Patents by Inventor Enea Garagnani

Enea Garagnani has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8039540
    Abstract: Polymer composition showing an improved balance of flexural modulus, IZOD impact strength and elongation at break comprising (percent by weight): A) a polymer blend comprising: A1) 50-70% of a crystalline propylene homopolymer or copolymer; and A2) 30-50% of one or more copolymer(s) of ethylene with one or more C4-C10 ?-olefin(s) containing from 15 to 35% of said C4-C10 ?-olefin(s); said polymer blend (A) having values of MFR equal to or higher than 10 g/10 min., a total content C4-C10 ?-olefin(s) equal to or higher than 8% and an intrinsic viscosity value of the fraction soluble in xylene at room temperature of from 1.3 to 2 dl/g, the amounts of (A1) and (A2) being referred to the total weight of the polymer blend; and optionally B) 1-15% of an elastomeric polymer different from A2), having a hardness (Shore A, ASTM D-2240) value equal to or lower than 90 points; and/or C) 0.5-20% of a mineral filler; the amounts of optional components (B) and (C) being referred to the total weight of the composition.
    Type: Grant
    Filed: May 30, 2005
    Date of Patent: October 18, 2011
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Anteo Pelliconi, Enea Garagnani
  • Patent number: 8008400
    Abstract: A masterbatch composition comprising (percent by weight): A) 50%-90% of a crystalline polypropylene component comprising: AI) from 25% to 75% of a fraction having a melt flow rate MFRI of from 0.1 to 10 g/10 min.; and AII) from 75% to 25% of a fraction having a melt flow rate value MFRII equal to or lower than 100 g/10 min.; wherein the ratio MFRI/MFRII is from 5 to 60; and B) 10%-50% of a copolymer component of ethylene and at least one C3-C10 ?-olefin, containing from 15% to 50% of ethylene; said masterbatch composition having a value of the intrinsic viscosity [?] of the fraction soluble in xylene at room temperature equal to or higher than 3.5 dl/g, is added to polyolefin materials to obtain final compositions suitable for injection molding.
    Type: Grant
    Filed: March 29, 2004
    Date of Patent: August 30, 2011
    Assignee: Basell Poliolenfine Italia s.r.l.
    Inventors: Anteo Pelliconi, Enea Garagnani, Gerald J. Ennis
  • Publication number: 20110136981
    Abstract: The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived units characterized by the following properties: d) Product of the reactivity ratios r1·r2?2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
    Type: Application
    Filed: January 26, 2011
    Publication date: June 9, 2011
    Applicant: BASELL POLIOLEFINE ITALIA S.P.A.
    Inventors: Giampiero Morini, Fabrizio Piemontesi, Gianni Vitale, Daniele Bigiavi, Anteo Pelliconi, Enea Garagnani, Pietro Baita
  • Patent number: 7943717
    Abstract: The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios r1·r2?2; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
    Type: Grant
    Filed: November 3, 2003
    Date of Patent: May 17, 2011
    Assignee: Basell Poliolefine Italia, S.p.A.
    Inventors: Giampiero Morini, Fabrizio Piemontesi, Gianni Vitale, Daniele Bigiavi, Anteo Pelliconi, Enea Garagnani, Pietro Baita
  • Patent number: 7728077
    Abstract: A masterbatch composition comprising (percent by weight): A) 15%-50% of a polypropylene component having a melt flow rate of from 1 to 250 g/10 min.; and B) 50%-85% of an olefin polymer partially soluble in xylene at room temperature, containing from 60% to 85% by weight of ethylene; said masterbatch composition having (i) a value of the intrinsic viscosity [?] of the fraction soluble in xylene at room temperature ([?]sol) equal to or lower than 2.9 dl/g, and (ii) a value of the ratio MFR/[?], , , , equal to or lower than 4, is added to polyolefin materials to obtain final compositions suitable for injection molding.
    Type: Grant
    Filed: March 22, 2005
    Date of Patent: June 1, 2010
    Assignee: Basell Pololefine Italia s.r.l.
    Inventors: Anteo Pelliconi, Enea Garagnani, Giampaolo Pellegatti, Antonella Angelini
  • Patent number: 7691939
    Abstract: A polyolefin composition comprising (percentage by weight): (A) from 60 to 85% of a broad molecular weight distribution propylene polymer (component A) having a polydispersity index from 5 to 15 and melt flow rate of from 20 to 78 g/10 min (according to ASTM-D 1238, condition L); and (B) from 15 to 40% of a partially xylene-soluble olefin polymer rubber (component B) containing at least 65% by weight of ethylene. Said composition finds application in automotive field.
