Patents by Inventor Frederick J. Krambeck

Frederick J. Krambeck has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4684757
    Abstract: A multistage process for producing ethers from lower aliphatic oxygenate feedstock, such as methanol. Feedstock is catalytically converted in a primary catalyst stage at elevated temperature in contact with zeolite catalyst to predominantly C.sub.2 -C.sub.5 lower olefins comprising isobutylene and isoamylene, by-product water and a minor amount of C.sub.6.sup.+ hydrocarbons, followed by fractionation of the C.sub.2 -C.sub.5 olefins to recover a C.sub.2 -C.sub.3 -rich recycle stream for further catalytic conversion in the primary stage. C.sub.4 -C.sub.5 olefins are passed to a second catalytic etherification stage for reaction of isoalkenes with methanol to produce methyl tertiary-butyl ether and methyl isoamylether. The second stage effluent may be fractionated to recover an ether product, C.sub.5.sup.+ hydrocarbon liquid product, and unreacted butenes.
    Type: Grant
    Filed: July 18, 1986
    Date of Patent: August 4, 1987
    Assignee: Mobil Oil Corporation
    Inventors: Amos A. Avidan, Frederick J. Krambeck, Samuel A. Tabak
  • Patent number: 4645589
    Abstract: A process for removing metal from a metal-containing hydrocarbon oil such as a heavy crude is disclosed which comprises:(a) contacting a hydrocarbon oil phase containing at least one metal selected from the group consisting of vanadium and nickel with an aqueous phase of dissolved phosphorous compound capable of forming a compound or a complex with said metal, said aqueous phase containing a substantial quantity of water relative to the amount of liquid hydrocarbon contacted therewith, said contacting resulting in the removal of a substantial quantity of the metal from the hydrocarbon oil phase to the aqueous phase; and,(b) separating the metal-containing aqueous phase from the demetalated hydrocarbon oil phase prior to subjecting the latter to downstream catalytic processing.
    Type: Grant
    Filed: October 18, 1985
    Date of Patent: February 24, 1987
    Assignee: Mobil Oil Corporation
    Inventors: Frederick J. Krambeck, Chiu T. Lam, Paul H. Schipper
  • Patent number: 4640463
    Abstract: An apparatus for atomizing a liquid hydrocarbon feed and injecting it into a reaction zone, such as a riser conversion zone or a dense fluid bed reactor of a fluid catalytic cracking unit, is disclosed. The hydrocarbon feed passes through a central passage with steam flowing concurrently in a concentrically aligned passage. By providing a flow restriction means in each hydrocarbon passage and each steam passage, substantially equal quantities of hydrocarbon and steam can be supplied to each of a plurality of hydrocarbon-steam nozzles so as to provide a uniform dispersion of small droplets of hydrocarbons.
    Type: Grant
    Filed: August 30, 1985
    Date of Patent: February 3, 1987
    Assignee: Mobil Oil Corporation
    Inventors: Frederick J. Krambeck, Stephen J. McGovern, John E. Sauer
  • Patent number: 4624772
    Abstract: A fluid catalytic cracking (FCC) apparatus and process comprising a reactor riser zone, a primary and a secondary cyclones, connected in series to the riser zone, and a stripping zone. The riser zone, the primary and the secondary cyclones, and the stripping zone, are placed within a single reactor vessel. The primary cyclone is connected to the reactor riser zone by an enclosed conduit which prevents random post-riser thermal cracking of the hydrocarbons after they exit the reactor riser zone. The conduit contains a trickle valve, or other means, to accommodate sudden increased surges of flow of the hydrocarbons and catalyst mixture.
    Type: Grant
    Filed: November 8, 1985
    Date of Patent: November 25, 1986
    Assignee: Mobil Oil Corporation
    Inventors: Frederick J. Krambeck, Klaus W. Schatz
  • Patent number: 4606810
    Abstract: A novel FCC method and apparatus, wherein a fresh hydrocarbon feed of relatively poor crackability is fed to one riser of a two riser system. The spent catalyst from the other of the two risers is fed to the inlet of the first riser to produce relatively mild cracking conditions. Improved total gasoline plus distillate yields are achieved. The novel two riser system facilitates heat balancing of the system.
