Abstract: Methods and compositions for generating stabilized oxidants using a stabilizer composition and an in situ generated oxidant in a water system. The method includes mixing the stabilizer composition and the in situ generated oxidant with water to form a liquid treatment composition, and then adding the liquid treatment composition to a water stream in the water system, the liquid treatment composition improving the efficacy of the in situ generated oxidant in the water stream.

Abstract: Disclosed herein are a method for treating a water stream in a zero liquid discharge (ZLD) system and a ZLD system. The method includes contacting the water stream with a metal agent that reduces a nitrate contained therein to a nitrite, and introducing an amide into the water stream that reduces the nitrite to nitrogen to provide a treated water stream having a reduced nitrate concentration. The ZLD system includes a mix tank, an amide tank including an amide, and a crystallizer. The mix tank includes an inlet for receiving a water stream within the mix tank, and a container including a metal agent. The container is designed to allow the water stream to contact the metal agent. The amide tank is designed to direct the amide into the water stream, and the crystallizer is designed to receive the water stream from the mix tank.

Abstract: Methods are described for monitoring biofouling in a closed water system. For example, a method includes adding nitrate to water circulating in the closed water system, and detecting whether nitrite is present in the water after adding the nitrate. Another method includes introducing chlorite into water circulating in the closed water system, the detecting the amount of chlorite present in the water; and at least one of (i) comparing the detected amount of chlorite to an expected amount of chlorite; and (ii) observing whether the amount of chlorite in the water decreases over time.

Abstract: Disclosed herein are a method for treating a water stream in a zero liquid discharge (ZLD) system and a ZLD system. The method includes contacting the water stream with a metal agent that reduces a nitrate contained therein to a nitrite, and introducing an amide into the water stream that reduces the nitrite to nitrogen to provide a treated water stream having a reduced nitrate concentration. The ZLD system includes a mix tank, an amide tank including an amide, and a crystallizer. The mix tank includes an inlet for receiving a water stream within the mix tank, and a container including a metal agent. The container is designed to allow the water stream to contact the metal agent. The amide tank is designed to direct the amide into the water stream, and the crystallizer is designed to receive the water stream from the mix tank.

Abstract: Methods and liquid compositions for stabilizing an oxidizing biocide in a water system. The liquid composition comprises a hydantoin, and a surfactant, a ratio of a concentration of the hydantoin to the surfactant in the liquid composition is in a range of 1:1 to 99:1 by volume. The method comprises mixing a hydantoin, a surfactant and an oxidizing biocide with water to form a liquid treatment composition, and then adding the liquid treatment composition to a water stream in the water system, the liquid treatment composition improving the efficacy of the oxidizing biocide in the water stream.

Abstract: Devices and methods for sterilizing and/or disinfecting workpieces, such as medical and dental instruments. The device can include a chamber that receives the workpieces and can be sealed. The chamber is filled with chlorine dioxide gas to a threshold concentration and for a time sufficient to sterilize and/or disinfect the workpieces.

Abstract: Methods and liquid compositions for stabilizing an oxidizing biocide in a water system. The liquid composition comprises a hydantoin, and a surfactant, a ratio of a concentration of the hydantoin to the surfactant in the liquid composition is in a range of 1:1 to 99:1 by volume. The method comprises mixing a hydantoin, a surfactant and an oxidizing biocide with water to form a liquid treatment composition, and then adding the liquid treatment composition to a water stream in the water system, the liquid treatment composition improving the efficacy of the oxidizing biocide in the water stream.

Abstract: Methods and systems for producing high purity gaseous chlorine dioxide are provided. A solid chlorite reactant is contacted with an ozone-containing reactant gas, or a gas containing both ozone and a component that reacts with any hydroxide byproduct (such as carbon dioxide), to produce chlorine dioxide. The reaction can be monitored and controlled to ensure that excess chlorite reactant is provided and to prevent ozone from passing into the product gas.

Abstract: Systems and methods are provided for measuring the amount of cationic organic water treatment additives in water systems. Disclosed systems and methods monitor, analyze and control the amounts of cationic organic water treatment additive supplied to the water. Disclosed systems and methods may include various dyes and surfactants for facilitating the monitoring and control of the cationic organic water treatment additives.

Abstract: Devices and methods for sterilizing and/or disinfecting workpieces, such as medical and dental instruments. The device can include a chamber that receives the workpieces and can be sealed. The chamber is filled with chlorine dioxide gas to a threshold concentration and for a time sufficient to sterilize and/or disinfect the workpieces.

Abstract: Methods of producing chlorine dioxide including providing an acid, a chlorate salt and an organic water treatment additive that can form a reducing agent in situ, mixing the acid, the chlorate salt and the organic water treatment additive, and reacting the mixture.

Abstract: Methods and systems for producing high purity gaseous chlorine dioxide are provided. A solid chlorite reactant is contacted with an ozone-containing reactant gas, or a gas containing both ozone and a component that reacts with any hydroxide byproduct (such as carbon dioxide), to produce chlorine dioxide. The reaction can be monitored and controlled to ensure that excess chlorite reactant is provided and to prevent ozone from passing into the product gas.

Abstract: Disclosed are methods, materials, apparatus and systems for removing or suppressing ambient levels of reactive gas contaminants, particularly acidic gases, using particles of zeolite, sepiolite or other suitable carrier material impregnated with at least one treatment compound selected to react with the acidic gas(es). The methods involve contacting a contaminated gas stream with the impregnated carrier materials whereby at least a portion of the reactive gases contacts the treatment compound and reacts, thereby consuming the reactive gas molecules.

Abstract: Systems and methods are provided for measuring the amount of cationic organic water treatment additives in water systems. Disclosed systems and methods monitor, analyze and control the amounts of cationic organic water treatment additive supplied to the water. Disclosed systems and methods may include various dyes and surfactants for facilitating the monitoring and control of the cationic organic water treatment additives.

Abstract: Methods of producing chlorine dioxide including providing an acid, a chlorate salt and an organic water treatment additive that can form a reducing agent in situ, mixing the acid, the chlorate salt and the organic water treatment additive, and reacting the mixture.

Abstract: Provided are methods and systems for continuously producing low concentrations of chlorine dioxide from dilute solutions of sodium chlorite. The low concentrations of chlorine dioxide produced allow for reduced exposure risk with direct application of the chlorine dioxide stream. The incorporation of a suitable chlorine dioxide detector permits continuous monitoring and control of chlorine dioxide production ensuring that the process stays within regulatory guidelines. Pretreatment of reaction water is preferred for achieving suitable conversion rates of the low concentrations of chlorite to chlorine dioxide.