    Type: Grant
    Filed: August 3, 2004
    Date of Patent: April 6, 2010
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Enea Garagnani, Anteo Pelliconi
  • Patent number: 7592393
    Abstract: A polyolefin composition comprising: (A) from 8 to 25% by weight of a crystalline homopolymer or copolymer of propylene: (B) from 75 to 92% by weight of an elastomeric fraction comprising: (1) a first elastomeric copolymer of propylene with from 15 to 32% by weight at least one alpha-olefin of formula H2C?CHR, where R is H or a C2-6 linear or branched alkyl, optionally containing 0.5 to 5% by weight of a diene, said first elastomeric copolymer containing alpha-olefin, and having solubility in xylene at room temperature greater than 50% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from 3.0 to 5.0 dl/g; and (2) a second elastomeric copolymer of propylene with at least one alpha-olefin of formula H2C?CHR, where R is H or a C2-6 linear or branched alkyl, optionally containing 0.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: September 22, 2009
    Assignee: Basel Poliolefine Italia S.p.A.
    Inventors: Anteo Pelliconi, Enea Garagnani, Alvaro Villanueva
  • Patent number: 7557161
    Abstract: Propylene polymer compositions comprising (by weight): A) from 15% to 60% with C4-C8 alpha-olefin(s), containing more than 10%, but less than 14%, of said C4-C8 alpha-olefins (s); B) from 40% to 85% of a copolymer of propylene with C4-C8 alpha-olefin(s), preferably butene, containing from 14% to 30% of said C4-C8 alpha-olefin(s), and optionally from 0.5% to 3% of ethylene; provided that the total content of C4-C8 alpha-olefin(s) in the propylene polymer composition be higher than 10%.
    Type: Grant
    Filed: October 4, 2002
    Date of Patent: July 7, 2009
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Anteo Pelliconi, Enea Garagnani, Paola Sgarzi
  • Patent number: 7538174
    Abstract: An isotactic 1-butene copolymer having a content up to 30% by mol of at least one alpha-olefin of formula CH2?CHZ derived units, wherein Z is a C3-C20 hydrocarbon group, having the following features: isotactic pentads (mmmm) >90%; and a percentage of soluble fraction in diethylether (% SD) and a molar content of said alpha olefins (% O) in the polymer chain meeting the following relation: % SD>2.8% O+8.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: May 26, 2009
    Assignee: Basell Polyolefine GmbH
    Inventors: Luigi Resconi, Anteo Pelliconi, Enea Garagnani
  • Patent number: 7534848
    Abstract: A process comprising contacting 1-butene and one or more alpha-olefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R1 and R3 are hydrocarbon groups; R2 and R4 are hydrogen atoms or hydrocarbon groups; T1 and T2, equal to or different from each other are a moiety of formula (II), (III) or (IV): wherein: R5, R6, R7, R8 and R9, equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an alkylmetallocene cation.
    Type: Grant
    Filed: November 14, 2003
    Date of Patent: May 19, 2009
    Assignee: Basell Polyolefine GmbH
    Inventors: Luigi Resconi, Anteo Pelliconi, Enea Garagnani
  • Publication number: 20080249273
    Abstract: An isotactic 1-butene copolymer having a content up to 30% by mol of at least one alpha-olefin of formula CH2?CHZ derived units, wherein Z is a C3-C20 hydrocarbon group, having the following features: isotactic pentads (mmmm) >90%; and a percentage of soluble fraction in diethylether (% SD) and a molar content of said alpha olefins (% O) in the polymer chain meeting the following relation: % SD>2.8% O+8.
