Abstract: In an embodiment, a method for decreasing reactor fouling in a steam cracking process is provided. The method includes steam cracking a hydrocarbon feed to obtain a quench oil composition comprising a concentration of donatable hydrogen of 0.5 wt. % or more based on a total weight percent of the quench oil composition; exposing a steam cracker effluent flowing from a pyrolysis furnace to the quench oil composition to form a mixture; and fractionating the mixture in a separation apparatus to obtain a steam cracker tar. In another embodiment, a hydrocarbon mixture is provided. The hydrocarbon mixture includes a mid-cut composition.

Abstract: Hydrocarbon-containing fluids are provided for use during solvent-assisted hydroprocessing of pyrolysis tar, such as steam cracker tar. The hydrocarbon-containing fluids can be used at any convenient time, such as during start-up of a pyrolysis process when recycled liquid pyrolysis product is not available; when the amount of liquid pyrolysis product available for recycle is not sufficient to maintain desired hydroprocessing conditions; and/or when the changes to the quality of the liquid pyrolysis product reduce the suitability of the recycle stream for use as a utility fluid.

Abstract: Processes for improving hydrocarbon feedstock compatibility are provided. More specifically, a process for preparing a liquid hydrocarbon product includes heat soaking a tar stream to produce a reduced reactivity tar and blending the reduced reactivity tar with a utility fluid comprising recycle solvent to produce a lower viscosity, reduced reactivity tar. The process also includes hydroprocessing the lower viscosity, reduced reactivity tar at a temperature of greater than 350° C. to produce a total liquids product containing the liquid hydrocarbon product and the recycle solvent. The process further includes separating the recycle solvent from the total liquids product, where the recycle solvent has the SBN of greater than 110, and flowing the recycle solvent to the reduced reactivity tar for blending to produce the lower viscosity, reduced reactivity tar.

Abstract: Processes for preparing a low particulate liquid hydrocarbon product are provided and include blending a tar stream containing particles with a fluid and heating to a temperature of 250° C. or greater to produce a fluid-feed mixture that contains tar, the particles, and the fluid. The fluid-feed mixture contains about 20 wt % or greater of the fluid, based on a combined weight of the tar stream and the fluid. Also, about 25 wt % to about 99 wt % of the particles in the tar stream are dissolved or decomposed when producing the fluid-feed mixture.

Abstract: Processes for preparing a low particulate liquid hydrocarbon product are provided and include blending a tar stream containing particles with a fluid and heating to a temperature of 250° C. or greater to produce a fluid-feed mixture that contains tar, the particles, and the fluid. The fluid-feed mixture contains about 20 wt % or greater of the fluid, based on a combined weight of the tar stream and the fluid. Also, about 25 wt % to about 99 wt % of the particles in the tar stream are dissolved or decomposed when producing the fluid-feed mixture.

Abstract: In an embodiment, a method for decreasing reactor fouling in a steam cracking process is provided. The method includes steam cracking a hydrocarbon feed to obtain a quench oil composition comprising a concentration of donatable hydrogen of 0.5 wt. % or more based on a total weight percent of the quench oil composition; exposing a steam cracker effluent flowing from a pyrolysis furnace to the quench oil composition to form a mixture; and fractionating the mixture in a separation apparatus to obtain a steam cracker tar. In another embodiment, a hydrocarbon mixture is provided. The hydrocarbon mixture includes a mid-cut composition.

Abstract: A process is described for upgrading pyrolysis tar, such as steam cracker tar, by hydroprocessing in the presence of a utility fluid. The hydroprocessing conditions comprise a pressure >8 MPa and a weight hourly space velocity of combined pyrolysis tar and utility fluid >0.3 hr?1 and are selected so that the hydrogen consumption rate is in the range of 270 to 445 standard cubic meters/cubic meter (S m3/m3) of pyrolysis tar.

Abstract: Processes for improving hydrocarbon feedstock compatibility are provided. More specifically, a process for preparing a liquid hydrocarbon product includes heat soaking a tar stream to produce a reduced reactivity tar and blending the reduced reactivity tar with a utility fluid comprising recycle solvent to produce a lower viscosity, reduced reactivity tar. The process also includes hydroprocessing the lower viscosity, reduced reactivity tar at a temperature of greater than 350° C. to produce a total liquids product containing the liquid hydrocarbon product and the recycle solvent. The process further includes separating the recycle solvent from the total liquids product, where the recycle solvent has the SBN of greater than 110, and flowing the recycle solvent to the reduced reactivity tar for blending to produce the lower viscosity, reduced reactivity tar.

