Patents by Inventor Fumihiko Shimizu

Fumihiko Shimizu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20060270794
    Abstract: Soft propylene-based resin compositions, which comprise substantially the following block (I) and block (II): Block (I): propylene-based polymer having propylene unit chain segments that bond in a mode of head-to-tail bonding, in which the chain segment has an isotactic block-containing stereoblock structure; Block (II): copolymer containing at least propylene and ethylene, exhibit good flexibility, transparency, and heat resistance.
    Type: Application
    Filed: August 2, 2006
    Publication date: November 30, 2006
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Fumihiko Shimizu, Kenjirou Takayanagi, Naomasa Sato, Fumiyoshi Yamada, Shixuan Xin
  • Patent number: 7122604
    Abstract: This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: October 17, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masato Onoe, Teruaki Ashihara, Kazuyuki Hata, Fumihiko Shimizu, Naomasa Sato, Akio Tanna
  • Patent number: 7115694
    Abstract: An object of the present invention is to provide a novel propylene-based polymer capable of providing a propylene-based polymer with a good adhesion and coatability. The present invention lies in a propylene-based polymer having a propylene component with several characteristics including a weight-average molecular weight Mw from not smaller than 5,000 to less than 1,000,000 as measured by GPC, and Regio irregular units based on 2,1-inserted propylene monomer and/or 1,3-inserted propylene monomer present in its main chain and the sum of the ratio of regio irregular units based on 2,1-insertion and 1,3-insertion to all propylene insertions not smaller than 0.05%.
    Type: Grant
    Filed: August 29, 2003
    Date of Patent: October 3, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Fumihiko Shimizu, Naomasa Sato, Akira Kuwahara, Fumiyoshi Yamada, Akio Tanna
  • Patent number: 7105604
    Abstract: Soft propylene-based resin compositions, which comprise substantially the following block (I) and block (II): Block (I): propylene-based polymer having propylene unit chain segments that bond in a mode of head-to-tail bonding, in which the chain segment has an isotactic block-containing stereoblock structure; Block (II): copolymer containing at least propylene and ethylene, exhibit good flexibility, transparency, and heat resistance.
    Type: Grant
    Filed: July 29, 2004
    Date of Patent: September 12, 2006
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Fumihiko Shimizu, Kenjirou Takayanagi, Naomasa Sato, Fumiyoshi Yamada, Shixuan Xin
  • Publication number: 20060178486
    Abstract: A polymer is provided which, even when no halogen such as chlorine is contained therein, has satisfactory adhesiveness and applicability in coating to propylene polymers as substrates and which has surface hydrophilicity. It is a propylene block copolymer characterized by being represented by the following formula (I): PP-a-R??(I) (wherein PP represents a polypropylene segment in which the proportion of pentads represented by mmmm to all pentads is 10-60%; symbol a represents a group which connects PP to R; and R represents a polymer segment containing polar groups).
    Type: Application
    Filed: January 17, 2006
    Publication date: August 10, 2006
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Toru Suzuki, Fumihiko Shimizu
  • Publication number: 20050281990
    Abstract: An electrophotographic transfer paper has a substrate and a thermoplastic foamed resin layer which is provided on at least one surface of the substrate and has pores. In the electrophotographic transfer paper, the temperature at which the viscosity of the thermoplastic foamed resin layer becomes 1×100 Pa•s ranges from 60° C. to 100° C. and a gradient R of a viscosity-temperature curve of the thermoplastic foamed resin layer defined by the following Equation (1) ranges from 0.02 to 0.10: R={Log(?t)?Log(?t+20)}/20??(1) where ?t indicates 1×104 Pa•s and ?t+20 indicates the viscosity (Pa•s) of the thermoplastic foamed resin layer at the temperature higher by 20° C. than the temperature showing the viscosity ?t.
    Type: Application
    Filed: January 26, 2005
    Publication date: December 22, 2005
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Eizo Kurihara, Ryosuke Nakanishi, Tsukasa Matsuda, Tomofumi Tokiyoshi, Fumihiko Shimizu
  • Publication number: 20050230861
    Abstract: An injection-foaming molding process for manufacturing a formed article by injecting a molten resin containing a foaming agent into a cavity of a mold being retained in an openable state and then expanding the cavity by opening the mold to allow the resin to foam includes: i) a step of discontinuing a cavity of a mold from a resin-reserving section located at front end of a screw immediately after the completion of injection of a molten resin containing an expandable resin into the mold cavity; and ii) a step of keeping the resin-reserving section under pressure at least equal to back pressure for charging during a period from the completion of injection to start of charging the molten resin containing the expandable resin for next shot, decreasing pressure in the resin-reserving section to back pressure for charging, and then starting the charging. According to the process, a molding cycle can be shortened and a lightweight formed article by foaming having high rigidity and good appearance can be obtained.