    Type: Application
    Filed: October 30, 2007
    Publication date: October 9, 2008
    Applicant: Basell Polyolefine GmbH
    Inventors: Luigi Resconi, Anteo Pelliconi, Enea Garagnani
  • Publication number: 20080071019
    Abstract: Polymer composition showing an improved balance of flexural modulus, IZOD impact strength and elongation at break comprising (percent by weight): A) a polymer blend comprising: A1) 50-70% of a crystalline propylene homopolymer or copolymer; and A2) 30-50% of one or more copolymer(s) of ethylene with one or more C4-C10 ?-olefin(s) containing from 15 to 35% of said C4-C10 ?-olefin(s); said polymer blend (A) having values of MFR equal to or higher than 10 g/10 min., a total content C4-C10 ?-olefin(s) equal to or higher than 8% and an intrinsic viscosity value of the fraction soluble in xylene at room temperature of from 1.3 to 2 dl/g, the amounts of (A1) and (A2) being referred to the total weight of the polymer blend; and optionally B) 1-15% of an elastomeric polymer different from A2), having a hardness (Shore A, ASTM D-2240) value equal to or lower than 90 points; and/or C) 0.5-20% of a mineral filler; the amounts of optional components (B) and (C) being referred to the total weight of the composition.
    Type: Application
    Filed: May 30, 2005
    Publication date: March 20, 2008
    Applicant: BASELL POLIOLEFINE ITALIA S.R.1.
    Inventors: Anteo Pelliconi, Enea Garagnani
  • Patent number: 7288598
    Abstract: A masterbatch composition comprising (1) 10-50 wt % of a crystalline propylene homopolymer and (2) 50-90 wt % of a blend consisting of (a) a copolymer of ethylene and one or more C4-CIO a-olefin(s), containing 10-40 of C4-CIO a-olefin(s), and (b) an amorphous copolymer of propylene and ethylene. Copolymer (b) has an ethylene content from 20-70 wt %, and an intrinsic viscosity value of the xylene-soluble moiety of from 2.2 to 3.5 d/Lg, this value being equal to 0.8 to 1.2 times the intrinsic viscosity value of the xylene-soluble moiety of copolymer (a). The weight ratio of copolymers (a)/(b) is from 3/1 to 1/3. Polyolefin compositions comprising the said masterbatch composition are suitable for the manufacture of automotive parts.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: October 30, 2007
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Anteo Pelliconi, Enea Garagnani, Yutaka Yokoyama, Junichiro Washiyama, Hiroshi Takenouchi, Takeshi Nakajima
  • Publication number: 20070232765
    Abstract: A masterbatch composition comprising (percent by weight): A) 15%-50% of a polypropylene component having a melt flow rate of from 1 to 250 g/10 min.; and B) 50%-85% of an olefin polymer partially soluble in xylene at room temperature, containing from 60% to 85% by weight of ethylene; said masterbatch composition having (i) a value of the intrinsic viscosity [?] of the fraction soluble in xylene at room temperature ([?]sol) equal to or lower than 2.9 dl/g, and (ii) a value of the ratio MFR/[?]sol equal to or lower than 4, is added to polyolefin materials to obtain final compositions suitable for injection molding.
    Type: Application
    Filed: March 22, 2005
    Publication date: October 4, 2007
    Applicant: BASELL POLIOLEFINE ITALIA S.R.L.
    Inventors: Anteo Pelliconi, Enea Garagnani, Giampaolo Pellegatti, Antonella Angelini
  • Publication number: 20060235139
    Abstract: A polyolefin composition comprising (percentage by weight): (A) from 60 to 85% of a broad molecular weight distribution propylene polymer (component A) having a polydispersity index from 5 to 15 and melt flow rate of from 20 to 78 g/10 min (according to ASTM-D 1238, condition L); and (B) from 15 to 40% of a partially xylene-soluble olefin polymer rubber (component B) containing at least 65% by weight of ethylene. Said composition finds application in automotive field.
    Type: Application
    Filed: August 3, 2004
    Publication date: October 19, 2006
    Applicant: BASELL POLIOLEFINE ITALIA S.P.A.
    Inventors: Enea Garagnani, Pelliconi Anteo
  • Publication number: 20060155071
    Abstract: The present invention relates to butene-1 copolymers containing up to 40% by mol of ethylene and/or propylene derived characterized by the following properties: d) Product of the reactivity ratios r1·r2?; e) Content of butene-1 units in form of isotactic pentads (mmmm)>98%; and f) absence of 4,1 insertions of butene units.
