Abstract: The present invention is directed toward multilayer pressure-sensitive adhesive constructions with improved convertibility and aging. In one embodiment, the multilayer constructions have one layer formed of a first adhesive composition having a first glass transition temperature, and also having a tangent delta greater than about 0.5 at 102 radians per second at 20° C., and a storage modulus greater than about 3×108 dynes/cm2 at 104 radians per second at 20° C. At least a second adhesive layer is provided in the construction, the second adhesive layer comprising a second adhesive composition with a second glass transition temperature.

Abstract: There is provided an adhesive article including (a) a radiation curable adhesive layer comprising an acrylic pressure sensitive adhesive and, optionally, an acrylated urethane polymer; and (b) a transparent carrier layer. The adhesive article may contain a radiation curable epoxy layer between the radiation curable adhesive layer and the transparent carrier layer. This adhesive article is particularly useful in preparing protective coatings on color filters for use in a liquid-crystal display panel structure. The radiation curable epoxy layer and radiation curable pressure sensitive adhesive are applied to the color filter and then exposed to UV radiation The UV radiation exposure transforms the pressure sensitive adhesive from a removable adhesive to a permanent adhesive. The color filter with the UV cured adhesive layer is then baked to fully cure the adhesive layer and to transform the adhesive further into a near structural adhesive.

Abstract: A polypropylene based composition is described which comprises a mixture of (A) a propylene polymer or copolymer and (B) an alkylene-alkyl acrylate copolymer. These polypropylene based compositions are useful in the preparation of continuous films such as by extrusion, and the films can be oriented by stretching in the machine direction. The films prepared from the polypropylene compositions of this invention exhibit a variety of useful properties including the desired printability, stiffness, and die-cuttability to be useful as a facestock in preparing labels. Films prepared from the polypropylene based compositions of the invention also can be used as a base film, and the films can be overlaminated with a functional film. Machine-direction oriented monolayer and multilayer film facestocks for labels, and adhesive containing film labelstock for use in adhesive labels also are described.

Abstract: There is provided an adhesive article including (a) a radiation curable adhesive layer comprising an acrylic pressure sensitive adhesive and, optionally, an acrylated urethane polymer; and (b) a transparent carrier layer. The adhesive article may contain a radiation curable epoxy layer between the radiation curable adhesive layer and the transparent carrier layer. This adhesive article is particularly useful in preparing protective coatings on color filters for use in a liquid-crystal display panel structure. The radiation curable epoxy layer and radiation curable pressure sensitive adhesive are applied to the color filter and then exposed to UV radiation. The UV radiation exposure transforms the pressure sensitive adhesive from a removable adhesive to a permanent adhesive. The color filter with the UV cured adhesive layer is then baked to fully cure the adhesive layer and to transform the adhesive further into a near structural adhesive.

Abstract: A polypropylene based composition is described which comprises a mixture of (A) a propylene polymer or copolymer and (B) an alkylene-alkyl acrylate copolymer. These polypropylene based compositions are useful in the preparation of continuous films such as by extrusion, and the films can be oriented by stretching in the machine direction. The films prepared from the polypropylene compositions of this invention exhibit a variety of useful properties including the desired printability, stiffness, and die-cuttability to be useful as a facestock in preparing labels. Films prepared from the polypropylene based compositions of the invention also can be used as a base film, and the films can be overlaminated with a functional film. Machine-direction oriented monolayer and multilayer film facestocks for labels, and adhesive containing film labelstock for use in adhesive labels also are described.

Abstract: A method of making a cover comprising a pair of welded thermoplastic polymer sheets having therebetween a stiffener. A stiffener is provided such that the stiffener has a leading edge, a trailing edge, and two side edges. A pair of thermoplastic polymer sheets are positioned on opposite sides of the stiffener. The thermoplastic polymer sheets each have two side edges substantially parallel to the side edges of the stiffener. The thermoplastic polymer sheets are ultrasonically welded around the periphery of the stiffener. The polymer sheets are cut to form a leading edge and trailing edge which are substantially parallel to the leading edge and trailing edge of the stiffener. The thermoplastic polymer is typically selected from the group consisting of polypropylene and a copolymer of ethylene or butene and propylene, the weight percent of ethylene or butene being between about 1 wt. % to about 10 wt.