    Type: Grant
    Filed: April 8, 1985
    Date of Patent: August 19, 1986
    Assignee: Mobil Oil Corporation
    Inventors: Frederick J. Krambeck, Carmo J. Pereira
  • Patent number: 4588558
    Abstract: A fluid catalytic cracking (FCC) apparatus comprising a reactor riser zone, primary and secondary cyclones, connected in series to the riser zone, and a stripping zone. The riser zone, the primary and the secondary cyclones, and the stripping zone, are placed within a single reactor vessel. The primary cyclone is connected to the reactor riser zone by an enclosed conduit which prevents random post-thermal cracking of the hydrocarbons after they exit the reactor riser zone. The secondary cyclone is also connected to the primary cyclone by an enclosed conduit. Any one or both of the enclosed conduits contain a trickle valve to accommodate sudden increased surges of pressure and of flow of the hydrocarbons and catalyst mixture. The reactor riser zone is equipped with an opening which allows stripping gases, from the stripping zone, to enter the riser. The gases are subsequently conducted through the primary and secondary cyclones to the downstream fractionation means.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: May 13, 1986
    Assignee: Mobil Oil Corporation
    Inventors: Anthony Y. Kam, Frederick J. Krambeck, Klaus W. Schatz
  • Patent number: 4579716
    Abstract: A fluid catalytic cracking (FCC) apparatus and process comprising a reactor riser zone, a primary and a secondary cyclones, connected in series to the riser zone, and a stripping zone. The riser zone, the primary and the secondary cyclones, and the stripping zone, are placed within a single reactor vessel. The primary cyclone is connected to the reactor riser zone by an enclosed conduit which prevents random post-riser thermal cracking of the hydrocarbons after they exit the reactor riser zone. The conduit contains a trickle valve, or other means, to accommodate sudden increased surges of flow of the hydrocarbons and catalyst mixture.
    Type: Grant
    Filed: September 6, 1983
    Date of Patent: April 1, 1986
    Assignee: Mobil Oil Corporation
    Inventors: Frederick J. Krambeck, Klaus W. Schatz
  • Patent number: 4555328
    Abstract: A process and an apparatus for atomizing a liquid hydrocarbon feed and injecting it into a reaction zone, such as a riser conversion zone or a dense fluid bed reactor of a fluid catalytic cracking unit, is disclosed. The hydrocarbon feed passes through a central passage with steam flowing concurrently in a concentrically aligned passage. By providing a flow restriction means in each hydrocarbon passage and each steam passage, substantially equal quantities of hydrocarbon and steam can be supplied to each of a plurality of hydrocarbon-steam nozzles so as to provide a uniform dispersion of small droplets of hydrocarbons.
    Type: Grant
    Filed: January 19, 1984
    Date of Patent: November 26, 1985
    Assignee: Mobil Oil Corporation
    Inventors: Frederick J. Krambeck, Stephen J. McGovern, John E. Sauer
  • Patent number: 4481103
    Abstract: Process for reduction of sulfur oxides emissions to the atmosphere from FCC regenerators. Spent FCC cracking catalyst containing sulfur and coke deposits is stripped at 500.degree. to 700.degree. C. for 1 to 10 minutes with steam to remove at least a portion of said sulfur deposits from said catalyst prior to catalyst regeneration.
    Type: Grant
    Filed: October 19, 1983
    Date of Patent: November 6, 1984
    Assignee: Mobil Oil Corporation
    Inventors: Frederick J. Krambeck, Donald M. Nace, Paul H. Schipper
  • Patent number: 4481100
    Abstract: An improved surge bin for a Lurgi-Ruhrgas process has baffles which promote uniform flow of feed material through the surge bin. Improved retorting of kerogen from oil shale is obtained. Stripping gas such as steam, is supplied to the surge bin. A separator has a large disengaging volume to remove entrained solid particles and improve the quality of the hydrocarbon product.
    Type: Grant
    Filed: July 29, 1983
    Date of Patent: November 6, 1984
    Assignee: Mobil Oil Corporation
    Inventors: Clinton R. Kennedy, Frederick J . Krambeck
  • Patent number: 4404095
    Abstract: A suspension of catalyst and gasiform material is separated by a catalyst particle concentrating means which discharges the catalyst into a steam stripping zone and transmits the separated gasiform material to a cyclone separator by means of a restricted passageway which minimizes the time the gasiform material is exposed to the catalytic reaction product temperature.
    Type: Grant
    Filed: July 22, 1982
    Date of Patent: September 13, 1983
    Assignee: Mobil Oil Corporation
    Inventors: James H. Haddad, Frederick J. Krambeck