution of polyethylene oxide homopolymer or copolymer having a viscosity average molecular weight of 500,000 or greater.

Abstract: Copolymer comprising at least 50 mol percent up to 85 mol percent tetrafluoroethylene (TFE), from 10-35 mol percent 3,3,3-trifluoropropylene (TFP), and from 0.5-15 mol percent of a fluorinated ethylenically unsaturated monomer of the formula RCF?CR2 wherein R, which can be the same or different, is selected from the group consisting of H, F, Cl, Br, I, alkyl of from 1 to 8 carbon atoms, perfluoroalkyl of from 1 to 8 carbon atoms, and perfluoroalkylether of from 1 to 8 carbon atoms are useful as process aids and for fuel barrier applications in flexible hose constructions.

Abstract: An aqueous semi-batch polymerization process is disclosed for the manufacture of dipolymers of tetrafluoroethylene and 3,3,3-trifluoropropene that contain between 45 and 95 mole percent tetrafluoroethylene and between 5 and 55 mole percent 3,3,3-trifluoropropene.

Abstract: An extrudable composition comprising a non-fluorinated, melt processable host polymer and from about 25 parts per million by weight to about 50% by weight, based on total weight of said extrudable composition, of a fluoropolymer consisting essentially of copolymerized units of from 45 to 95 mole percent, based on total weight of said fluoropolymer, of tetrafluoroethylene (TFE) and from 5 and 55 mole percent, based on total weight of said fluoropolymer, of 3,3,3-trifluoropropylene (TFP).

Abstract: In a process for the manufacture of fluoroelastomers, a water-soluble polymeric coagulant is employed that is an aqueous solution of polyethyleneimine or its copolymers.