Patents by Inventor Eric Benazzi

Eric Benazzi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8318006
    Abstract: The present invention concerns an improved once-through process for hydrocracking hydrocarbon-containing feeds with high nitrogen contents, with partial elimination of ammonia, for example by a hot flash located between the hydrorefining zone and the hydrocracking zone. Said hot flash drum functions at a pressure close to that of the hydrorefining reactor and at a temperature in the range from 150° C. to the hydrorefining reactor outlet temperature.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: November 27, 2012
    Assignee: IFP Energies Nouvelles
    Inventors: Eric Benazzi, Pierre Marion, Christophe Gueret
  • Patent number: 7704378
    Abstract: The invention relates to a process for preparing middle distillates from a paraffinic feedstock produced by Fischer-Tropsch synthesis, using a hydrocracking/hydroisomerization catalyst which comprises at least one hydrodehydrogenating element chosen from the group formed by the noble elements of Group VIII of the periodic table, a silica-alumina-based non-zeolitic support obtained from wherein the non-zeolitic silica-alumina based support was obtained from a process comprising starting from a mixture of a partially soluble alumina compound in an acid medium with a totally soluble silica compound or with a totally soluble combination of alumina and hydrated silica, the resultant moldable mixture is concentrated to form a moldable mixture, the resultant mixture is molded and the resultant molded article is subjected to a hydrothermal or thermal treatment.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: April 27, 2010
    Assignees: Institut Francais du Petrole, ENI S.p.A.
    Inventors: Eric Benazzi, Patrick Euzen
  • Patent number: 7540951
    Abstract: A process for preparation of synthetic crude from a deposit of heavy crude, comprises: (a) the extraction of heavy crude by technology using steam; (b) the separation of crude extract and water; (c) the separation of crude into at least one light fraction and one heavy fraction; (d) the conversion of the heavy fraction of separation into a lighter product, said converted product, and a residue; (e) optionally, the partial or total hydrotreatment of the converted product and/or the light fraction (or fractions) obtained during the separation c), (f) the combustion and/or gasification of the conversion residue; the converted product and the light fraction (or fractions) for separation, optionally having been subjected to a hydrotreatment e), constituting the synthetic crude; said combustion allowing the generation of steam and/or electricity and said gasification allowing the generation of hydrogen; the steam and/or electricity thus generated being used for the extraction a) and/or the electricity and/or hydrog
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: June 2, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Arnault Selmen, Thierry Gauthier, Mathieu Pinault, Eric Benazzi
  • Patent number: 7507325
    Abstract: The invention relates to a process and installation for treating heavy petroleum feedstocks for producing a gas oil fraction that has a sulfur content of less than 50 ppm and most often 10 ppm that includes the following stages: a) mild hydrocracking in a fixed catalyst bed, b) separation from hydrogen sulfide of a distillate fraction that includes a gas oil fraction and a heavier fraction than the gas oil, c) hydrotreatment (including desulfurization) of said distillate fraction, and d) separation of a gas oil fraction with less than 50 ppm of sulfur. Advantageously, the heavy fraction is sent into catalytic cracking. The process preferably operates with make-up hydrogen that is brought to stage c), and very advantageously all of the make-up hydrogen of the process in introduced in stage c).
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: March 24, 2009
    Assignee: Institut Francais du Petrole
    Inventors: Christophe Gueret, Pierre Marion, Cecile Plain, Jerome Bonnardot, Eric Benazzi, Olivier Martin
  • Patent number: 7449421
    Abstract: A catalyst comprising at least one zeolite (molecular sieve) chosen from the group formed by the TON structure type zeolites (Theta-1, ZSM-22, ISI-1, NU-10 and KZ-2) and at least one zeolite chosen from the group formed by the zeolites (ZSM-48, EU-2, EU-11 and ZBM-30), at least one porous mineral matrix, at least one hydro-dehydrogenating element, preferably chosen from the elements of Group VIB and Group VIII of the periodic table, is used for the conversion of hydrocarbons, in particular for the reduction of the pour point of charges containing long (more than 10 carbon atoms) linear and/or slightly branched paraffins, in particular in order to convert, with a good yield, charges having high pour points to at least one cut having a low pour point and a high viscosity index for oil bases.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: November 11, 2008
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Emmanuelle Guillon, Johan Martens
  • Patent number: 7404890
    Abstract: The invention concerns a process and apparatus wherein the paraffin effluent from the Fischer-Tropsch process is separated into a heavy fraction with an initial boiling point of 120-200° C., said heavy fraction then optionally being hydrotreated then brought into contact with an amorphous hydroisomerization/hydrocracking catalyst that converts at least 80% by weight of the 370° C.+ products into products with a boiling point of less than 370° C. After distilling the hydrocracked fraction obtained to separate middle distillates, the residual heavy fraction is recycled.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: July 29, 2008
    Assignees: Institut Francais du Petrole, Agip Petroli S.p.A., Eni S.p.A, Lini Technologie S.p.A.
