Patents by Inventor Freddy Henderickx

Freddy Henderickx has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6472137
    Abstract: A light-sensitive silver halide photographic film material has been provided, said film material comprising a transparent support and on both sides thereof at least one light-sensitive emulsion layer having spectrally and chemically sensitized tabular silver halide grains rich in silver bromide, further having silver iodide in an amount of less than 3 mole % based on silver, with two flat parallel {111} crystal faces, said grains accounting for a total projective surface of said parallel crystal faces in said emulsion of at least 50%, further having an average aspect ratio of at least 2:1, a grain thickness of from 0.05 up to 0.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: October 29, 2002
    Assignee: Agfa-Gevaert
    Inventors: Ann Verbeeck, Paul Callant, Freddy Henderickx
  • Publication number: 20020119405
    Abstract: A multilayer light-sensitive silver halide photographic negative image type material and a method to prepare said material has been described, said material comprising on at least one side of a support a multilayer composition of at least two layers of negative image type silver halide emulsions adjacent to each other, wherein the emulsion layer closest to the said support comprises tabular emulsion crystals selected from the group consisting of silver chloride, silver chlorobromide, silver chloroiodide and silver chlorobromoiodide having a {111} crystal habit and silver chloride, silver chlorobromide, silver chloroiodide and silver chlorobromoiodide having a {100} crystal habit and wherein the adjacent layer(s) farther from the said support comprise(s) essentially cubic emulsion crystals selected from the group consisting of silver chloride, silver chlorobromide and silver bromide, wherein the essentially cubic grains are less sensitive than the tabular grains and wherein the said tabular
    Type: Application
    Filed: February 21, 2002
    Publication date: August 29, 2002
    Applicant: Agfa-Gevaert, N.V.
    Inventors: Hieronymus Andriessen, Freddy Henderickx
  • Patent number: 6436621
    Abstract: A multilayer light-sensitive silver halide photographic negative image type material and a method to prepare said material has been described, said material comprising on at least one side of a support a multilayer composition of at least two layers of negative image type silver halide emulsions adjacent to each other, wherein the emulsion layer closest to the said support comprises tabular emulsion crystals selected from the group consisting of silver chloride, silver chlorobromide, silver chloroiodide and silver chlorobromoiodide having a {111} crystal habit and silver chloride, silver chlorobromide, silver chloroiodide and silver chlorobromoiodide having a {100} crystal habit and wherein the adjacent layer(s) farther from the said support comprise(s) essentially cubic emulsion crystals selected from the group consisting of silver chloride, silver chlorobromide and silver bromide, wherein the essentially cubic grains are less sensitive than the tabular grains and wherein the said tabular
    Type: Grant
    Filed: February 21, 2002
    Date of Patent: August 20, 2002
    Assignee: Agfa-Gevaert
    Inventors: Hieronymus Andriessen, Freddy Henderickx
  • Patent number: 6379877
    Abstract: According to this invention a developer has been disclosed having a low pH value between 9.6 and 11.0, preferably between 9.6 and 10.3, and comprising hydroquinone in an amount from 0 to less than 30 g per liter, an auxiliary developing agent, and as silver halide complexing agents alkali metal sulphite salts, preferably sodium salts, in an amount from 0 to less than 50 g per liter, more preferably to less than 40 g per liter, and thiocyanate salts in amounts from 0.1 to 3 g, more preferably from 0.5 to 2.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: April 30, 2002
    Assignee: Agfa-Gevaert
    Inventors: Freddy Henderickx, Ann Verbeeck, Pascal Meeus, Hieronymus Andriessen
  • Patent number: 6348293
    Abstract: A radiographic film material is described including a transparent film support having first and second major surfaces coated with a subbing layer, optionally overcoated with an antihalation undercoat. Coated adjacent on each side of the film support is a light-sensitive silver halide emulsion overcoated with a protective antistress layer. The emulsion layer has chemically and spectrally sensitized {111} tabular hexagonal grains or crystals, having silver iodide in an amount of at most 3 mole %, based on silver, covering at least 50% of the total projective surface of all grains, having an average grain thickness of less than 0.30 &mgr;m. The antistress layer, or the optional antihalation undercoat or both includes a N-amino mercapto-triazole compound containing one or more alkali soluble group(s). A radiographic screen/film combination is also described including the film material.