    Type: Application
    Filed: February 28, 2003
    Publication date: October 20, 2005
    Applicant: UBE MACHINERY CORPORATION, LTD.
    Inventors: Hiroyuki Takatori, Akio Okamoto, Naoto Yamamoto, Fumihiko Shimizu
  • Publication number: 20050153227
    Abstract: The present invention provides an image forming method including forming an image on a transfer paper for electrophotography by using oilless fixing, in which the transfer paper for electrophotography comprises a thermoplastic foam resin layer on at least one side of a substrate, the thermoplastic foam resin layer containing a thermoplastic resin having a softening point of 50° C. to 120° C. as determined according to JIS K 7234 (Ring and Ball method), and the thermoplastic foam resin layer having an average void size of 0.5 ?m to 50 ?m on the surface thereof. A difference between a gloss before the fixing and a gloss after the fixing, on a non-image portion, is 10% to 100%.
    Type: Application
    Filed: December 28, 2004
    Publication date: July 14, 2005
    Applicant: FUJI XEROX CO., LTD.
    Inventors: Eizo Kurihara, Ryosuke Nakanishi, Tsukasa Matsuda, Tomofumi Tokiyoshi, Fumihiko Shimizu
  • Publication number: 20050131160
    Abstract: Soft propylene-based resin compositions, which comprise substantially the following block (I) and block (II): Block (I): propylene-based polymer having propylene unit chain segments that bond in a mode of head-to-tail bonding, in which the chain segment has an isotactic block-containing stereoblock structure; Block (II): copolymer containing at least propylene and ethylene, exhibit good flexibility, transparency, and heat resistance.
    Type: Application
    Filed: July 29, 2004
    Publication date: June 16, 2005
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Fumihiko Shimizu, Kenjirou Takayanagi, Naomasa Sato, Fumiyoshi Yamada, Shixuan Xin
  • Publication number: 20050124753
    Abstract: A polypropylene type aqueous dispersion comprising the following components (a) to (c): (a) a polypropylene type polymer 100 parts by weight and/or a modified polypropylene type polymer (b) a surfactant 1 to 100 parts by weight, and (c) water 100 to 1,000 parts by weight, wherein the component (a) has a main chain having the following features (1) and (2) and dispersion particles in the dispersion have an average particle size of at most 0.5 ?m, Feature (1) when observing a peak derived from a carbon atom of a methyl group in a propylene unit chain part comprising a head-to-tail bond by 13C-NMR and fixing a chemical shift of a peak top at a peak attributable to pentad expressed by mmmm to 21.8 ppm, a ratio (S1/S) of an area S1 of a peak of a peak top at 21.8 ppm to a total area S of peaks at from 19.8 ppm to 22.1 ppm is at least 10% and at most 60%, and when an area of a peak (mmmr) of a peak top at 21.5 to 21.
    Type: Application
    Filed: October 26, 2004
    Publication date: June 9, 2005
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Teruaki Ashihara, Masato Onoe, Kazuyuki Hata, Fumihiko Shimizu, Naomasa Sato, Yukihito Zanka, Kouichi Nakayama
  • Patent number: 6887943
    Abstract: This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.
    Type: Grant
    Filed: October 31, 2002
    Date of Patent: May 3, 2005
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Masato Onoe, Teruaki Ashihara, Kazuyuki Hata, Fumihiko Shimizu, Naomasa Sato, Akio Tanna
  • Publication number: 20050075441
    Abstract: This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.
    Type: Application
    Filed: November 12, 2004
    Publication date: April 7, 2005
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Masato Onoe, Teruaki Ashihara, Kazuyuki Hata, Fumihiko Shimizu, Naomasa Sato, Akio Tanna
  • Patent number: 6846395
    Abstract: The present invention relates to an edge insulation member for an electrode plate used for electrolytic refinement of metal, and to a fixing method for it. On a tip portion 22A of a main body 22, a fitting groove 23 and a jaw portion 24 for tightly fitting an electrode plate 1 are formed to extend along the lengthwise direction of the main body 22. On a base end portion of the main body 22, an engagement notch 25 for fitting a support rod 26 is formed to extend along the lengthwise direction of the main body 22. A plurality of pin insertion holes 27 are formed on the side surface of the jaw portion 24. Fitting jigs made up from a pin 30 and a stopper 40 is removably fitted in this pin insertion hole 27. The support rod 26 is removably fitted in the engagement notch 25.
