Abstract: A mask element for flexographic printing is provided. The mask element can be used for preparing a mask that has a mask image. The mask element can include: a transparent polymeric carrier sheet; a barrier layer on the transparent polymeric carrier sheet, wherein the barrier layer comprises non-crosslinked nitrocellulose; and an imaging layer on the barrier layer, wherein the imaging layer includes a non-silver halide thermally-ablatable material comprising non-crosslinked nitrocellulose, carbon black, and an infrared (IR) dye. In some aspects, the mask element further includes a transparent overcoat layer on the imaging layer. The mask can include: imaged regions in the imaging layer, wherein the imaged regions have optical apertures that are substantially devoid of the carbon black and non-crosslinked nitrocellulose thereof; and non-imaged regions in the imaging layer, wherein the non-imaged regions have the non-crosslinked nitrocellulose, carbon black, and infrared dye.

Abstract: A relief image is prepared by: A) imaging an imageable material to form a mask element; B) exposing a relief-forming precursor through the mask element; C) removing the mask element; and D) developing the imaged relief-forming precursor. The imageable material has, in order: (a) a transparent polymeric carrier sheet; (b) a non-ablatable light-to-heat converting having an average dry thickness of 1-5 ?m and comprising: (i) an infrared radiation absorbing material at 0.1-5 weight %; (ii) a thermally crosslinked organic polymeric binder material; and (iii) non-thermally ablatable particles having an average particle size of 0.1-20 ?m in an amount of 0.2-10 weight %; and (c) a non-silver halide thermally-ablatable imaging layer (IL) disposed on the LTHC layer, the IL comprising a second infrared radiation absorbing material and a UV-light absorbing material dispersed within one or more thermally-ablatable polymeric binder materials. The imageable material can be included in a relief image-forming assembly.

Abstract: An imageable material can be used to form a mask element that in turn is useful for providing relief images such as in flexographic printing plates. The imageable material has, in order: (a) a transparent polymeric carrier sheet; (b) a non-ablatable light-to-heat converting having an average dry thickness of 1-5 ?m and comprising: (i) an infrared radiation absorbing material at 0.1-5 weight %; (ii) a thermally crosslinked organic polymeric binder material; and (iii) non-thermally ablatable particles having an average particle size of 0.1-20 ?m in an amount of 0.2-10 weight %; and (c) a non-silver halide thermally-ablatable imaging layer (IL) disposed on the LTHC layer, the IL comprising a second infrared radiation absorbing material and a UV-light absorbing material dispersed within one or more thermally-ablatable polymeric binder materials.

Abstract: An imageable material can be used to form a mask element that in turn is useful for providing relief images such as in flexographic printing plates. The imageable material has, in order: (a) a transparent polymeric carrier sheet; (b) a non-ablatable light-to-heat converting having an average dry thickness of 1-5 ?m and comprising: (i) an infrared radiation absorbing material at 0.1-5 weight %; (ii) a thermally crosslinked organic polymeric binder material; and (iii) non-thermally ablatable particles having an average particle size of 0.1-20 ?m in an amount of 0.2-10 weight %; and (c) a non-silver halide thermally-ablatable imaging layer (IL) disposed on the LTHC layer, the IL comprising a second infrared radiation absorbing material and a UV-light absorbing material dispersed within one or more thermally-ablatable polymeric binder materials.

Abstract: A relief image is prepared by: A) imaging an imageable material to form a mask element; B) exposing a relief-forming precursor through the mask element; C) removing the mask element; and D) developing the imaged relief-forming precursor. The imageable material has, in order: (a) a transparent polymeric carrier sheet; (b) a non-ablatable light-to-heat converting having an average dry thickness of 1-5 ?m and comprising: (i) an infrared radiation absorbing material at 0.1-5 weight %; (ii) a thermally crosslinked organic polymeric binder material; and (iii) non-thermally ablatable particles having an average particle size of 0.1-20 ?m in an amount of 0.2-10 weight %; and (c) a non-silver halide thermally-ablatable imaging layer (IL) disposed on the LTHC layer, the IL comprising a second infrared radiation absorbing material and a UV-light absorbing material dispersed within one or more thermally-ablatable polymeric binder materials. The imageable material can be included in a relief image-forming assembly.

