Abstract: The present disclosure relates to polymer compounds for use as polymerization agents in coatings, paints or inks. In one embodiment, a polymer compound comprises a metal-bearing urethanized polymer having a metal content greater than 6% by weight, and a water solubility below 20 mg/l according to OECD 105, wherein the urethanized polymer is soluble in a low-volatile organic compound (low-VOC) solvent. Methods of producing and using such polymer compounds are also disclosed.

Abstract: The present disclosure relates to polymer compounds for use as polymerization agents in coatings, paints or inks. In one embodiment, a polymer compound comprises at least one of a cobalt-bearing urethanized polymer having a cobalt content of no more than 6% by weight and a mean molecular weight of no more than 2500 Da, or a manganese-bearing urethanized polymer having a manganese content of 1% to 6% by weight and a mean molecular weight of no more than 2000 Da.

Abstract: The present disclosure relates to polymer compounds for use as both a drying agent and an anti-skinning agent in coatings and paints. In one embodiment, a polymer compound comprises a urethanized polymer having a metal, an antioxidant, and a water solubility according to OECD 105 below 20 mg/l. Methods of synthesizing and using such polymer compounds are also disclosed.

Abstract: The present disclosure relates to polymer compounds for use as polymerization agents in coatings, paints or inks. In one embodiment, a polymer compound comprises a metal-bearing urethanized polymer having a metal content greater than 6% by weight, and a water solubility below 20 mg/l according to OECD 105, wherein the urethanized polymer is soluble in a low-volatile organic compound (low-VOC) solvent. Methods of producing and using such polymer compounds are also disclosed.

Abstract: The present disclosure relates to polymer compounds for use as polymerization agents in coatings, paints or inks. In one embodiment, a polymer compound comprises at least one of a cobalt-bearing urethanized polymer having a cobalt content of no more than 6% by weight and a mean molecular weight of no more than 2500 Da, or a manganese-bearing urethanized polymer having a manganese content of 1% to 6% by weight and a mean molecular weight of no more than 2000 Da.

Abstract: This disclosure relates to catalysts for the auto-oxidative drying of polymers, in particular for polymers used in paints or inks, based on unsaturated fatty acids, mostly from vegetal origin A compound is divulged for use as a polymerisation agent in coatings, characterized in that it comprises a cobalt-bearing alkyd polymer, said polymer having a cobalt content of 0.5 to 6% by weight, a mean molecular weight of more than 3000, and comprising cobalt carboxylate sequences Several processes are presented to illustrate the synthesis of the cobalt-bearing polymer These polymers retain the catalytic effect of cobalt towards the drying of polymers, while they greatly suppress the toxicity of cobalt by being essentially insoluble in water.

Abstract: The invention relates to polymeric cobalt bearing compounds, in particular for use as metal-rubber adhesion promoters (RAPs) in tires, belts and hoses. Known active substances are a.o. cobalt stearates, naphthenates, resinates, decanoates, boro-decanoates and many other forms of acylates. While these substances appear to enhance the metal-rubber adhesion, all of them also come with significant drawbacks, a.o. linked to the relatively high bioavailability of cobalt in these substances. The invention concerns more particularly a polymer comprising Co-carboxylate sequences, with a Co content of at least 3% by weight, and with a mean molecular weight of more than 2000. Several synthesis methods, allowing to reach relatively high Co concentrations in the polymer, illustrate the invention. The invented polymers show a strongly reduced bioavailability of Co compared to currently available products, as demonstrated by aqueous leaching tests.

Abstract: This disclosure relates to catalysts for the auto-oxidative drying of polymers, in particular for polymers used in paints or inks, based on unsaturated fatty acids, mostly from vegetal origin A compound is divulged for use as a polymerisation agent in coatings, characterized in that it comprises a cobalt-bearing alkyd polymer, said polymer having a cobalt content of 0.5 to 6% by weight, a mean molecular weight of more than 3000, and comprising cobalt carboxylate sequences Several processes are presented to illustrate the synthesis of the cobalt-bearing polymer These polymers retain the catalytic effect of cobalt towards the drying of polymers, while they greatly suppress the toxicity of cobalt by being essentially insoluble in water.

Abstract: The invention relates to polymeric cobalt bearing compounds, in particular for use as metal-rubber adhesion promoters (RAPs) in tires, belts and hoses. Known active substances are a.o. cobalt stearates, naphthenates, resinates, decanoates, boro-decanoates and many other forms of acylates. While these substances appear to enhance the metal-rubber adhesion, all of them also come with significant drawbacks, a.o. linked to the relatively high bioavailability of cobalt in these substances. The invention concerns more particularly a polymer comprising Co-carboxylate sequences, with a Co content of at least 3% by weight, and with a mean molecular weight of more than 2000. Several synthesis methods, allowing to reach relatively high Co concentrations in the polymer, illustrate the invention. The invented polymers show a strongly reduced bioavailability of Co compared to currently available products, as demonstrated by aqueous leaching tests.