Patents by Inventor Eckhard Hickmann

Eckhard Hickmann has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6005144
    Abstract: Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: December 21, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5980594
    Abstract: Reaction products of polymers of C.sub.2 -C.sub.6 -olefins having an average degree of polymerization P of from 5 to 100 and oxides of nitrogen or mixtures of oxides of nitrogen and oxygen are used as additives for fuels, in particular for fuels for gasoline engines.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: November 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5972856
    Abstract: Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: October 26, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5879420
    Abstract: Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: March 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5679863
    Abstract: The preparation of .alpha.-carbonylphosphine oxides by oxidizing an .alpha.-hydroxyalkyl phosphine oxide with an organic hydroperoxide or of an organic peroxy acid in the presence of a compound of a Group IV to Group VIII metal in the periodic table, and novel .alpha.-hydroxybenzyl phosphine oxides. .alpha.-Carbonylphosphine oxides are used as photoinitiators for polymerizable compositions.
    Type: Grant
    Filed: October 16, 1995
    Date of Patent: October 21, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Fischer, Eckhard Hickmann, Rudolf Kropp, Jochen Schroeder, Beate Trentmann
  • Patent number: 5504236
    Abstract: The preparation of .alpha.-carbonylphosphine oxides by oxidizing an .alpha.-hydroxyalkyl phosphine oxide with an organic hydroperoxide or of an organic peroxy acid in the presence of a compound of a Group IV to Group VIII metal in the periodic table, and novel .alpha.-hydroxybenzyl phosphine oxides..alpha.-Carbonylphosphine oxides are used as photoinitiators for polymerizable compositions.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: April 2, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Fischer, Eckhard Hickmann, Rudolf Kropp, Jochen Schroeder, Beate Trentmann
  • Patent number: 5382732
    Abstract: A process of preparing symmetric C.sub.40 -carotenoids by reacting a C.sub.15 -triphenylphosphonium salt of the formula ##STR1## and a 2,5-bis(1,1-dialkoxy-2-propyl)-2,5-dihydrofuran to form a reaction product containing a diacetyl and a triphenylphosphonium salt, adding a strong base to the reaction product to convert the triphenylphosphonium salt to a carbenium ion, hydrolyzing the diacetyl to a dialdehyde, subjecting the dialdehyde and the carbenium ion to a Wittig reaction to prepare a Wittig reaction product, and converting the Wittig reaction product to the C.sub.40 -carotenoid by acid treatment.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: January 17, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Frank, Udo Rheude, Bernhard Schulz, Joachim Paust, Eckhard Hickmann
  • Patent number: 5300658
    Abstract: 2,5-bis(1,1-dialkoxy-2-propyl)-2,5-dihydrofurans of the formula I ##STR1## where R.sup.1 and R.sup.2 can be identical or different and can be alkyl of 1 to 4 carbons, the preparation thereof by reaction of 2,5-dialkoxy-2,5-dihydrofurans of the formula II ##STR2## In the presence of protic acids or Lewis acids with an alkyl propenyl ether of the formula III ##STR3## and the use thereof for preparing 2,7-dimethyl-2,4,6-octatrienedial and symmetric C.sub.40 -carotenoids such as .beta.-carotene, canthaxanthin and astaxanthin, are described.
    Type: Grant
    Filed: April 10, 1992
    Date of Patent: April 5, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Juergen Frank, Udo Rheude, Bernhard Schulz, Joachim Paust, Eckhard Hickmann
  • Patent number: 5260484
    Abstract: Polytetrahydrofuran derivatives of the general formula ##STR1## where n is from 2 to 70, X is the bridge member --NH-- or --O-- and R.sup.1 to R.sup.4 are each hydrogen or various radicals.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: November 9, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Eckhard Hickmann, Ulrich Koehler, Hardo Stegel
  • Patent number: 5245042
    Abstract: A process is described for the preparation of cis-2-(1H-1,2,4-triazol-1-ylmethyl)-2-(halophenyl)-3-(halophenyl)oxirane I ##STR1## by epoxidizing Z-3-(1H-1,2,4-triazol-1-yl)-2-(halophenyl)-1-halophenyl)propene II, ##STR2## where halogen is in each case fluorine, chlorine or bromine, which comprises reacting the crude product of the epoxidation with one or more reducing agents, which are added to the reaction mixture in a considerable excess over the amount necessary to destroy any peroxide compounds present.
