Publication number: 20060199926
Abstract: The present invention relates to novel oxygen-containing organoaluminium complexes of the general formula (I) in which R1, independently of one another, denote branched or unbranched C1-C7-alkyl, -cycloalkyl, -alkenyl, -cycloalkenyl, -aryl or -alkynyl; R2 denotes unsubstituted, mono- or polyalkylated and/or mono- or polyfluorinated aromatic hydrocarbons from the group R3, R4, independently of one another, denote CH2, CF2 or C(R1)2; independently of one another, m denotes 0, 1, 2 n denotes 0, 1, 2. These compounds can serve as cocatalysts in olefinic polymerisation reactions. In particular, they can be employed for the preparation of novel Ziegler-Natta catalysts having improved properties, in particular having higher activities compared with conventional Ziegler-Natta catalysts with AlEt3, as cocatalyst, or of novel coordination catalyst systems which have higher activities than conventional Ziegler-Natta catalysts, even at low temperatures, such as 60° C., and a pressure of 2 bar.
Type:
Application
Filed:
September 13, 2002
Publication date:
September 7, 2006
Applicant:
Merck Patent GmbH
Inventors:
Katrin Koehler, Eike Poetsch, Jens Eichhorn, Herbert Schumann, Birgit Wassermann, Sebastiain Dechert, Markus Hummert, Stefan Schutte, Walter Kaminsky, Andrea Eisenhardt, Manfred Arnold
Publication number: 20060025615
Abstract: The present invention relates to a process for the preparation of a compound of the general formula R-(A1-Z-)mB—CF2O-A2-(A3)n-R???(I) in which R is alkyl, in which one or more CH2 groups may be replaced, independently of one another, by O, CF2, CH?CH, CH?CF or CF?CF, with the proviso that peroxide structures O—O and formaldehyde acetals O—CH2—O are excluded, A1 is, independently of one another, 1,4-cyclohexylene, 2,5-1,3-dioxanylene, 1,3-cyclobutylene or A2 and A3 are 1,4-phenylene, in which, independently of one another, from one to four hydrogens may be replaced by fluorine or one or two CH groups may be replaced by N, Z is a single bond, —CH2—CH2—, —CF2—CF2—, —CH?CH—, —CF?CF—, —CH?CF— or —CF?CH—, B is 2,6-disubstituted naphthalene, 2,6-disubstituted 5,6,7,8-tetrahydronaphthalene or 2,6-disubstituted trans-decalin, R? is R, F, OCF3, OCF2H, CF3, CI, SF5, CN or NCS, and m and n are, independently of one another, 0 or 1, comprising the following steps: a) conversion of a compound of the general formu
Type:
Application
Filed:
October 30, 2003
Publication date:
February 2, 2006
Inventors:
Eike Poetsch, Werner Binder, Peer Kirsch, Andreas Taugerbeck