Patents by Inventor Enea Garagnani
Enea Garagnani has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 8039540Abstract: Polymer composition showing an improved balance of flexural modulus, IZOD impact strength and elongation at break comprising (percent by weight): A) a polymer blend comprising: A1) 50-70% of a crystalline propylene homopolymer or copolymer; and A2) 30-50% of one or more copolymer(s) of ethylene with one or more C4-C10 ?-olefin(s) containing from 15 to 35% of said C4-C10 ?-olefin(s); said polymer blend (A) having values of MFR equal to or higher than 10 g/10 min., a total content C4-C10 ?-olefin(s) equal to or higher than 8% and an intrinsic viscosity value of the fraction soluble in xylene at room temperature of from 1.3 to 2 dl/g, the amounts of (A1) and (A2) being referred to the total weight of the polymer blend; and optionally B) 1-15% of an elastomeric polymer different from A2), having a hardness (Shore A, ASTM D-2240) value equal to or lower than 90 points; and/or C) 0.5-20% of a mineral filler; the amounts of optional components (B) and (C) being referred to the total weight of the composition.Type: GrantFiled: May 30, 2005Date of Patent: October 18, 2011Assignee: Basell Poliolefine Italia s.r.l.Inventors: Anteo Pelliconi, Enea Garagnani
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Patent number: 8008400Abstract: A masterbatch composition comprising (percent by weight): A) 50%-90% of a crystalline polypropylene component comprising: AI) from 25% to 75% of a fraction having a melt flow rate MFRI of from 0.1 to 10 g/10 min.; and AII) from 75% to 25% of a fraction having a melt flow rate value MFRII equal to or lower than 100 g/10 min.; wherein the ratio MFRI/MFRII is from 5 to 60; and B) 10%-50% of a copolymer component of ethylene and at least one C3-C10 ?-olefin, containing from 15% to 50% of ethylene; said masterbatch composition having a value of the intrinsic viscosity [?] of the fraction soluble in xylene at room temperature equal to or higher than 3.5 dl/g, is added to polyolefin materials to obtain final compositions suitable for injection molding.Type: GrantFiled: March 29, 2004Date of Patent: August 30, 2011Assignee: Basell Poliolenfine Italia s.r.l.Inventors: Anteo Pelliconi, Enea Garagnani, Gerald J. Ennis
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Publication number: 20110136981Abstract: The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived units characterized by the following properties: d) Product of the reactivity ratios r1·r2?2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.Type: ApplicationFiled: January 26, 2011Publication date: June 9, 2011Applicant: BASELL POLIOLEFINE ITALIA S.P.A.Inventors: Giampiero Morini, Fabrizio Piemontesi, Gianni Vitale, Daniele Bigiavi, Anteo Pelliconi, Enea Garagnani, Pietro Baita
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Patent number: 7943717Abstract: The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios r1·r2?2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.Type: GrantFiled: November 3, 2003Date of Patent: May 17, 2011Assignee: Basell Poliolefine Italia, S.p.A.Inventors: Giampiero Morini, Fabrizio Piemontesi, Gianni Vitale, Daniele Bigiavi, Anteo Pelliconi, Enea Garagnani, Pietro Baita
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Patent number: 7728077Abstract: A masterbatch composition comprising (percent by weight): A) 15%-50% of a polypropylene component having a melt flow rate of from 1 to 250 g/10 min.; and B) 50%-85% of an olefin polymer partially soluble in xylene at room temperature, containing from 60% to 85% by weight of ethylene; said masterbatch composition having (i) a value of the intrinsic viscosity [?] of the fraction soluble in xylene at room temperature ([?]sol) equal to or lower than 2.9 dl/g, and (ii) a value of the ratio MFR/[?], , , , equal to or lower than 4, is added to polyolefin materials to obtain final compositions suitable for injection molding.Type: GrantFiled: March 22, 2005Date of Patent: June 1, 2010Assignee: Basell Pololefine Italia s.r.l.Inventors: Anteo Pelliconi, Enea Garagnani, Giampaolo Pellegatti, Antonella Angelini
