Abstract: The present invention provides uniaxially oriented films and packages formed from such films. In one aspect, a uniaxially oriented film includes (a) a first layer including (i) a first composition including an ethylene-based polymer prepared in the presence of a single-site catalyst, wherein the first composition has a density of 0.935 g/cm3 to 0.965 g/cm3, a melt index (12) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, and (ii) a Ziegler-Natta catalyzed ultra low density polyethylene having a density of 0.880 g/cm3 to 0.912 g/cm3, a melt index (12) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, (b) a second layer including at least one polyolefin, and (c) at least one inner layer between the first layer and the second layer including a high density polyethylene. The film is oriented in the machine direction at a draw ratio of between 4:1 and 10:1, and can exhibit a machine direction 2% secant modulus of 85,000 psi or more when measured as per ASTM D882.

Abstract: A film structure including: (a) at least one functionalized film layer, wherein the at least one film layer comprises a polar-reactive group polyolefin layer used as an internal layer in the film structure; and (b) a lamination adhesive composition present on, and in contact with, a least a portion of a surface of the internal layer; wherein the green tack value of the adhesive composition is greater than 0.772 Newtons/centimeter; a laminate including the above film structure bonded to a substrate layer; a process for producing the film structure; a process for producing the laminate; and a laminated article made from the above laminate.

Abstract: The present invention relates to a film structure comprising an outer layer, a core and an inner layer (or sealant layer). The outer layer comprises a polyolefinic material having a Vicat softening temperature of 85° C. or greater, and a total crystallinity in the range of 25 to 45%. The core comprises a linear low density polyethylene having a density of 0.925 g/cm3 or less, and a melt index of 4.0 g/10 min or less. The inner layer comprises linear low density polyethylene having a density of from 0.865 to 0.926 g/cm3 and a melt index of less than 4.0 g/10 minutes. The films of the present invention have less than 25% of polyethylenes having a density of 0.930 g/cm3 or greater. Further, the films of the present invention can be characterized by the substantial absence of polyamide, polyester, ethylene vinyl acetate, ionomers, polyvinyl chloride, and/or cyclic olefin polymers.

Abstract: The present invention provides uniaxially oriented films and packages formed from such films. In one aspect, a uniaxially oriented film comprises (a) a first layer comprising (i) a first composition comprising an ethylene-based polymer prepared in the presence of a single-site catalyst, wherein the first composition has a density of 0.935 g/cm3 to 0.965 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, and (ii) a Ziegler-Natta catalyzed ultra low density polyethylene having a density of 0.880 g/cm3 to 0.912 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, (b) a second layer comprising at least one polyolefin, and (c) at least one inner layer between the first layer and the second layer comprising a high density polyethylene. The film is oriented in the machine direction at a draw ratio of between 4:1 and 10:1, and can exhibit a machine direction 2% secant modulus of 85,000 psi or more when measured as per ASTM D882.

Abstract: A film structure including: (a) at least one functionalized film layer, wherein the at least one film layer comprises a polar-reactive group polyolefin layer used as an internal layer in the film structure; and (b) a lamination adhesive composition present on, and in contact with, a least a portion of a surface of the internal layer; wherein the green tack value of the adhesive composition is greater than 0.772 Newtons/centimeter; a laminate including the above film structure bonded to a substrate layer; a process for producing the film structure; a process for producing the laminate; and a laminated article made from the above laminate.

Abstract: A film structure including: (a) at least one functionalized film layer, wherein the at least one film layer comprises a polar-reactive group polyolefin layer used as an internal layer in the film structure; and (b) a lamination adhesive composition present on, and in contact with, a least a portion of a surface of the internal layer; wherein the green tack value of the adhesive composition is greater than 0.772 Newtons/centimeter; a laminate including the above film structure bonded to a substrate layer; a process for producing the film structure; a process for producing the laminate; and a laminated article made from the above laminate.

Abstract: The present invention provides uniaxially oriented films and packages formed from such films. In one aspect, a uniaxially oriented film comprises (a) a first layer including (i) a first composition including an ethylene-based polymer prepared in the presence of a single-site catalyst, wherein the first composition has a density of 0.935 g/cm3 to 0.965 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, and (ii) a Ziegler-Natta catalyzed ultra low density polyethylene having a density of 0.880 g/cm3 to 0.912 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, (b) a second layer including at least one polyolefin, and (c) at least one inner layer between the first layer and the second layer including a high density polyethylene. The film is oriented in the machine direction at a draw ratio of between 4:1 and 10:1, and can exhibit a machine direction 2% secant modulus of 85,000 psi or more when measured as per ASTM D882.

Abstract: A multilayer coextruded film which includes at least one oil and grease absorbing layer and at least one oil barrier layer. The at least one oil and grease absorbing layer includes at least one styrenic block copolymer. Each oil barrier layer includes one or more polyolefins. Some multilayer coextruded films include an interior sealing layer. Further multilayer coextruded films include an exterior finishing layer with the oil barrier layer and the oil and grease absorbing layer disposed between the interior sealing layer and the exterior finishing layer.

