Patents by Inventor Franz Nierlich

Franz Nierlich has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6331657
    Abstract: A process for preparing higher oxo alcohols from mixtures of isomeric olefins having from 5 to 24 carbon atoms by two-stage hydroformylation in the presence of a cobalt catalyst or rhodium catalyst at elevated temperature and at elevated pressure, which comprises selectively hydrogenating the first hydroformylation stage reaction mixture, separating the hydrogenation mixture in a distillation into crude alcohol and low-boilers predominantly consisting of olefins, passing these low-boilers to the second hydroformylation stage, again selectively hydrogenating the second hydroformylation stage reaction mixture, separating the hydrogenation mixture in one distillation into crude alcohol and low-boilers, working up the crude alcohol by distillation to pure alcohol and taking off at least some of the low-boilers to discharge saturated hydrocarbons.
    Type: Grant
    Filed: September 15, 1999
    Date of Patent: December 18, 2001
    Assignee: Oxeno Olefinchemie GmbH
    Inventors: Alfred Kaizik, Bernhard Scholz, Walter Toetsch, Wilfried Bueschken, Franz Nierlich
  • Patent number: 5998685
    Abstract: A highly flexible process for preparing butene oligomers from field butanes. The process can be controlled to produce the desired oligomerization products by appropriate selection of the starting materials.
    Type: Grant
    Filed: July 24, 1997
    Date of Patent: December 7, 1999
    Assignee: Huels Aktiengesellschaft
    Inventors: Franz Nierlich, Paul Olbrich, Wilhelm Droste, Richard Mueller, Walter Toetsch
  • Patent number: 5993763
    Abstract: A catalyst based on titanium oxide, zirconium oxide or combinations thereof for decomposing HCN in gases, which additionally comprises:molybdenum, vanadium, tungsten, manganese, silicon, selenium, tellurium, niobium, tantalum, sulfur, phosphorus in the form of their oxides, hydrated oxides, other compounds, or combinations thereof.
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: November 30, 1999
    Assignee: Huels Aktiengesellschaft
    Inventors: Alfred Kaizik, Dietrich Maschmeyer, Franz Nierlich
  • Patent number: 5994601
    Abstract: A process is described in which butene oligomers are prepared from Fischer-Tropsch olefins, in which the butenes present in a C.sub.4 fraction of Fischer-Tropsch hydrocarbons are oligomerized to obtain dibutene. The dibutene can be fractionated in a fine distillation stage into di-n-butene and di-isobutene. In one embodiment of the process, the ethylene present in the Fischer-Tropsch olefins is dimerized and the dimerization mixture is recycled to the C.sub.4 fraction. In another embodiment, the isobutene present in the C.sub.4 fraction is reacted with an alcohol to give an alkyl tert-butyl ether, and only the remaining n-butene is oligomerized so that di-n-butene is formed as the sole dibutene.
    Type: Grant
    Filed: July 24, 1997
    Date of Patent: November 30, 1999
    Assignee: Huels Aktiengesellschaft
    Inventors: Franz Nierlich, Walter Toetsch, Paul Olbrich, Wilhelm Droste, Richard Mueller
  • Patent number: 5912191
    Abstract: A process for the coupled production of alkyl tert-butyl ethers and butene oligomers from a mixture containing isobutane and n-butane. The isobutane is converted to the alkyl tert-butyl ether and the n-butane is converted to the oligomers. The ratio of the two reaction products may be controlled by setting the ratio of n-butane to isobutane appropriately by isomerization.
    Type: Grant
    Filed: July 24, 1997
    Date of Patent: June 15, 1999
    Assignee: Huels Aktiengesellschaft
    Inventors: Franz Nierlich, Paul Olbrich, Wilhelm Droste, Richard Mueller, Walter Toetsch
  • Patent number: 5864052
    Abstract: The invention relates to a process for preparing di-n-butene and alkyl tertbutyl ethers in a coupled production from field butanes, which indicates (a) separating the field butanes 1 into n-butane and isobutane in the separation stage 4, (b) dehydrogenating the n-butane 5 in a dehydrogenation stage 6 to give an n-butene-containing dehydrogenation mixture 7, oligomerizing the n-butene in the oligomerization stage 10 to give an oligomer mixture 11 and separating di-n-butene 12 off from this, and (c) de-hydrogenating the isobutane 15 in the dehydrogenation stage 16 to give an isobutene-containing dehydrogenation mixture 17 and reacting the isobutene with an alkanol 20 in the etherification stage 19 to give an alkyl tert-butyl ether 21.