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Patent number: 7691939Abstract: A polyolefin composition comprising (percentage by weight): (A) from 60 to 85% of a broad molecular weight distribution propylene polymer (component A) having a polydispersity index from 5 to 15 and melt flow rate of from 20 to 78 g/10 min (according to ASTM-D 1238, condition L); and (B) from 15 to 40% of a partially xylene-soluble olefin polymer rubber (component B) containing at least 65% by weight of ethylene. Said composition finds application in automotive field.Type: GrantFiled: August 3, 2004Date of Patent: April 6, 2010Assignee: Basell Poliolefine Italia s.r.l.Inventors: Enea Garagnani, Anteo Pelliconi
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Patent number: 7592393Abstract: A polyolefin composition comprising: (A) from 8 to 25% by weight of a crystalline homopolymer or copolymer of propylene: (B) from 75 to 92% by weight of an elastomeric fraction comprising: (1) a first elastomeric copolymer of propylene with from 15 to 32% by weight at least one alpha-olefin of formula H2C?CHR, where R is H or a C2-6 linear or branched alkyl, optionally containing 0.5 to 5% by weight of a diene, said first elastomeric copolymer containing alpha-olefin, and having solubility in xylene at room temperature greater than 50% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from 3.0 to 5.0 dl/g; and (2) a second elastomeric copolymer of propylene with at least one alpha-olefin of formula H2C?CHR, where R is H or a C2-6 linear or branched alkyl, optionally containing 0.Type: GrantFiled: April 8, 2002Date of Patent: September 22, 2009Assignee: Basel Poliolefine Italia S.p.A.Inventors: Anteo Pelliconi, Enea Garagnani, Alvaro Villanueva
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Patent number: 7557161Abstract: Propylene polymer compositions comprising (by weight): A) from 15% to 60% with C4-C8 alpha-olefin(s), containing more than 10%, but less than 14%, of said C4-C8 alpha-olefins (s); B) from 40% to 85% of a copolymer of propylene with C4-C8 alpha-olefin(s), preferably butene, containing from 14% to 30% of said C4-C8 alpha-olefin(s), and optionally from 0.5% to 3% of ethylene; provided that the total content of C4-C8 alpha-olefin(s) in the propylene polymer composition be higher than 10%.Type: GrantFiled: October 4, 2002Date of Patent: July 7, 2009Assignee: Basell Poliolefine Italia S.p.A.Inventors: Anteo Pelliconi, Enea Garagnani, Paola Sgarzi
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Patent number: 7538174Abstract: An isotactic 1-butene copolymer having a content up to 30% by mol of at least one alpha-olefin of formula CH2?CHZ derived units, wherein Z is a C3-C20 hydrocarbon group, having the following features: isotactic pentads (mmmm) >90%; and a percentage of soluble fraction in diethylether (% SD) and a molar content of said alpha olefins (% O) in the polymer chain meeting the following relation: % SD>2.8% O+8.Type: GrantFiled: October 30, 2007Date of Patent: May 26, 2009Assignee: Basell Polyolefine GmbHInventors: Luigi Resconi, Anteo Pelliconi, Enea Garagnani
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Patent number: 7534848Abstract: A process comprising contacting 1-butene and one or more alpha-olefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R1 and R3 are hydrocarbon groups; R2 and R4 are hydrogen atoms or hydrocarbon groups; T1 and T2, equal to or different from each other are a moiety of formula (II), (III) or (IV): wherein: R5, R6, R7, R8 and R9, equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an alkylmetallocene cation.Type: GrantFiled: November 14, 2003Date of Patent: May 19, 2009Assignee: Basell Polyolefine GmbHInventors: Luigi Resconi, Anteo Pelliconi, Enea Garagnani
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Publication number: 20080249273Abstract: An isotactic 1-butene copolymer having a content up to 30% by mol of at least one alpha-olefin of formula CH2?CHZ derived units, wherein Z is a C3-C20 hydrocarbon group, having the following features: isotactic pentads (mmmm) >90%; and a percentage of soluble fraction in diethylether (% SD) and a molar content of said alpha olefins (% O) in the polymer chain meeting the following relation: % SD>2.8% O+8.Type: ApplicationFiled: October 30, 2007Publication date: October 9, 2008Applicant: Basell Polyolefine GmbHInventors: Luigi Resconi, Anteo Pelliconi, Enea Garagnani