    Type: Application
    Filed: November 3, 2003
    Publication date: July 13, 2006
    Inventors: Giampiero Morini, Fabrizio Piemontesi, Gianni Vitale, Daniele Bigiavi, Anteo Pelliconi, Enea Garagnani, Pietro Baita
  • Publication number: 20060084769
    Abstract: A process for preparing isotactic 1-butene copolymers containing up to 30% by mol of units derived from of one or more alpha olefins of formula CH2?CHZ, wherein Z is a C3C20 hydrocarbon group comprising contacting 1-butene and one or more of said alphaolefins under polymerization conditions in the presence of a catalyst system obtainable by contacting: (A) a metallocene compound of formula (I) (1) wherein: M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, are hydrogen atoms, halogen atoms, or an hydrocarbon group; L is a divalent bridging group; R1 and R3 are hydrocarbon groups; R2 and R4 are hydrogen atoms or hydrocarbon groups; T1 and T2, equal to or different from each other are a moiety of formula (II), (III) or (IV): wherein: the atom marked with the symbol * is bound the atom marked with the same symbol in formula (I); R5, R6, R7, R8 and R9, equal to or different from each other, are hydrogen or hydrocarbon groups; and (B) an alumoxane or a compound able to form an a
    Type: Application
    Filed: November 14, 2003
    Publication date: April 20, 2006
    Inventors: Luigi Resconi, Anteo Pelliconi, Enea Garagnani
  • Patent number: 6908967
    Abstract: Highly transparent and flexible elastoplastic polyolefin compositions which contain A) 10-20 parts by weight of a propylene homopolymer or copolymer with ethylene and/or one or more CH2?CHR ?-olefins, the copolymer containing at least 95% by weight of propylene; B) 5-20 parts by weight of propylene copolymer fraction containing ethylene and insoluble in xylene at room temperature; and C) 60-80 parts by weight of a propylene copolymer fraction containing a comonomer selected from ethylene and mixtures of ethylene with one or more CH2?CHR ?-olefin and soluble in xylene at room temperature, the fraction containing from 15 to 25% by weight of the comonomer, the percent by weight of the sum of the B and C components with respect to the total polyolefin composition being from 80% to 90%.
    Type: Grant
    Filed: November 27, 2002
    Date of Patent: June 21, 2005
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Gianni Collina, Anteo Pelliconi, Enea Garagnani
  • Publication number: 20050113521
    Abstract: A masterbatch composition comprising (1) 10-50 wt % of a crystalline propylene homopolymer and (2) 50-90 wt % of a blend consisting of (a) a copolymer of ethylene and one or more C4-CIO a-olefin(s), containing 10-40 of C4-CIO a-olefin(s), and (b) an amorphous copolymer of propylene and ethylene. Copolymer (b) has an ethylene content from 20-70 wt %, and an intrinsic viscosity value of the xylene-soluble moiety of from 2.2 to 3.5 d/Lg, this value being equal to 0.8 to 1.2 times the intrinsic viscosity value of the xylene-soluble moiety of copolymer (a). The weight ratio of copolymers (a)/(b) is from 3/1 to 1/3. Polyolefin compositions comprising the said masterbatch composition are suitable for the manufacture of automotive parts.
    Type: Application
    Filed: March 6, 2003
    Publication date: May 26, 2005
    Applicant: Basell Poliolefine Italia S.p. A.
    Inventors: Anteo Pelliconi, Enea Garagnani, Yutaka Yokoyama, Junichiro Washiyama, Hiroshi Takenouchi, Takeshi Nakajima
  • Publication number: 20040198919
    Abstract: A polyolefin composition comprising: (A) from 8 to 25% by weight of a crystalline homopolymer or copolymer of propylene: (B) from 75 to 92% by weight of an elastomeric fraction comprising: (1) a first elastomeric copolymer of propylene with from 15 to 32% by weight at least one alpha-olefin of formula H2C═CHR, where R is H or a C2-6 linear or branched alkyl, optionally containing 0.5 to 5% by weight of a diene, said first elastomeric copolymer containing alpha-olefin, and having solubility in xylene at room temperature greater than 50% by weight, the intrinsic viscosity of the xylene soluble fraction ranging from 3.0 to 5.0 dl/g; and (2) a second elastomeric copolymer of propylene with at least one alpha-olefin of formula H2C═CHR, where R is H or a C2-6 linear or branched alkyl, optionally containing 0.
    Type: Application
    Filed: January 26, 2004
    Publication date: October 7, 2004
    Inventors: Anteo Pelliconi, Enea Garagnani, Alvaro Villanueva