    Type: Grant
    Filed: April 27, 1992
    Date of Patent: September 14, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Eckhard Hickmann, Rainer Seele, Reiner Kober, Heinz Isak
  • Patent number: 5231231
    Abstract: Poly(1,4-butanediol-.omega.,.omega.'-mercaptans) have the general formulaHS--(CH.sub.2).sub.4 --O--[(CH.sub.2).sub.4 --O].sub.n --(CH.sub.2).sub.4 --SH Iwhere n is from 1 to 150.
    Type: Grant
    Filed: October 30, 1989
    Date of Patent: July 27, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulrich Koehler, Hardo Siegel, Eckhard Hickmann
  • Patent number: 5159117
    Abstract: A process for preparing .alpha.,.alpha.-dialkoxy ketones of the formula I ##STR1## where R.sup.1 and R.sup.2 are each, independently of one another, hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.20 -cycloalkyl, C.sub.4 -C.sub.30 -cycloalkylakyl, C.sub.9 -C.sub.30 -alkylcycloalkyl, unsubstituted or C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkoxy-, halogen-, C.sub.1 -C.sub.4 -haloalkyl-, C.sub.1 -C.sub.4 -haloalkoxy-, phenyl-, phenoxy-, halophenyl-, halophenoxy- and/or cyano-substituted aryl, C.sub.7 -C.sub.20 -aralkyl or heterocyclyl,R.sup.2 is also ##STR2## R.sup.3 and R.sup.4 are each, independently of one another, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.20 -cycloalkyl, aryl, C.sub.7 -C.sub.20 -arylalkyl, or together are an unsubstituted or C.sub.1-C.sub.4 -alkyl- substituted C.sub.2 -C.sub.7 -alkylene chain andR.sup.5 is R.sup.1 or together with R.sup.1 is an unsubstituted or C.sub.1 -C.sub.4 -alkyl-substituted C.sub.2 -C.sub.
    Type: Grant
    Filed: August 20, 1991
    Date of Patent: October 27, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Guenter Wegner, Stefan Karbach, Hubert Smuda, Eckhard Hickmann, Reiner Kober, Rainer Seele, Thomas Zierke
  • Patent number: 5130454
    Abstract: Polytetrahydrofuran derivatives of the general formula ##STR1## where n is from 2 to 70, X is the bridge member --NH-- or --O-- and R.sup.1 and R.sup.4 are each hydrogen or various radicals.
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: July 14, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Eckhard Hickmann, Ulrich Koehler, Hardo Siegel
  • Patent number: 5124488
    Abstract: Polytetrahydrofuran ethers of the formulaR.sup.1 --O--(CH.sub.2).sub.4 ].sub.n O--R.sup.2 Iwhere n is a number from 3 to 70, and R.sup.1 and R.sup.2 are hydrocarbon radicals containing 3 to 5 carbon atoms and a double bond, but where R.sup.2 may alternatively be hydrogen.
    Type: Grant
    Filed: May 7, 1990
    Date of Patent: June 23, 1992
    Assignee: BASF Aktiengesellschaft
    Inventor: Eckhard Hickmann
  • Patent number: 5104438
    Abstract: N-Oxoazolylmethyloxiranes of the formula I ##STR1## where A and B are identical or different and each is alkyl, cycloalkyl, tetrahydropyranyl, benzyl, norbornyl, naphthyl, biphenyl or phenyl, these radicals being unsubstituted or substituted, and X is CH or N, and fungicides and bioregulators containing them.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: April 14, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Eckhard Hickmann, Eberhard Ammermann, Gisela Lorenz
  • Patent number: 5034559
    Abstract: Polyethercarboxylic esters of the formula ##STR1## where Alk is alkyl of 1 to 8 carbon atoms, R is hydrogen or methyl and n is from 3 to 70.
