Patents by Inventor Esko Tirronen

Esko Tirronen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9580865
    Abstract: The invention relates to a method for dissolving cationic starch. In the method is obtained an aqueous polyelectrolyte solution comprising a synthetic cationic polymer, which has a charge density value of at least 0.1 meq/g, determined at pH3, the concentration of the cationic polymer in the polyelectrolyte solution being >2.5 weight-%, and the aqueous polyelectrolyte solution is brought together with cationic starch having a degree of substitution, DS, >0.1. The cationic starch is dissolved to the polyelectrolyte solution by heating and/or mixing. The invention relates also to a papermaking agent comprising 2-40 weight-% of synthetic cationic polymer which has a charge density value of at least 0.1 meq/g, determined at p H 3, and 2.5-25 weight-% cationic starch having degree of substitution, DS, >0.1. The papermaking agent is in slurry form and has a viscosity of 50-20 000 m Pas, measured at 25° C. with Brookfield DVI+ viscometer.
    Type: Grant
    Filed: March 22, 2013
    Date of Patent: February 28, 2017
    Assignee: Kemira OYJ
    Inventors: Asko Karppi, Esko Tirronen
  • Patent number: 9290393
    Abstract: Processes for forming high iron content ferric chloride solutions, reconstituting ferric chloride solutions, and transporting the stable ferric chloride solutions with the high iron content are disclosed.
    Type: Grant
    Filed: November 30, 2011
    Date of Patent: March 22, 2016
    Assignee: KEMIRA OYJ
    Inventors: Krister Eskilsson, Stig Gunnarsson, Jeffrey Campbell, Jan Pavlicek, Faziollah Azarnoush, Esko Tirronen
  • Patent number: 9073847
    Abstract: The present invention relates to a method and an arrangement for separation and recovery of at least one carboxylic acid and furfural from a dilute aqueous mixture thereof. In the method of the present invention a dilute aqueous mixture comprising at least one carboxylic acid and furfural is extracted with methyltetrahydrofurane, and at least one carboxylic acid and furfural are recovered. The arrangement of the present invention comprises an extraction unit 302 for carrying out extraction of at least one carboxylic acid and furfural from dilute aqueous mixture with methyltetrahydrofuran, connected to distillation unit 307 for carrying out distillation of the extract 305 from the extraction unit 302, and connected to acids distillation unit 320 for carrying out distillation of the bottom stream 308 from the distillation unit 307 to separate at least one carboxylic acid and furfural.
    Type: Grant
    Filed: November 2, 2012
    Date of Patent: July 7, 2015
    Assignee: TAMINCO FINLAND
    Inventors: Esko Tirronen, Antero Laitinen, Jukka Hietala
  • Patent number: 9024066
    Abstract: The present invention provides a method for purifying and recovering propionic acid from an aqueous mixture containing a fermentation product obtained from a fermentation process using glycerol as substrate, the method comprising optionally acidifying the aqueous mixture to a pH below 4.5, subjecting the aqueous mixture to an extraction with extracting agent containing a heavy extractant and optionally a light extractant as a diluent to obtain an extract comprising the extracting agent and organic acids, and a raffinate comprising water and any unreacted glycerol, and subjecting the extract to vacuum evaporation to separate propionic acid-containing organic acids from the extractant.
    Type: Grant
    Filed: November 26, 2012
    Date of Patent: May 5, 2015
    Assignee: Taminco Finland
    Inventors: Tom Granstrom, Juhana Ahola, Jukka Hietala, Esko Tirronen
  • Publication number: 20150068697
    Abstract: The invention relates to a method for dissolving cationic starch. In the method is obtained an aqueous polyelectrolyte solution comprising a synthetic cationic polymer, which has a charge density value of at least 0.1 meq/g, determined at pH3, the concentration of the cationic polymer in the polyelectrolyte solution being >2.5 weight-%, and the aqueous polyelectrolyte solution is brought together with cationic starch having a degree of substitution, DS, >0.1. The cationic starch is dissolved to the polyelectrolyte solution by heating and/or mixing. The invention relates also to a papermaking agent comprising 2-40 weight-% of synthetic cationic polymer which has a charge density value of at least 0.1 meq/g, determined at p H 3, and 2.5-25 weight-% cationic starch having degree of substitution, DS, >0.1. The papermaking agent is in slurry form and has a viscosity of 50-20 000 m Pas, measured at 25° C. with Brookfield DVI+ viscometer.
    Type: Application
    Filed: March 22, 2013
    Publication date: March 12, 2015
    Inventors: Asko Karppi, Esko Tirronen
  • Publication number: 20140330039
    Abstract: The present invention provides a method for purifying and recovering propionic acid from an aqueous mixture containing a fermentation product obtained from a fermentation process using glycerol as substrate, the method comprising optionally acidifying the aqueous mixture to a pH below 4.5, subjecting the aqueous mixture to an extraction with extracting agent containing a heavy extractant and optionally a light extractant as a diluent to obtain an extract comprising the extracting agent and organic acids, and a raffinate comprising water and any unreacted glycerol, and subjecting the extract to vacuum evaporation to separate propionic acid-containing organic acids from the extractant.