Abstract: An assembly can be used to provide flexographic printing plates. This assembly has (a) a flexographic photosensitive element consisting essentially of: a backing film, and a water-soluble or water-dispersible photosensitive layer comprising a photosensitive resin composition and having a front imaging surface and a backside imaging surface that is in contact with the backing film; and (b) a mask element directly in contact with the front imaging surface of the water-soluble or water-dispersible photosensitive layer. The water-soluble or water-dispersible photosensitive layer has a controlled release of at least 5 g/cm and up to and including 700 g/cm as established by ASTM D-3330 Method D, between the front imaging surface and the mask element.

Abstract: Flexographic printing members are prepared by developing an exposed flexographic printing member precursor with an aqueous flexographic developer. The aqueous flexographic developer comprises: a) a fatty acid composition consisting of one or more saturated or unsaturated fatty acids or alkali metal salts thereof, each saturated or unsaturated fatty acid or alkali metal salt thereof independently having 12 to 20 carbon atoms, the fatty acid composition being present in an amount of 0.25-2.0 weight %, and at least 85 weight % of the fatty acid composition is composed of one or more C18 mono- or poly-unsaturated fatty acids or alkali metal salts thereof; b) an aminopolycarboxylic acid or alkali metal salt thereof in an amount of 0.05-0.30 weight %; c) a buffer compound in an amount of 05-0.60 weight %; and d) water. Such aqueous flexographic developers can also be provided in concentrated form and appropriately diluted before or during use.

Abstract: Flexographic printing members are prepared by developing an exposed flexographic printing member precursor with an aqueous flexographic developer. The aqueous flexographic developer comprises: a) a fatty acid composition consisting of one or more saturated or unsaturated fatty acids or alkali metal salts thereof, each saturated or unsaturated fatty acid or alkali metal salt thereof independently having 12 to 20 carbon atoms, the fatty acid composition being present in an amount of 0.25-2.0 weight %, and at least 85 weight % of the fatty acid composition is composed of one or more C18 mono- or poly-unsaturated fatty acids or alkali metal salts thereof; b) an aminopolycarboxylic acid or alkali metal salt thereof in an amount of 0.05-0.30 weight %; c) a buffer compound in an amount of 05-0.60 weight %; and d) water. Such aqueous flexographic developers can also be provided in concentrated form and appropriately diluted before or during use.

Abstract: Flexographic printing members are prepared by developing an exposed flexographic printing member precursor with an aqueous flexographic developer. The aqueous flexographic developer comprises: a) a fatty acid composition consisting of one or more saturated or unsaturated fatty acids or alkali metal salts thereof, each saturated or unsaturated fatty acid or alkali metal salt thereof independently having 12 to 20 carbon atoms, the fatty acid composition being present in an amount of 0.25-2.0 weight %, and at least 85 weight % of the fatty acid composition is composed of one or more C18 mono- or poly-unsaturated fatty acids or alkali metal salts thereof; b) an aminopolycarboxylic acid or alkali metal salt thereof in an amount of 0.05-0.30 weight %; c) a buffer compound in an amount of 05-0.60 weight %; and d) water. Such aqueous flexographic developers can also be provided in concentrated form and appropriately diluted before or during use.

Abstract: Flexographic printing members are prepared by developing an exposed flexographic printing member precursor with an aqueous flexographic developer. The aqueous flexographic developer comprises: a) a fatty acid composition consisting of one or more saturated or unsaturated fatty acids or alkali metal salts thereof, each saturated or unsaturated fatty acid or alkali metal salt thereof independently having 12 to 20 carbon atoms, the fatty acid composition being present in an amount of 0.25-2.0 weight %, and at least 85 weight % of the fatty acid composition is composed of one or more C18 mono- or poly-unsaturated fatty acids or alkali metal salts thereof; b) an aminopolycarboxylic acid or alkali metal salt thereof in an amount of 0.05-0.30 weight %; c) a buffer compound in an amount of 05-0.60 weight %; and d) water. Such aqueous flexographic developers can also be provided in concentrated form and appropriately diluted before or during use.