    Type: Grant
    Filed: July 2, 1990
    Date of Patent: July 23, 1991
    Assignee: BASF Aktiengesellschaft
    Inventor: Eckhard Hickmann
  • Patent number: 5008461
    Abstract: Benzyl ketones of the general formula I ##STR1## where R.sup.1 is C.sub.1 -C.sub.8 -alkyl which is unsubstituted or substituted by cycloalkyl or aryl and R.sup.2 and R.sup.3 are each halogen, C.sub.1 -C.sub.4 -alkyl, hydroxyl, C.sub.1 -C.sub.4 -alkoxy or C.sub.2 -C.sub.4 -methylenedioxy, are prepared by a process in which a glycol monoether of the general formula II ##STR2## where R.sup.1, R.sup.2 and R.sup.3 have the abovementioned meanings and R.sup.4 is C.sub.1 -C.sub.8 -alkyl, is converted in the presence of silica, a phosphate or a zeolite at from 50.degree. to 500.degree. C. and under from 0.01 to 50 bar.
    Type: Grant
    Filed: March 7, 1990
    Date of Patent: April 16, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Fritz Naeumann, Eckhard Hickmann
  • Patent number: 4973751
    Abstract: Compounds of the formula IR.sup.1 --CH.dbd.CH--R.sup.2 Iwhere R.sup.1 is hydrogen or alkyl and R.sup.2 is alkoxy or acylamino, and R.sup.1 and R.sup.2 together may form a heterocyclic ring, are prepared by elimination of the radical R.sup.3 OH from a compound of the formula II ##STR1## where R.sup.1 and R.sup.2 have the above meanings and R.sup.3 is alkyl, by a method in which the elimination is carried out by passing the compound of the formula II in a liquid or gaseous state into a high-boiling mineral oil above the boiling point of compound I being formed, compound I is taken off in gaseous form, and the high-boiling mineral oil enriched with by-products is removed and replaced with fresh mineral oil.
    Type: Grant
    Filed: November 22, 1988
    Date of Patent: November 27, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Toni Dockner, Eckhard Hickmann, Herbert Krug
  • Patent number: 4918205
    Abstract: Alkylated dodecahydronaphtho[2,1-b]furans of the general formula I ##STR1## where R.sup.1 and R.sup.2 are identical and each is hydrogen or methyl are prepared by reacting alkylated 2-hydroxydecahydronaphthalene-1-ethanol of the formula II ##STR2## where R.sup.1 and R.sup.2 are as defined above, with a sulfonyl chloride in the presence of basic catalysts by performing the cyclization in the presence of concentrated aqueous alkali metal hydroxides and a phase transfer catalyst, preferably a tetra-substituted ammonium or phosphonium salt, the sulfonyl chloride used preferably comprising a sulfonyl chloride of the general formula IIIR.sub.3 -SO.sub.2 Clwhere R.sup.3 is C.sub.1 -C.sub.3 -alkyl or phenyl which may be substituted in the para position by methyl, chlorine, bromine or nitro.
    Type: Grant
    Filed: September 28, 1988
    Date of Patent: April 17, 1990
    Assignee: BASF Aktiengesellschaft
    Inventors: Walter Gramlich, Eckhard Hickmann, Rainer Becker, Gerald Lauterbach
  • Patent number: 4734499
    Abstract: .alpha.,.beta.-Diaminoacrylonitriles of the general formula IR.sup.3 R.sup.2 NC(R.sup.1).dbd.C(NR.sup.2 R.sup.3)CN Iwhere R.sup.1, R.sup.2 and R.sup.3 are identical or different and independently of one another are each hydrogen, alkyl, cycloalkyl, aralkyl, aryl or a heterocyclic radical, and the organic radicals R.sup.2 may furthermore be bonded to one another to form a 6-membered or 7-membered ring, or R.sup.2 and R.sup.3 may be bonded to one another to form a 5-membered or 6-membered ring, are prepared by reacting an .alpha.-dicarbonyl compound R.sup.1 COCHO, or a reactive derivative of this with (a) a salt of sulfurous acid or sulfur dioxide, (b) an amine HNR.sup.2 R.sup.3 or an aliphatic diamine R.sup.3 HN-(CH.sub.2).sub.n NHR.sub.3 where n is 2 or 3 and (c) hydrocyanic acid or a hydrocyanic acid donor in any sequence.
    Type: Grant
    Filed: September 19, 1985
    Date of Patent: March 29, 1988
    Assignee: BASF Aktiengesellschaft
    Inventor: Eckhard Hickmann