    Type: Application
    Filed: November 26, 2012
    Publication date: November 6, 2014
    Applicant: TAMINCO FINLAND
    Inventors: Tom Granstrom, Juhana Ahola, Jukka Hietala, Esko Tirronen
  • Publication number: 20140275581
    Abstract: The present invention relates to a method and an arrangement for separation and recovery of at least one carboxylic acid and furfural from a dilute aqueous mixture thereof. In the method of the present invention a dilute aqueous mixture comprising at least one carboxylic acid and furfural is extracted with methyltetrahydrofurane, and at least one carboxylic acid and furfural are recovered. The arrangement of the present invention comprises an extraction unit 302 for carrying out extraction of at least one carboxylic acid and furfural from dilute aqueous mixture with methyltetrahydrofuran, connected to distillation unit 307 for carrying out distillation of the extract 305 from the extraction unit 302, and connected to acids distillation unit 320 for carrying out distillation of the bottom stream 308 from the distillation unit 307 to separate at least one carboxylic acid and furfural.
    Type: Application
    Filed: November 2, 2012
    Publication date: September 18, 2014
    Applicant: TAMINCO FINLAND
    Inventors: Esko Tirronen, Antero Laitinen, Jukka Hietala
  • Publication number: 20130331601
    Abstract: The present invention relates to a method and an arrangement for recovery of at least one organic acid from a dilute aqueous solution thereof. In this method a complex between said organic acid and an extractant is formed by contacting the solution with a reactive extractant and dissolving the formed complex into said extractant thus forming an extractant phase. The organic acid is removed from the formed complex by esterification using an alcohol.
    Type: Application
    Filed: December 9, 2011
    Publication date: December 12, 2013
    Inventors: Esko Tirronen, Jukka Hietala, Reijo Aksela
  • Publication number: 20130236379
    Abstract: Processes for forming high iron content ferric chloride solutions, reconstituting ferric chloride solutions, and transporting the stable ferric chloride solutions with the high iron content are disclosed.
    Type: Application
    Filed: November 30, 2011
    Publication date: September 12, 2013
    Inventors: Krister Eskilsson, Stig Gunnarsson, Jeffrey Campbell, Jan Pavlicek, Faziollah Azarnoush, Esko Tirronen
  • Patent number: 8492586
    Abstract: Processes for the recovery of formate salt from biomass and the product obtained thereof generally include subjecting an aqueous liquid mixture containing levulinic acid, formic acid and possibly furfural to a liquid-liquid extraction process, followed by the recovery of the furfural, the formate salt and the levulinic acid or the levulinate salt.
    Type: Grant
    Filed: April 21, 2009
    Date of Patent: July 23, 2013
    Assignee: Kemira Oyj
    Inventors: Jarmo Reunanen, Pekka Oinas, Timo Nissinen, Esko Tirronen
  • Publication number: 20110098490
    Abstract: Processes for the recovery of formate salt from biomass and the product obtained thereof generally include subjecting an aqueous liquid mixture containing levulinic acid, formic acid and possibly furfural to a liquid-liquid extraction process, followed by the recovery of the furfural, the formate salt and the levulinic acid or the levulinate salt.
    Type: Application
    Filed: April 21, 2009
    Publication date: April 28, 2011
    Applicant: KEMIRA OYJ
    Inventors: Jarmo Reunanen, Pekka Oinas, Timo Nissinen, Esko Tirronen
  • Publication number: 20100062255
    Abstract: The invention relates to a gypsum product which consists of essentially intact crystals having a size of between 0.1 and below 2.0 ?m. The product is especially suitable as a coating pigment or filler in paper manufacture. The invention also relates to a process for the preparation of a gypsum product, wherein calcium sulphate hemihydrate and/or calcium sulphate anhydrite, water and a crystallization habit modifier are contacted so that the calcium sulphate hemihydrate and/or calcium sulphate anhydrite and the water are reacted with each other and form a crystalline gypsum product. The calcium sulphate hemihydrate and/or calcium sulphate anhydrite is/are used in such an amount that the reaction mixture formed from the calcium sulphate hemihydrate and/or calcium sulphate anhydrite, the water and the crystallization habit modifier has a dry matter content of between 50 and 84% by weight. Then, said gypsum product can be formed which consists of essentially intact crystals having a size of between 0.
    Type: Application
    Filed: February 1, 2008
    Publication date: March 11, 2010
    Inventors: Reijo Aksela, Outi Gronfors, Pasi Hagelberg, Perttu Heiska, Hanna-Mari Kangaslahti, Jori Kerala, Jarmo Reunanen, Esko Tirronen, Tarja Turkki
  • Patent number: 6429333
    Abstract: In a method for preparing formic acid, methyl formate is prepared with methanol as a reactant.
    Type: Grant
    Filed: June 19, 2001
    Date of Patent: August 6, 2002
    Assignee: Kemira Chemicals Oy
    Inventors: Kari Saari, Esko Tirronen, Antti Vuori, Marko Lahtinen