    Inventors: Eric Benazzi, Christophe Gueret
  • Patent number: 7390393
    Abstract: The invention relates to a process for treating heavy petroleum feedstocks for producing a gas oil fraction that has a sulfur content of less than 50 ppm and most often 10 ppm that includes the following stages: a) ebulliated-bed catalytic hydrocracking, b) separation from hydrogen sulfide of a distillate fraction that includes a gas oil fraction and a heavier fraction than the gas oil, c) hydrotreatment of said distillate fraction, and d) separation of a gas oil fraction with less than 50 ppm of sulfur. Make-up hydrogen, preferably all make-up hydrogen, is to stage c). Advantageously, the heavier fraction from step (b) is subjected to catalytic cracking. The invention also relates to an installation that can be used for implementing this process.
    Type: Grant
    Filed: August 17, 2006
    Date of Patent: June 24, 2008
    Assignee: Institute Francais du Petrole
    Inventors: Christophe Gueret, Pierre Marion, Cecile Plain, Jerome Bonnardot, Eric Benazzi, Olivier Martin
  • Patent number: 7381321
    Abstract: Process for transforming a gas-oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a hydrocracking stage, whereby the latter uses a catalyst that contains at least one zeolite. The conversion of products that have a boiling point of less than 150° C. is, throughout the two stages of hydrocracking and hydrorefining, less than 40% by weight and, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the hydrocracking stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: June 3, 2008
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Pierre Marion
  • Patent number: 7371315
    Abstract: A process for production of very high-quality base oils, and simultaneous production of high-quality middle distillates, comprises the successive stages of hydroisomerization and catalytic dewaxing. The hydroisomerization takes place in the presence of a catalyst containing at least one noble metal deposited on an amorphous acid support, the metal dispersion being less than 20%. The support is preferably an amorphous silica-alumina. The catalytic dewaxing takes place in the presence of a catalyst containing at least one hydrodehydrogenating element (Group VIII) and at least one molecular sieve chosen from ZBM-30, EU-2, and EU-11.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: May 13, 2008
    Assignee: Institut Francáis du Petrole
    Inventors: Eric Benazzi, Nathalie Marchal-George, Tivadar Cseri, Pierre Marion, Christophe Gueret, Slavik Kasztelan
  • Patent number: 7332071
    Abstract: Process for transforming a gas oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a subsequent stage, whereby the latter uses a catalyst that is selected from the group that consists of hydrorefining catalysts and catalysts that comprise at least one mixed oxide, a metal of group VIB, and a non-noble metal of group VIII. The conversion of products that have a boiling point of less than 150° C. is, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the subsequent stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: February 19, 2008
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Pierre Marion
  • Patent number: 7326331
    Abstract: The invention concerns a process for producing middle distillates from effluents obtained from the Fischer-Tropsch process, comprising separating a heavy cut with an initial boiling point of 120-200° C., hydrotreating said cut and fractionating the hydrotreated cut to obtain at least one intermediate fraction and at least one fraction that is heavier than the intermediate fraction. The intermediate fraction boils between T1 and T2, T1 being in the range 120-200° C. and T2 being in the range 300-410° C. The heavy and intermediate fractions are treated over a hydrocracking/hydroisomerisation catalyst and the effluents obtained are distilled. The invention also concerns a unit.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: February 5, 2008
    Assignees: Institut Francais du Petrole, AGIP Petroli, ENI S.p.A., Enitechnologies E Uffici Di Via
    Inventors: Eric Benazzi, Christophe Gueret
  • Patent number: 7300900
    Abstract: A hydrocracking catalyst containing at least one matrix, at least one zeolite chosen from the group formed by the zeolites ZBM-30, ZSM-48, EU-2, and EU-11, at least one Y zeolite, at least one hydro-dehydrogenating metal chosen from the group formed by the metals from Group VIB and Group VIII of the periodic table, optionally at least one element chosen from the group formed by phosphorus, boron and silicon, optionally at least one element from Group VIIA, and optionally at least one element from Group VIIB is used in a process of hydrocracking/hydroconversion of hydrocarbon charges.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: November 27, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Emmanuelle Guillon, Johan Martens
  • Patent number: 7282465
    Abstract: A catalyst comprising at least one ZBM-30 zeolite, synthesized in the presence of a particular structuring agent such as triethylenetetramine, at least one porous mineral matrix, at least one hydro-dehydrogenating element, preferably chosen from the elements of Group VIB and Group VIII of the periodic table, is used in order to improve the pour point of charges containing long (more than 10 carbon atoms) linear and/or slightly branched paraffins, in particular in order to convert, with a good yield, charges having high pour points to at least one cut having a low pour point and a high viscosity index for oil bases.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: October 16, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Emmanuelle Guillon, Johan Martens
  • Patent number: 7270738
    Abstract: This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 ?, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 ?, of less than 0.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: September 18, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Patrick Euzen, Carole Bobin, Magalie Roy-Auberger, Eric Benazzi, Patrick Bourges, Christophe Gueret
  • Patent number: 7267758
    Abstract: For producing very high quality base stock and for simultaneously producing high quality middle distillates, successive hydroisomerisation and catalytic dewaxmg steps are employed wherein the hydroisomerisation is carried out in the presence of a catalyst containing at least one noble metal deposited on an amorphous acidic support, the dispersion of the metal being 20%-100%. The support is preferably an amorphous silica-alumina. Catalytic dewaxing is carried out in the presence of a catalyst containing at least one hydrodehydrogenating element (group VIII) and at least one molecular sieve selected from ZBM-30, EU-2 and EU-11.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: September 11, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie Marchal-George, Tivadar Cseri, Pierre Marion, Christophe Gueret
  • Patent number: 7250107
    Abstract: For producing basic oils and in particular very high quality oils, i.e. oils possessing a high viscosity index (VI), a low aromatics content, good UV stability and a low pour point, from oil cuts having an initial boiling point higher than 340° C., possibly with simultaneous production of middle distillates (in particular gasoils and kerosene) of very high quality, i.e. having a low aromatics content and a low pour point, the invention provides a flexible procedure for producing oils and middle distillates from a charge containing heteroatoms, i.e. containing more than 200 ppm by weight of nitrogen, and more than 500 ppm by weight of sulphur. The procedure comprises at least one hydrorefining stage, at least one stage of catalytic dewaxing on zeolite, and at least one hydrofinishing stage.