Abstract: A pattern of an electrically conductive print material is formed on a receiver element using an elastomeric relief element that has a relief pattern comprising (1) an uppermost relief surface, and (2) an average relief image depth of at least 50 ?m relative to the uppermost relief surface. A printable material composition is applied to the uppermost relief surface, which printable material composition contains an electrically conductive print material and a carrier liquid. At least 50 weight % of the carrier liquid is removed from the uppermost relief surface, leaving the electrically conductive print material on the uppermost relief surface. Either the elastomeric relief element or the printable material composition on the elastomeric relief element, or both, are treated with an acid in vapor or liquid form to improve conductivity of the electrically conductive print material after it has been transferred from the uppermost relief surface to the receiver element.

Abstract: A print material pattern is formed on a receiver element using an elastomeric relief element having a relief pattern. A printable material composition is applied only to the uppermost relief surface of the elastomeric relief element and at least at least 50 weight % of a carrier liquid is removed. A receiver element has a print material receptive layer having a dry thickness of 0.05-10 ?m and is heated. During contact of the print material composition on the uppermost relief surface and the heated receiver element, the elastomeric relief element is compressed to provide sufficient contact with the receiver element. The elastomeric relief element is then separated from the heated receiver element to leave a pattern of the functional material on the heated receiver element, wherein at least 70 weight % of the original print material is transferred to the heated receiver element.

Abstract: A multilayer structure having at least two different print materials pattern is formed on a receiver element using an elastomeric relief element having a relief pattern. Multiple different printable material compositions are sequentially applied only to the uppermost relief surface of the elastomeric relief element and at least at least 50 weight % of a carrier liquid is removed from each printable material composition. During contact of the multilayer structure on the uppermost relief surface and the receiver element, the elastomeric relief element is compressed by at least 10 ?m of its original thickness. The elastomeric relief element is then separated from the receiver element to leave a pattern of the multilayer structure on the receiver element, wherein at least 70 weight % of the multiple print materials is transferred to the receiver element.

Abstract: A multilayer structure having at least two different print materials pattern is formed on a receiver element using an elastomeric relief element having a relief pattern. Multiple different printable material compositions are sequentially applied only to the uppermost relief surface of the elastomeric relief element and at least at least 50 weight % of a carrier liquid is removed from each printable material composition. During contact of the multilayer structure on the uppermost relief surface and the receiver element, the elastomeric relief element is compressed by at least 10 ?m of its original thickness. The elastomeric relief element is then separated from the receiver element to leave a pattern of the multilayer structure on the receiver element, wherein at least 70 weight % of the multiple print materials is transferred to the receiver element.

Abstract: A pattern of an electrically conductive print material is formed on a receiver element using an elastomeric relief element that has a relief pattern comprising (1) an uppermost relief surface, and (2) an average relief image depth of at least 50 ?m relative to the uppermost relief surface. A printable material composition is applied to the uppermost relief surface, which printable material composition contains an electrically conductive print material and a carrier liquid. At least 50 weight % of the carrier liquid is removed from the uppermost relief surface, leaving the electrically conductive print material on the uppermost relief surface. Either the elastomeric relief element or the printable material composition on the elastomeric relief element, or both, are treated with an acid in vapor or liquid form to improve conductivity of the electrically conductive print material after it has been transferred from the uppermost relief surface to the receiver element.

Abstract: A print material pattern is formed on a receiver element using an elastomeric relief element having a relief pattern. A printable material composition is applied only to the uppermost relief surface of the elastomeric relief element and at least at least 50 weight % of a carrier liquid is removed. A receiver element has a print material receptive layer having a dry thickness of 0.05-10 ?m and is heated. During contact of the print material composition on the uppermost relief surface and the heated receiver element, the elastomeric relief element is compressed to provide sufficient contact with the receiver element. The elastomeric relief element is then separated from the heated receiver element to leave a pattern of the functional material on the heated receiver element, wherein at least 70 weight % of the original print material is transferred to the heated receiver element.