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Publication number: 20080071019Abstract: Polymer composition showing an improved balance of flexural modulus, IZOD impact strength and elongation at break comprising (percent by weight): A) a polymer blend comprising: A1) 50-70% of a crystalline propylene homopolymer or copolymer; and A2) 30-50% of one or more copolymer(s) of ethylene with one or more C4-C10 ?-olefin(s) containing from 15 to 35% of said C4-C10 ?-olefin(s); said polymer blend (A) having values of MFR equal to or higher than 10 g/10 min., a total content C4-C10 ?-olefin(s) equal to or higher than 8% and an intrinsic viscosity value of the fraction soluble in xylene at room temperature of from 1.3 to 2 dl/g, the amounts of (A1) and (A2) being referred to the total weight of the polymer blend; and optionally B) 1-15% of an elastomeric polymer different from A2), having a hardness (Shore A, ASTM D-2240) value equal to or lower than 90 points; and/or C) 0.5-20% of a mineral filler; the amounts of optional components (B) and (C) being referred to the total weight of the composition.Type: ApplicationFiled: May 30, 2005Publication date: March 20, 2008Applicant: BASELL POLIOLEFINE ITALIA S.R.1.Inventors: Anteo Pelliconi, Enea Garagnani
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Patent number: 7288598Abstract: A masterbatch composition comprising (1) 10-50 wt % of a crystalline propylene homopolymer and (2) 50-90 wt % of a blend consisting of (a) a copolymer of ethylene and one or more C4-CIO a-olefin(s), containing 10-40 of C4-CIO a-olefin(s), and (b) an amorphous copolymer of propylene and ethylene. Copolymer (b) has an ethylene content from 20-70 wt %, and an intrinsic viscosity value of the xylene-soluble moiety of from 2.2 to 3.5 d/Lg, this value being equal to 0.8 to 1.2 times the intrinsic viscosity value of the xylene-soluble moiety of copolymer (a). The weight ratio of copolymers (a)/(b) is from 3/1 to 1/3. Polyolefin compositions comprising the said masterbatch composition are suitable for the manufacture of automotive parts.Type: GrantFiled: March 6, 2003Date of Patent: October 30, 2007Assignee: Basell Poliolefine Italia S.p.A.Inventors: Anteo Pelliconi, Enea Garagnani, Yutaka Yokoyama, Junichiro Washiyama, Hiroshi Takenouchi, Takeshi Nakajima
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Publication number: 20070232765Abstract: A masterbatch composition comprising (percent by weight): A) 15%-50% of a polypropylene component having a melt flow rate of from 1 to 250 g/10 min.; and B) 50%-85% of an olefin polymer partially soluble in xylene at room temperature, containing from 60% to 85% by weight of ethylene; said masterbatch composition having (i) a value of the intrinsic viscosity [?] of the fraction soluble in xylene at room temperature ([?]sol) equal to or lower than 2.9 dl/g, and (ii) a value of the ratio MFR/[?]sol equal to or lower than 4, is added to polyolefin materials to obtain final compositions suitable for injection molding.Type: ApplicationFiled: March 22, 2005Publication date: October 4, 2007Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: Anteo Pelliconi, Enea Garagnani, Giampaolo Pellegatti, Antonella Angelini
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Publication number: 20060235139Abstract: A polyolefin composition comprising (percentage by weight): (A) from 60 to 85% of a broad molecular weight distribution propylene polymer (component A) having a polydispersity index from 5 to 15 and melt flow rate of from 20 to 78 g/10 min (according to ASTM-D 1238, condition L); and (B) from 15 to 40% of a partially xylene-soluble olefin polymer rubber (component B) containing at least 65% by weight of ethylene. Said composition finds application in automotive field.Type: ApplicationFiled: August 3, 2004Publication date: October 19, 2006Applicant: BASELL POLIOLEFINE ITALIA S.P.A.Inventors: Enea Garagnani, Pelliconi Anteo
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Publication number: 20060155071Abstract: The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios r1·r2?; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.Type: ApplicationFiled: November 3, 2003Publication date: July 13, 2006Inventors: Giampiero Morini, Fabrizio Piemontesi, Gianni Vitale, Daniele Bigiavi, Anteo Pelliconi, Enea Garagnani, Pietro Baita