    Type: Grant
    Filed: November 20, 2000
    Date of Patent: February 19, 2002
    Assignee: Agfa-Gevaert
    Inventors: Ann Verbeeck, Johan Loccufier, Govert De Baecke, Freddy Henderickx, Heinrich Odenwälder
  • Patent number: 6346360
    Abstract: A radiographic film material has been provided, comprising a transparent film support having first and second major surfaces coated, apart from a subbing layer and, optionally, a non-light-sensitive hydrophilic layer thereupon, with at least one light-sensitive silver halide emulsion layer overcoated with a protective antistress layer, said emulsion layer(s) having chemically and spectrally sensitized {111} tabular hexagonal core-shell emulsion grains or crystals in an amount of at least 50% of the total projective grain surface of all grains, said grains being composed of a silver bromide core and a silver bromoiodide shell having an average amount over the whole crystal volume of more than 90 mole % of silver bromide, said grains further having a mean equivalent volume diameter of from 0.3 &mgr;m up to 1.0 &mgr;m and an average grain thickness of less than 0.
    Type: Grant
    Filed: November 7, 2000
    Date of Patent: February 12, 2002
    Assignee: Agfa-Gevaert
    Inventors: Ann Verbeeck, Freddy Henderickx
  • Patent number: 6342338
    Abstract: A black-and-white silver halide photographic film material, particularly suitable for use in radiography, has been disclosed, said material comprising a transparent film support having first and second major surfaces coated with a subbing layer, further coated adjacent thereto on one side (for a single-side coated material) or on both sides (for a duplitized material) of said film support and overcoated with a protective antistress layer, a light-sensitive silver halide emulsion layer having chemically and spectrally sensitized {111} tabular hexagonal grains, accounting for at least 50% of the total projective surface of all grains, wherein said film material is coated with a low amount of silver and wherein said protective antistress layer(s)and/or another hydrophilic non-light-sensitive layer comprise(s) a compound according to general formula (I) in an amount of at least 0.5 mmole per mole of coated silver halide, as claimed.
    Type: Grant
    Filed: November 14, 2000
    Date of Patent: January 29, 2002
    Assignee: Agfa-Gevaert
    Inventors: Ann Verbeeck, Govert Wim De Baecke, Johan August Loccufier, Freddy Henderickx
  • Patent number: 6066441
    Abstract: A method is disclosed of processing an exposed black-and-white light-sensitive silver halide photographic material having silver halide, coated in an amount, expressed as an equivalent amount of silver nitrate of less than 6 g/m.sup.2 comprising the steps of developing, fixing, rinsing and drying, making use in the developing step of an ascorbic acid type developer and of an equivalent developer replenisher providing a regeneration amount of less than 150 ml/m.sup.2, characterized in that the said material has a buffering capacity of less than 6 mmole/m.sup.2, wherein said buffering capacity is defined as the amount of alkali, expressed in mmole/square meter, required to bridge across pH differences between the material and the developer.
    Type: Grant
    Filed: May 3, 1999
    Date of Patent: May 23, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Benedictus Jansen, Freddy Henderickx, Ann Verbeeck, Frank Michiels
  • Patent number: 6048096
    Abstract: An image-forming system for radiological imaging is described consisting of an intensifying screen comprising on a support at least one layer of a green-light emitting phosphor and, in operative association therewith, a prehardened light-sensitive photographic silver halide film material, comprising a support and on both sides thereof one or more hydrophilic colloid layers having monodisperse cubic silver chloroiodide grains with a mean crystal diameter of from 0.40 .mu.m up to 0.65 .mu.m or {111} tabular silver chloroiodide grains having an aspect ratio of from 5 to 20 and a tabularity from 20 to 200; wherein said grains have been spectrally sensitized in the green wavelength range and have been coated in a total amount of silver per sq.m. of from 6 g up to 8 g, expressed as an equivalent amount of silver nitrate per sq.m.; wherein in the image-forming system silver chloroiodide grains have been chemically sensitized with one or more selenide compound(s) generating silver selenide.
    Type: Grant
    Filed: February 24, 1998
    Date of Patent: April 11, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Ann Verbeeck, Freddy Henderickx, Johan Loccufier, Peter Verrept
  • Patent number: 5998083
    Abstract: An image-forming system for radiological imaging is disclosed said system consisting of an intensifying screen comprising on a support at least one layer of a green-light emitting phosphor and, in operative association therewith, a prehardened light-sensitive photographic silver halide film material, comprising a support and on both sides thereof one or more hydrophilic colloid layers, said layers being hardened to such an extent that their swelling degree is reduced to less than 200% after immersing said material for 2 minutes in demineralised water of 35.degree. C.; further comprising in at least one of said hydrophilic layers chemically ripened, monodisperse essentially cubic silver chloroiodide grains having a mean crystal diameter of from 0.40 mm up to 0.65 mm; wherein said grains have been spectrally sensitised in the wavelength range between 520 and 580 nm, have a maximum absorption between 540 and 500 nm and have been coated in a total amount of silver per sq.m.