    Type: Grant
    Filed: July 24, 1997
    Date of Patent: January 26, 1999
    Assignee: Huels Aktiengesellschaft
    Inventors: Franz Nierlich, Paul Olbrich, Wilhelm Droste, Richard Mueller, Walter Toetsch
  • Patent number: 5518699
    Abstract: Carrying out a chemical reaction in a reaction distillation column on an inorganic catalyst in the form of a column packing material which is maintained above the column bottom permits the use of high reaction temperatures and the easy removal or replacement of inactivated catalyst.
    Type: Grant
    Filed: July 8, 1994
    Date of Patent: May 21, 1996
    Assignee: Huels Aktiengesellschaft
    Inventors: John Kashnitz, Frank Steding, Alfred Oberholz, Franz Nierlich, Bernd Nowitzki
  • Patent number: 5177282
    Abstract: Olefins are oligomerized by passing a hydrocarbon feedstock mixture containing olefins of from 2 to 8 carbon atoms over a molecular sieve having a pore diameter of from greater than 4 angstroms to 15 angstroms, and then oligomerizing said olefins by passing the hydrocarbon feedstock over a nickel-containing catalyst at a temperature of from 0.degree.to 200.degree. C. and at a pressure of from 1 to 70 bar absolute.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: January 5, 1993
    Assignee: Huels Aktiengesellschaft
    Inventors: Franz Nierlich, Joachim Neumeister, Thomas Wildt, Wilhelm Droste, Fritz Obenaus
  • Patent number: 5146039
    Abstract: A hydrocarbon containing sulfides, disulfides, trisulfides, tetrasulfides or mixtures can be desulfurized by contacting the hydrocarbon with a zeolite containing copper, silver, zinc or mixtures thereof.
    Type: Grant
    Filed: November 6, 1990
    Date of Patent: September 8, 1992
    Assignee: Huels Aktiengesellschaft
    Inventors: Thomas Wildt, Franz Nierlich, Wilhelm Droste, Joachim Neumeister, Bernhard Scholz
  • Patent number: 4517395
    Abstract: A process for the selective hydrogenation of hydrocarbons having three and more carbon atoms and several double bonds or with triple bonds in monoene-containing hydrocarbon mixtures is described. These compounds are selectively hydrogenated to monoenes in a practically quantitative fashion. Before beginning the hydrogenation, a small amount of carbon monoxide and once to twice the stoichiometric quantity of hydrogen are homogeneously dissolved in the hydrocarbon mixture. The mixture is hydrogenated as a homogeneous liquid phase on a fixed palladium catalyst under a moderately high pressure and at a moderately high temperature. No isomerization can be found in the monoenes and no side reactions or secondary reactions occur.
    Type: Grant
    Filed: November 2, 1982
    Date of Patent: May 14, 1985
    Assignee: Chemische Werke Huls Aktiengesellschaft
    Inventors: Fritz Obenaus, Franz Nierlich, Otto Reitemeyer, Bernhard Scholz
  • Patent number: 4335018
    Abstract: Ethylenically unsaturated C.sub.4 -n-hydrocarbons are oxidized to maleic anhydride by passing a stream of oxygen-containing gas at high temperature over a catalyst of the formulaW.sub.a Mo.sub.b Sb.sub.c Y.sub.d X.sub.e O.sub.xwherein Y=P, Si; X=V, Bi, Te, alkali metal; a and b each =1-12; c=2-20; d=0.2-2; e=0-10; and x is the number of oxygen atoms required to satisfy the remaining valences of the other elements, prepared by reacting an Sb compound and optionally also a V, Bi, Te and/or alkali metal compound, with a solution of a heteropoly acid of Mo and W, drying and tempering the resultant blue complex.
    Type: Grant
    Filed: October 30, 1980
    Date of Patent: June 15, 1982
    Assignee: Chemische Werke Huels Aktiengesellschaft
    Inventors: Gerhard Franz, Franz Nierlich, Hans-Josef Ratajczak
  • Patent number: 4268448
    Abstract: Ethylenically unsaturated C.sub.4 -n-hydrocarbons are oxidized to maleic anhydride by passing a stream of oxygen-containing gas at high temperature over a catalyst of the formulaW.sub.a Mo.sub.b Sb.sub.c Y.sub.d X.sub.e O.sub.xwherein Y=P, Si; X=V, Bi, Te, alkali metal; a and b each=1-12; c=2-20; d=0.2-2; e=0-10; and x is the number of oxygen atoms required to satisfy the remaining valences of the other elements, prepared by reacting an Sb compound and optionally also a V, Bi, Te and/or alkali metal compound, with a solution of a heteropoly acid of Mo and W, drying and tempering the resultant blue complex.
    Type: Grant
    Filed: January 22, 1980
    Date of Patent: May 19, 1981
    Assignee: Chemische Werke Huls Aktiengesellschaft
    Inventors: Gerhard Franz, Franz Nierlich, Hans-Josef Ratajczak