    Type: Grant
    Filed: July 23, 2001
    Date of Patent: July 31, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Christophe Gueret, Pierre Marion, Alain Billon
  • Patent number: 7250106
    Abstract: For the production of high quality base oils with production of high quality middle distillates, feedstocks are obtained from the distillation of crude or from units for transformation and refining of the latter, there are provided a converting pretreatment stage of the feedstock and a catalytic dewaxing stage. The converting pretreatment stage occurs in the presence of a catalyst containing at least one noble metal deposited on an acid substrate in particular silica-alumina, to effect hydrocracking and hydroisomerization reactions. The catalytic dewaxing occurs in the presence of a catalyst with a zeolite base that is preferably selected from zeolites of the TON-structural type (theta-1, ISI-1, ZSM-22, KZ-2, NU-10), and the zeolites ZSM-48, ZBM-30, EU-2, EU-11, ferrierite, EU-1 and EU-13, and the catalyst also contains at least one hydro-dehydrogenating element.
    Type: Grant
    Filed: October 30, 2003
    Date of Patent: July 31, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Patrick Euzen
  • Patent number: 7220349
    Abstract: The invention concerns a process for producing middle distillates from an effluent produced by a Fischer-Tropsch unit, comprising optional fractionation to obtain at least one heavy fraction with an initial boiling point in the range 120-200° C., said heavy fraction or said effluent optionally being hydrotreated, then bringing it into contact with a first amorphous hydrocracking/hydroisomerization catalyst that contains at least one noble group VIII metal, the effluent obtained is distilled, then the residual fraction boiling above the middle distillates and/or a portion of the middle distillates is brought into contact with a second amorphous hydrocracking/hydroisomerization catalyst containing at least one noble group VIII metal. The invention also concerns a unit.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: May 22, 2007
    Assignees: Institut Francais du Petrole, AGIP Petroli S.p.A., ENI S.p.A., EniTecnolgie SpA
    Inventors: Eric Benazzi, Christophe Gueret
  • Publication number: 20070045155
    Abstract: A process for preparation of synthetic crude from a deposit of heavy crude, comprises: (a) the extraction of heavy crude by technology using steam; (b) the separation of crude extract and water; (c) the separation of crude into at least one light fraction and one heavy fraction; (d) the conversion of the heavy fraction of separation into a lighter product, said converted product, and a residue; (e) optionally, the partial or total hydrotreatment of the converted product and/or the light fraction (or fractions) obtained during the separation c), (f) the combustion and/or gasification of the conversion residue; the converted product and the light fraction (or fractions) for separation, optionally having been subjected to a hydrotreatment e), constituting the synthetic crude; said combustion allowing the generation of steam and/or electricity and said gasification allowing the generation of hydrogen; the steam and/or electricity thus generated being used for the extraction a) and/or the electricity and/or hydrog
    Type: Application
    Filed: August 23, 2006
    Publication date: March 1, 2007
    Inventors: Arnault Selmen, Thierry Gauthier, Mathieu Pinault, Eric Benazzi
  • Patent number: 7160436
    Abstract: An improved hydrocracking process of hydrocarbon charges, in two stages with an intermediate separation, in which the second-stage of hydrocracking is carried out in the presence of an added nitrogen content which is greater than 150 ppm by weight, preferably about 500 ppm by weight, and preferably in the presence of a Y zeolite catalyst, produces high yields of middle distillate.
    Type: Grant
    Filed: July 26, 2001
    Date of Patent: January 9, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Jean-Marie Deves, Pierre Marion, Christophe Gueret, Alain Billon, Patrick Bourges