Abstract: The present invention provides uniaxially oriented films and packages formed from such films. In one aspect, a uniaxially oriented film comprises (a) a first layer comprising a polyolefm plastomer having a density of 0.865 to 0.908 g/cm3 and a melt index (I2) of 0.5-6 g/10 minutes, and at least one of a single-site catalyzed linear low density polyethylene having a density of 0.912 g/cm3 to 0.935 g/cm3 and a melt index (I2) of 0.5 to 6 g/10 minutes, or a Ziegler-Natta catalyzed ultra low density polyethylene having a density of 0.880 g/cm3 to 0.912 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less; (b) a second layer comprising a Ziegler-Natta catalyzed ultra low density polyethylene having a density of 0.880 g/cm3 to 0.912 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less; and (c) at least one inner layer between the first layer and the second layer comprising at least one polyolefin.

Abstract: The present invention provides uniaxially oriented films and packages formed from such films. In one aspect, a uniaxially oriented film comprises (a) a first layer comprising (i) a first composition comprising an ethylene-based polymer prepared in the presence of a single-site catalyst, wherein the first composition has a density of 0.935 g/cm3 to 0.965 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, and (ii) a Ziegler-Natta catalyzed ultra low density polyethylene having a density N of 0.880 g/cm3 to 0.912 g/cm3, a melt index (I2) of 0.5 to 6 g/10 minutes, and a MWD of 6.0 or less, (b) a second layer comprising at least one polyolefin, and (c) at least one inner layer between the first layer and the second layer comprising a high density polyethylene. The film is oriented in the machine direction at a draw ratio of between 4:1 and 10:1, and can exhibit a machine direction 2% secant modulus of 85,000 psi or more when measured as per ASTM D882.

Abstract: A multilayer structure comprising at least one barrier layer, said barrier layer including less than or equal to 12 percent, by weight of the barrier layer, of an anhydride and/or carboxylic acid functionalized ethylene/alpha-olefin interpolymer having a density in the range of from 0.855 to 0.900 g/cm3; and having a melt viscosity less than 50,000 cP at 350° F. (177° C.); and at least 60 percent, by weight of the barrier layer, of EVOH having from 10 to 32 mole percent units derived from ethylene monomer is provided. Further provided are thermoformed articles made therefrom.

Abstract: This invention relates to coupling of polyethylene resins, more specifically coupling of polyethylene resins for use in extruded profiles, especially extruded profiles for sheet extrusion and cut sheet thermoforming applications and geomembranes. The process involves conveying a HDPE resin through an extruder, wherein the extruder comprises a feed zone, a first melt zone downstream of the feed zone, a second melt zone downstream of the first melt zone, and a third melt zone downstream of the second melt zone. The resin is melted in the first zone, contacted with oxygen in the second melt zone, and contacted antioxidant in the third melt zone.

Abstract: The present invention relates to a film structure comprising an outer layer, a core and an inner layer (or sealant layer). The outer layer comprises a polyolefinic material having a Vicat softening temperature of 85° C. or greater, and a total crystallinity in the range of 25 to 45%. The core comprises a linear low density polyethylene having a density of 0.925 g/cm3 or less, and a melt index of 4.0 g/10 min or less. The inner layer comprises linear low density polyethylene having a density of from 0.865 to 0.926 g/cm3 and a melt index of less than 4.0 g/10 minutes. The films of the present invention have less than 25% of polyethylenes having a density of 0.930 g/cm3 or greater. Further, the films of the present invention can be characterized by the substantial absence of polyamide, polyester, ethylene vinyl acetate, ionomers, polyvinyl chloride, and/or cyclic olefin polymers.

Abstract: The present invention relates to the use of particular blends of LLDPE and LDPE together with specific fabrication conditions to make foamed sheets of thin gauge with MD tear properties similar to an equivalent gauge non-foamed sheet of the same composition. In particular, blends which combine a high MI LLDPE rich fraction with a low MI branched LDPE minor fraction provide the adequate balance of mechanical strength of the polymer base with its melt strength, extensibility and stress relaxation, allowing a thin foam film with MD tear strength which is comparable to non foamed counterparts of similar gauge and composition. The foamed films of the present invention are thin (generally from about 1 to 10 mils thick), and have an MD tear strength of at least about 160 grams for a 3 mil film as measured by ASTM D 1922. The foamed films of the present invention are preferably made at least in part from blends which comprise from 10 to 95 percent by weight of LLDPE having a relatively high (1.

Abstract: This invention relates to coupling of polyethylene resins, more specifically coupling of polyethylene resins for use in extruded profiles, especially extruded profiles for sheet extrusion and cut sheet thermoforming applications and geomembranes. The process involves conveying a HDPE resin through an extruder, wherein the extruder comprises a feed zone, a first melt zone downstream of the feed zone, a second melt zone downstream of the first melt zone, and a third melt zone downstream of the second melt zone. The resin is melted in the first zone, contacted with oxygen in the second melt zone, and contacted antioxidant in the third melt zone.