    Type: Grant
    Filed: February 24, 1998
    Date of Patent: December 7, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Ann Verbeeck, Freddy Henderickx, Dirk Vandenbroucke, Peter Verrept
  • Patent number: 5912108
    Abstract: A method has been disclosed of processing an image-wise exposed light-sensitive black-and-white silver halide photographic material comprising a support coated on one or both sides thereof with hydrophilic layers, wherein at least one of said layers comprises one or more emulsions having tabular silver halide crystals rich in silver chloride, said method comprising the steps of developing, fixing, rinsing and drying, further characterized in that said developing step proceeds in a black-and-white developer comprising one or more organic compounds inhibiting development, more preferably one or more benzotriazole compounds, and in that said developer is substantially free from bromide ions in favor of a low fog level, a high speed and a sufficiently high covering power of the developed tabular grains.
    Type: Grant
    Filed: December 16, 1997
    Date of Patent: June 15, 1999
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Ann Verbeeck, Peter Verrept, Freddy Henderickx
  • Patent number: 5783379
    Abstract: A silver halide photographic material for industrial radiography is disclosed comprising a film support and on one or both sides thereof at least one gelatino silver halide emulsion layer wherein each silver halide emulsion layer comprises as silver halide crystals silver chloride and/or silver chlorobromide crystals the amount of bromide therein being at most 25 mole %; has a gelatin to silver halide (expressed as silver nitrate) ratio from 2:10 to 6:10 and has an amount of silver halide corresponding to from 5 g to 15 g of silver per m.sup.2 and wherein said photographic material has been fore-hardened to such an extent that when it is immersed in demineralized water of 25.degree. C. for 3 minutes there is absorbed less than 2.5 g of water per gram of gelatin, characterized in that said silver chloride or silver chlorobromide emulsion crystals are chemically ripened in the presence of at least one sulphur compound and at least one gold compound, wherein gold is present in an amount from 0.01 to 1 .mu.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: July 21, 1998
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Peter Willems, Freddy Henderickx
  • Patent number: 5763148
    Abstract: A silver halide photographic activation material is disclosed comprising a film support, on one or both sides thereof at least one gelatino silver halide emulsion layer and between said emulsion layer and said support a hydrophilic undercoat layer comprising as a binder at least 50% of a loaded latex polymer, said latex polymer being loaded with at least one developing agent, further characterised in that water absorption during activation processing is not higher than 2.5 g per gram of binder present in said material.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: June 9, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Peter Willems, Freddy Henderickx, Marcel Monbaliu
  • Patent number: 5712081
    Abstract: A method of reproducing an electronically stored medical image on a hardcopy material is disclosed, said material comprising a support and on only one side thereof a silver halide emulsion layer and a hydrophilic colloid layer, wherein said emulsion layer comprises red sensitized homogeneous cubic silver chloride, silver chloroiodide, silver chlorobromide or silver chlorobromoiodide crystals having not less than 70 mole % of chloride ions and preferably not less than 90 mole %; not more than 1 mole % of iodide ions and an average crystal size of from 0.12 to 0.30 .mu.m and more preferred from 0.15 to 0.25 .mu.m; wherein said crystals are coated in an amount, expressed as an equivalent amount of silver nitrate of from 2 to 6 g per sq.m.
    Type: Grant
    Filed: March 6, 1997
    Date of Patent: January 27, 1998
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Hieronymus Andriessen, Freddy Henderickx
  • Patent number: 5660966
    Abstract: A silver halide photographic material for industrial radiography is disclosed comprising a film support and on one or both sides thereof at least one silver halide emulsion layer which is characterized in that each gelatino silver halide emulsion layer comprises as silver halide silver chloride or silver chlorobromide wherein the amount of bromide is not more than 10 mole %; has a gelatin to silver halide (expressed as silver nitrate) ratio from 0.2 to 0.6 and a total amount of silver halide corresponding to from 11 g to 35 g of silver/m.sup.2 and in that the photographic material has been fore-hardened to such an extent that when it is immersed in demineralized water of 25.degree. C. for 3 minutes there is not absorbed more than 3.0 g of water per gram of gelatin, and wherein said material further comprises a dihydroxybenzene compound and a 3-pyrazolidine-1-one compound as developing agents.