Abstract: Methods to generate a model of composition for a petroleum sample can include providing a petroleum sample to a two-dimensional gas chromatograph coupled with at least one detector. The chromatograph can have first and second columns. The chromatograph can be adapted to output data for each detector representing first and second dimension retention times corresponding to the first and second columns, respectively. The data representing the first and second dimension retention times for each detector based on the petroleum sample can be obtained from the chromatograph. Molecular components of the petroleum sample can be identified based at least in part on the first and second dimension retention times for each detector. The identified molecular components of the petroleum sample can be quantified based at least in part on integrated peaks of the first and second dimension retention times for each detector to generate a model of composition of the petroleum sample.

Abstract: A process is described for upgrading pyrolysis tar, such as steam cracker tar, by hydroprocessing in the presence of a utility fluid. The hydroprocessing conditions comprise a pressure >8 MPa and a weight hourly space velocity of combined pyrolysis tar and utility fluid >0.3 hr?1 and are selected so that the hydrogen consumption rate is in the range of 270 to 445 standard cubic meters/cubic meter (S m3/m3) of pyrolysis tar.

Abstract: Adsorbent materials comprising a core, for example CHA, and at least one coating, for example DDR, are provided herein. Adsorbent contactors and gas separation processes using the adsorbent materials are also provided herein.

Abstract: Provided are processes for making saturated hydrocarbons from renewable feed sources. In an embodiment, a process for producing a lube basestock and/or a diesel fuel from a feedstock of biological origin includes: contacting the feedstock in a single reactor in the presence of hydrogen with catalyst components including a first catalyst and a second catalyst, wherein the first catalyst comprises an acidic material, a basic material, or a combination of both, and wherein the second catalyst is a hydrogenation catalyst including a hydrothermally stable binder.

Abstract: Adsorbent materials comprising a core, for example CHA, and at least one coating, for example DDR, are provided herein. Adsorbent contactors and gas separation processes using the adsorbent materials are also provided herein.

Abstract: The thermally modulated, two-dimensional gas chromatographic separation of a mixture of compounds with boiling points higher than 260° C. uses a cold trap with a gas jet at ambient temperatures.

Abstract: The distribution of nitrogen species in a long chain alkenyl succinimide dispersants is quantitated and speciated by means of 15N nuclear magnetic resonance spectroscopy.

Abstract: The nitrogen species in a long chain alkenyl succinimide are quantitated and speciated by means of X-Ray Photoelectron Spectroscopy with speciation being made by chemometrically curve resolving the XPS spectrum.

Abstract: Provided are lube base stocks produced from renewable biological sources with improved low temperature properties. In one form, the lube base stock includes from 10 to 35 wt. % paraffins, 40 to 70 wt. % 1-ring naphthenes, and 0 to 40 wt. % combined 2-ring naphthenes and aromatics, and has a ratio of 1-ring naphthenes to paraffins from 1.8 to 5.0, and a Viscosity Index of from 100 to 160. The lube base stock has a 14C level ranging from 2 to 101% of the modern day 14C level in the atmosphere, and yields a CCS ratio (Cold Crank Simulator (CCS) viscosity to the predicted CCS viscosity by Walther equation) of less than or equal to 0.85 at ?35° C. The base stocks are useful as in formulated lubricant compositions requiring improved low temperature properties.

Abstract: Provided are lubricant compositions from renewable biological sources with improved properties and methods of making and using such compositions. In one form, the lubricant composition includes from 20 to 99.8 wt. % of a lube base stock produced from a renewable biological source and an effective amount of one or more lubricant additives. The lube base stock includes 10 to 35 wt. % paraffins, 40 to 70 wt. % 1-ring naphthenes, and 0 to 40 wt. % combined 2-ring naphthenes and aromatics, and has a ratio of 1-ring naphthenes to paraffins from 1.8 to 5.0, and a Viscosity Index of from 100 to 160. The lube base stock has a 14C level ranging from 2 to 101% of the modern day 14C level in the atmosphere, and yields a CCS ratio of less than or equal to 0.85 at ?35° C. The lubricant compositions exhibit improved solvency and % thickening when blended with a viscosity modifier.

Abstract: Provided is a hydrocarbon tar. The tar has 75 wt % or more of aromatics of 10 carbons to 75 carbons based on the total weight of the tar. The aromatics exhibit 40% to 80% aromaticity. The tar has a boiling point of from 300° F. to 1350° F. There is also a fuel oil composition having the tar therein. There are also processes for making the hydrocarbon tar.

Abstract: Provided are processes for making saturated hydrocarbons from renewable feed sources. In an embodiment, a process for producing a lube basestock and/or a diesel fuel from a feedstock of biological origin includes: contacting the feedstock in a single reactor in the presence of hydrogen with catalyst components including a first catalyst and a second catalyst, wherein the first catalyst comprises an acidic material, a basic material, or a combination of both, and wherein the second catalyst is a hydrogenation catalyst including a hydrothermally stable binder.