Abstract: Transfer tapes and methods of making transfer tapes are described. In one aspect, the transfer tape comprises a template layer having a structured surface; a backfill layer disposed on at least a portion of the template layer, the backfill layer having a microstructured surface opposite the structured surface; and a layer disposed adjacent the microstructured surface, wherein the layer disposed adjacent the microstructured surface has a refractive index that differs from the backfill layer. The microstructured surface together with the adjacent layer functions as a diffusive layer, or in other words a diffusive interface. Also described are microoptical glazing and methods of making microoptical glazing as well as insulated glazing units and methods of making insulated glazing units.

Abstract: Lamination transfer films and methods for transferring a structured layer to a receptor substrate. The transfer films include a carrier substrate having a releasable surface, a sacrificial template layer applied to the releasable surface of the carrier substrate and having a non-planar structured surface, and a thermally stable backfill layer applied to the non-planar structured surface of the sacrificial template layer. The sacrificial template layer is capable of being removed from the backfill layer, such as via pyrolysis, while leaving the structured surface of the backfill layer substantially intact.

Abstract: A transfer film is provided which includes a sacrificial template layer having a first surface and a second surface opposite the first surface, wherein the second surface comprises a non-planar structured surface and a thermally stable backfill layer applied to the second surface of the sacrificial template layer, wherein the backfill layer has a structured surface corresponding with and applied to the non-planar structured surface of the sacrificial template layer. The sacrificial template layer comprises oriented dimensionally anisotropic inorganic nanomaterials and is capable of being removed from the backfill layer while leaving the structured surface of the backfill layer and the oriented dimensionally anisotropic inorganic nanomaterials substantially intact.

Abstract: Transfer films, articles made therewith, and methods of making and using transfer films to form bridged nanostructures are disclosed.

Abstract: A polishing solution includes a fluid component and a plurality of conditioning particles. The fluid component includes water, a basic pH adjusting agent, and a polymeric thickening agent. The polymeric thickening agent is present in the fluid component at greater than 0.01 weight percent based on the total weight of the polishing solution.

Abstract: A transfer tape is disclosed that includes a carrier, a template layer having a first surface applied to the carrier and having a second surface opposite the first surface, wherein the second surface comprises a non-planar structured surface, a release coating disposed upon the non-planar structured surface of the template layer, and a backfill layer disposed upon and conforming to the non-planar structured surface of the release coating. In some embodiments, the backfill layer includes a silsesquioxane such as polyvinyl silsesquioxane. The disclosed transfer tape can be used to transfer replicated structures to a receptor substrate.

Abstract: A method of making patterned structured solid surfaces is disclosed that includes filling a structured template with backfill material to produce a structured transfer film, patternwise curing the backfill material to produce cured areas and uncured areas in the structured transfer film, and laminating the structured transfer film to a receptor substrate. The structured template is capable of being removed to form structured and unstructured backfill layers. The structured and unstructured backfill layers may then be blanket cured. The backfill layer can include at least two different materials, one of which can be an adhesion promotion layer. In some embodiments the backfill layer includes a silsesquioxane such as polyvinyl silsesquioxane. The structured transfer film is a stable intermediate that can be covered temporarily with a release liner for storage and handling.

Abstract: An electronically switchable privacy device suitable for use in display devices is described. The electronically switchable privacy device comprises a first transparent electrode layer, an electronically switchable layer disposed adjacent to the first transparent electrode layer, and a second transparent electrode layer disposed adjacent to the electronically switchable layer and opposite the first transparent electrode layer. The second transparent electrode layer comprises a transparent substrate layer having a plurality of microstructured ribs extending across a major surface of the transparent substrate layer such that the microstructured ribs form an alternating series of ribs and channels, each channel having channel walls defined by adjacent ribs.

Abstract: Transfer films comprising a carrier film, a sacrificial template layer deposed on the carrier film and comprising reentrant forming template features, and a thermally stable backfill layer having a first surface conforming to the reentrant forming template features and forming reentrant features and an opposing planar second surface; and methods of making transfer films are disclosed.

Abstract: Transfer films, articles made therewith, and methods of making and using transfer films to form bridged nanostructures are disclosed.

Abstract: Methods for transferring nanoparticles and nanowires to permanent glass receptors using transfer films. The transfer films include nanoparticles within a sacrificial material having a structured backfill layer on a substrate and a nanowire formulation between sacrificial substrates. To transfer the nanoparticles, the transfer film is laminated to a glass receptor, the substrate is removed, and the sacrificial material is baked-out to leave the nanoparticles aligned within the structured surface of the backfill layer on the glass receptor. To transfer the nanowires, the transfer film is laminated to a glass receptor, and the sacrificial substrates are baked-out to leave the nanowires aligned on the glass receptor.

Abstract: A method of forming a transfer film is described. The transfer film includes a template layer having a first major surface and an opposing second major surface. The second major surface includes a structured non-planar release surface. A backfill layer is disposed upon and conforms to the non-planar structured surface. The backfill layer includes a first cross-linked polymer and a plurality of multifunctional monomers, which cure via different and independent curing mechanisms.

Abstract: A transfer film includes a template layer having a first major surface and an opposing second major surface. The second major surface includes a structured non-planar release surface. A backfill layer is disposed upon and conforms to the non-planar structured surface. The backfill layer includes a first cross-linked polymer and a plurality of multifunctional monomers, which cure via different and independent curing mechanisms.

Abstract: Methods of making transfer films to form bridged nanostructures are disclosed. The methods include applying a thermally stable backfill layer to a structured surface of a sacrificial template layer.

Abstract: Transfer films, articles made therewith, and methods of making and using transfer films that include antireflective structures are disclosed.

Abstract: A method for forming patterns of organic polymer materials. The method can be used to form a layer with two patterned organic polymer materials. The photoresist and solvents used in the photoresist deposition and removal steps do not substantially affect the organic polymer materials.