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Publication number: 20060084769Abstract: A process for preparing isotactic 1-butene copolymers containing up to 30% by mol of units derived from of one or more alpha olefins of formula CH2?CHZ, wherein Z is a C3C20 hydrocarbon group comprising contacting 1-butene and one or more of said alphaolefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) (1) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R1 and R3 are hydrocarbon groups; R2 and R4 are hydrogen atoms or hydrocarbon groups; T1 and T2, equal to or different from each other are a moiety of formula (II), (III) or (IV): wherein: the atom marked with the symbol * is bound the atom marked with the same symbol in formula (I); R5, R6, R7, R8 and R9, equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an aType: ApplicationFiled: November 14, 2003Publication date: April 20, 2006Inventors: Luigi Resconi, Anteo Pelliconi, Enea Garagnani
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Patent number: 6908967Abstract: Highly transparent and flexible elastoplastic polyolefin compositions which contain A) 10-20 parts by weight of a propylene homopolymer or copolymer with ethylene and/or one or more CH2?CHR ?-olefins, the copolymer containing at least 95% by weight of propylene; B) 5-20 parts by weight of propylene copolymer fraction containing ethylene and insoluble in xylene at room temperature; and C) 60-80 parts by weight of a propylene copolymer fraction containing a comonomer selected from ethylene and mixtures of ethylene with one or more CH2?CHR ?-olefin and soluble in xylene at room temperature, the fraction containing from 15 to 25% by weight of the comonomer, the percent by weight of the sum of the B and C components with respect to the total polyolefin composition being from 80% to 90%.Type: GrantFiled: November 27, 2002Date of Patent: June 21, 2005Assignee: Basell Poliolefine Italia S.p.A.Inventors: Gianni Collina, Anteo Pelliconi, Enea Garagnani
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Publication number: 20050113521Abstract: A masterbatch composition comprising (1) 10-50 wt % of a crystalline propylene homopolymer and (2) 50-90 wt % of a blend consisting of (a) a copolymer of ethylene and one or more C4-CIO a-olefin(s), containing 10-40 of C4-CIO a-olefin(s), and (b) an amorphous copolymer of propylene and ethylene. Copolymer (b) has an ethylene content from 20-70 wt %, and an intrinsic viscosity value of the xylene-soluble moiety of from 2.2 to 3.5 d/Lg, this value being equal to 0.8 to 1.2 times the intrinsic viscosity value of the xylene-soluble moiety of copolymer (a). The weight ratio of copolymers (a)/(b) is from 3/1 to 1/3. Polyolefin compositions comprising the said masterbatch composition are suitable for the manufacture of automotive parts.Type: ApplicationFiled: March 6, 2003Publication date: May 26, 2005Applicant: Basell Poliolefine Italia S.p. A.Inventors: Anteo Pelliconi, Enea Garagnani, Yutaka Yokoyama, Junichiro Washiyama, Hiroshi Takenouchi, Takeshi Nakajima
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Publication number: 20040198919Abstract: A polyolefin composition comprising: (A) from 8 to 25% by weight of a crystalline homopolymer or copolymer of propylene: (B) from 75 to 92% by weight of an elastomeric fraction comprising: (1) a first elastomeric copolymer of propylene with from 15 to 32% by weight at least one alpha-olefin of formula H2C═CHR, where R is H or a C2-6 linear or branched alkyl, optionally containing 0.5 to 5% by weight of a diene, said first elastomeric copolymer containing alpha-olefin, and having solubility in xylene at room temperature greater than 50% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from 3.0 to 5.0 dl/g; and (2) a second elastomeric copolymer of propylene with at least one alpha-olefin of formula H2C═CHR, where R is H or a C2-6 linear or branched alkyl, optionally containing 0.Type: ApplicationFiled: January 26, 2004Publication date: October 7, 2004Inventors: Anteo Pelliconi, Enea Garagnani, Alvaro Villanueva