    Type: Grant
    Filed: July 15, 1996
    Date of Patent: August 26, 1997
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Peter Willems, Freddy Henderickx
  • Patent number: 5604082
    Abstract: A method has been disclosed of processing an exposed silver halide photographic material comprising at least one coated hydrophilic silver halide emulsion layer comprising tabular grains rich in chloride, bounded by [100] or [111] major faces, characterized by the steps of developing, followed by fixing, rinsing and drying the said material, wherein developing proceeds in a developer, comprising hydroquinone in an amount from 0 to 30 g per liter, an auxiliary developer, as silver halide complexing agents alkali metal sulphite salts in an amount from 1 to 50 g per liter, at least 1 g of a compound corresponding to the formula (I), a precursor thereof, a derivative thereof and/or a metal salt thereof ##STR1## wherein the substituents are defined in the main embodiment of the specification.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: February 18, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Freddy Henderickx, Hieronymus Andriessen, Ann Verbeeck
  • Patent number: 5593817
    Abstract: A photographic developing solution and a method of developing silver halide materials in the said developing solution is disclosed, the said developing solution comprising hydroquinone in an amount from 0 to 30 g per litre, an auxiliary developer, and silver halide complexing agents in an amount from 0 to 50 g per litre, characterized in that said developer further comprisesin amounts from 0.1 to 5 g per litre a compound corresponding to the formula (I), accompanied by charge compensating anions,Z'N.sup.+ --R--N.sup.+ Z" (I)wherein at least divalent group R contains at least one oxyethylene group and wherein Z' and Z", being the same or different, are composed of enough atoms to form a heterocyclic aromatic 5- or 6-ring;andat least 1 g of a compound corresponding to the formula (II), a precursor thereof, a derivative thereof and/or a metal salt thereof ##STR1## wherein each of A, B and D independently represents an oxygen atom or NR.sup.1 ;X represents an oxygen atom, a sulphur atom, NR.sup.2 ; CR.sup.3 R.
    Type: Grant
    Filed: January 31, 1996
    Date of Patent: January 14, 1997
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Freddy Henderickx, Ann Verbeeck, Pascal Meeus, Hieronymus Andriessen
  • Patent number: 5447817
    Abstract: To eliminate the "pi-line" artefact after processing a method of image formation in a silver halide industrial X-ray photographic material is disclosed wherein said material comprises on at least one side of a support, at least one gelatino silver halide emulsion layer and a total amount of silver halide, corresponding to from 6 to 20 g of silver nitrate per square meter and per side, and at least one non-sensitive protective antistress coating and wherein said method proceeds by the steps of exposing said material to direct X-rays and processing the material in an automatic processing machine by development, fixing, rinsing and drying, characterized in that said material further comprises at least one vinyl sulphone compound as a hardening agent in at least one of its hydrophilic layers, that development occurs in a developer comprising as a surfactant at least one anionic alkylphenoxy and/or alkoxy polyalkyleneoxy phosphate ester, sulphate ester, alkyl carboxylic, sulphonic or phosphonic acid and/or a salt
    Type: Grant
    Filed: April 5, 1994
    Date of Patent: September 5, 1995
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Raymond Florens, Pieter Perdieus, Peter Willems, Freddy Henderickx
  • Patent number: 5397687
    Abstract: The preparation of x-ray materials, especially suitable for non-destructive testing applications, is described. The emulsion layers of said material are comprising silver halide emulsion grains containing at least 75 mole % of silver chloride and less than 25 mole % of silver bromide and are characterized by a ratio between the amount of gelatin and the amount of silver halide, being expressed as the equivalent amount of silver nitrate, of less than 0.6. Hardening of said material is performed in such a way that the amount of demineralized water of 25.degree. C. absorbed in 3 minutes is less than 2.5 g per gram of gelatin present in said material. A rapid processing system is available with a total processing time of less than 3 minutes with a developer and fixer being substantially free from hardening agents and the fixer being substantially free from ammonium ions.
    Type: Grant
    Filed: December 14, 1993
    Date of Patent: March 14, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Peter Willems, Freddy Henderickx, Gino De Rycke, Romain Bollen
  • Patent number: 5167875
    Abstract: An aqueous silver sulfide sol is prepared which has an absorption spectrum such that its optical density at 360 nm is at least 100 times its optical density at 700 nm. The sol is ultrafine in particle size and is useful for the chemical sensitization of silver halide emulsions and for the preparation of development layers for the silver complex diffusion transfer copying process or the production of optical filters.
    Type: Grant
    Filed: October 23, 1989
    Date of Patent: December 1, 1992
    Assignee: Agea-Gevaert N. V.
    Inventors: Gino L. De Rycke, Freddy Henderickx