Abstract: This invention relates to a method for selecting a substrate intended for use in a cutting operation. The method is particularly suitable for selecting facestock materials intended for use in making pressure-sensitive adhesive (PSA) constructions such as PSA labels. The method includes the following steps (A)-(D). Step (A) involves cutting the substrate during a first cutting step to form at least two shapes in the substrate. The shapes are positioned in spaced relationship to each other. A matrix is formed during this cutting step. The matrix is the waste substrate material around the shapes. Step (B) involves cutting the substrate with a second cutting step to form a test sample. The test sample is comprised of part of one shape, part of the next adjacent shape, and the matrix around the shape parts. Step (C) involves separating the matrix from the shape parts while measuring the force required to separate the matrix from the shape parts and measuring the displacement of the separating force.

Abstract: The present invention is directed toward a multilayer, pressure-sensitive adhesive construction wherein one layer is formed of a first adhesive composition having a first glass transition temperature, and at least a second layer is formed of a second adhesive composition having a second glass transition temperature. The first glass transition temperature differs from the second glass transition temperature by from about 10.degree. C. to about 50.degree. C.

Abstract: A release liner providing a release surface which comprises a first olefin polymer film formed having dispersed therein by high shear mixing a release substance which is polyethyleneimine octadecyl carbamide, polyvinyl octadecyl carbamate or a mixture thereof, coextruded or cocast onto a film formed from a second olefin polymer. The release liner has particular utility in diaper tape application.

Abstract: A refastenable diaper is provided with a securing zone on the diaper outer cover of a peak strength of less than 2750 grams/inch. A refastenable adhesive taping system for the diaper includes an adhesive fastening tape comprising a flexible backing and a layer of pressure-sensitive adhesive permanently combined to said flexible backing and adapted to be applied to and released from the securing zone to fasten and open the diaper. The adhesive exhibits a 180.degree. peel adhesion of the tape to the securing zone that is less than the peak strength of the securing zone. The adhesive is selected to be within a specified rheological window, that is, have a maximum tan delta, or (tan delta).sub.max, of from 1.5 to 2.5 at 20.degree. C., reached at a frequency, or (w).sub.max, of greater than 500 rad/sec.

Abstract: A fluorophore is added to or chemically attached to a curable release coating and the release coating is applied to a substrate. By exposing the release coating to an ultraviolet light source and measuring the intensity ratio of the dimer to monomer fluorescence, the cure of the release coating can be monitored. This method can be used as an on-line cure monitor in order to determine and control the extent of cure of coated substrates particularly silicone release liners.

Abstract: Pyrene based fluorescent organopolysiloxanes which bear two or more reactive silicon-bonded sites are useful as durable markers and indicators of the degree of cure in curable silicone compositions. Having more than one reactive site the compounds participate in the curing reaction of the curable composition and thus do not adversely affect its curing behavior. The resulting fluorescent curable compositions are particularly useful in the preparation of adhesive-release coatings.

Abstract: A porous polyfluoroalkylene sheet, very preferably of polytetrafluoroethylene, which is suitable for use as a separator in an electrolytic cell, such as one used for the electrolysis of brine, has a porosity in the range of 70 to 90%, a thickness in the range of 0.2 to 3.5 mm. and at least one of (a) an A X-ray ratio in the range of 0.1 to 0.35 and (b) a B X-ray ratio in the range of 0.75 to 0.98. Preferably the A X-ray ratio is in the range of 0.1 to 0.3, the B.sub.2 X-ray ratio is in the range of 0.75 to 0.98 and the B.sub.1 X-ray ratio is in the range of 0.1 to 0.32. The porous sheets are incorporated in separators or diaphragms for electrolytic cells and the uses of such separators and cells in electrolysis processes, preferably in the electrolysis of brine, are described. Also shown in the specification are a method for the manufacture of the porous sheets and a method for ascertaining which milled, sintered and leached porous sheets are more suitable for use in electrolytic processes.

Abstract: A porous polyfluoroalkylene sheet, very preferably of polytetrafluoroethylene, which is suitable for use as a separator in an electrolytic cell, such as one used for the electrolysis of brine, has a porosity in the range of 70 to 90%, a thickness in the range of 0.2 to 3.5 mm. and at least one of (a) an A X-ray ratio in the range of 0.1 to 0.35 and (b) a B X-ray ratio in the range of 0.75 to 0.98. Preferably the A X-ray ratio is in the range of 0.1 to 0.3, the B.sub.2 X-ray ratio is in the range of 0.75 to 0.98 and the B.sub.1 X-ray ratio is in the range of 0.1 to 0.32. The porous sheets are separators or diaphragms for electrolytic cells and the uses of such separators and cells in electrolysis processes, preferably in the electrolysis of brine, are described. Also known in the specification are a method for the manufacture of the porous sheets and a method for ascertaining which milled, sintered and leached porous sheets are more suitable for use in electrolytic processes.