Abstract: The present disclosure provides a method of flushing a reactor used in the production of linear alpha olefins, including flushing reactor equipment with toluene from a solvent source, wherein the reactor contains by-products from the production of the linear alpha olefins, wherein the by-products include a polymeric material. The flushed toluene containing polymeric material is directed into a separation train containing the linear alpha olefins, wherein the polymeric material is soluble in at least one of the linear alpha olefins. The linear alpha olefins can be separated from the toluene and the toluene is recycled to the solvent source.

Abstract: The present disclosure provides a method of flushing a reactor used in the production of linear alpha olefins, including flushing reactor equipment with toluene from a solvent source, wherein the reactor contains by-products from the production of the linear alpha olefins, wherein the by-products include a polymeric material. The flushed toluene containing polymeric material is directed into a separation train containing the linear alpha olefins, wherein the polymeric material is soluble in at least one of the linear alpha olefins. The linear alpha olefins can be separated from the toluene and the toluene is recycled to the solvent source.

Abstract: A method for removal of an organic amine from a hydrocarbon stream includes mixing the hydrocarbon stream including the amine with an aqueous inorganic acid in a volumetric ratio of hydrocarbon stream: aqueous inorganic acid of greater than 1.5:1 to 5:1, phase separating a hydrocarbon phase and an aqueous phase, removing the hydrocarbon phase, mixing the aqueous phase with an aqueous alkaline solution, phase separating the aqueous phase and an organic phase, and removing the organic phase. The aqueous inorganic acid has a concentration of greater than or equal to 30 weight percent. The disclosed method results in improved phase separation time during an amine removal process.