    Type: Grant
    Filed: June 12, 2001
    Date of Patent: January 25, 2005
    Assignee: Mitsubishi Materials Corporation
    Inventors: Hiroshi Tanaka, Fumihiko Shimizu
  • Publication number: 20040162403
    Abstract: An object of the present invention is to provide a novel propylene-based polymer capable of providing a propylene-based polymer with a good adhesion and coatability.
    Type: Application
    Filed: August 29, 2003
    Publication date: August 19, 2004
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Fumihiko Shimizu, Naomasa Sato, Akira Kuwahara, Fumiyoshi Yamada, Akio Tanna
  • Publication number: 20040020765
    Abstract: The present invention relates to an edge insulation member for an electrode plate used for electrolytic refinement of metal, and to a fixing method for it. On a tip portion 22A of a main body 22, a fitting groove 23 and a jaw portion 24 for tightly fitting an electrode plate 1 are formed to extend along the lengthwise direction of the main body 22. On a base end portion of the main body 22, an engagement notch 25 for fitting a support rod 26 is formed to extend along the lengthwise direction of the main body 22. A plurality of pin insertion holes 27 are formed on the side surface of the jaw portion 24. Fitting jigs made up from a pin 30 and a stopper 40 is removably fitted in this pin insertion hole 27. The support rod 26 is removably fitted in the engagement notch 25.
    Type: Application
    Filed: May 27, 2003
    Publication date: February 5, 2004
    Inventors: Hiroshi Tanaka, Fumihiko Shimizu
  • Publication number: 20040024149
    Abstract: Methods and compositions for the generation of quasi-living catalysts for homo-polymerization of olefins such as ethylene, &agr;-olefins and functionalized olefins and for the co-polymerization of olefins with functionalized monomers is disclosed. A process for producing these homo- and co-polymers is also disclosed. A polymeric material with enhanced hydrophilic properties, generated by the co-polymerization of ethylene with 5-norbornen-2-yl acetate, is also disclosed.
    Type: Application
    Filed: March 3, 2003
    Publication date: February 5, 2004
    Inventors: Guillermo C. Bazan, Prasenjit Ghosh, Fumihiko Shimizu
  • Publication number: 20030153686
    Abstract: This invention provides a graft modified polypropylene polymer which does not contain halogens, is excellent in certain properties such as solubility and can add good adhesiveness and coating ability to crystalline propylene polymer base materials, and a composition containing the same; and in particular, it provides a propylene polymer which contains a propylene polymer main chain having a stereo-block structure containing an isotactic block and a side chain containing a carboxylic acid group, an acid anhydride group or a carboxylic acid ester group, wherein when it is dissolved in toluene to a concentration of 10% by weight at 25° C., the insoluble matter is 1% by weight or less based on the total polymer, and a composition containing the same.
    Type: Application
    Filed: October 31, 2002
    Publication date: August 14, 2003
    Applicant: MITSUBISHI CHEMICAL CORPORATION
    Inventors: Masato Onoe, Teruaki Ashihara, Kazuyuki Hata, Fumihiko Shimizu, Naomasa Sato, Akio Tanna
  • Patent number: 6191232
    Abstract: The present invention provides a propylene block copolymer comprising polymer particles whose rubber-like component contents are 50% by weight or more, in an amount less than 1.0% by weight of the whole polymer particles finally discharged from a polymerization system.
    Type: Grant
    Filed: October 2, 1998
    Date of Patent: February 20, 2001
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Kenji Mitsutani, Kiyoshi Yukawa, Fumihiko Shimizu, Glen H. Ko, Eiji Tanaka, Fuminao Watanabe
  • Patent number: 5859143
    Abstract: A process for continuously producing a propylene-based block copolymer having an excellent impact resistance of the present invention, comprises:a first polymerization step comprising polymerizing .alpha.-olefin comprising propylene in the presence of hydrogen and a stereoregular polymerization catalyst comprising a solid catalyst component containing magnesium, titanium, halogen atom and an electron-donor compound, an organoaluminum compound and, if required, an electron-donar compound in a single polymerization reactor; anda second polymerization step comprising transporting .alpha.-olefin polymer obtained in the first polymerization step to a copolymerization reactor and copolymerizing propylene with .alpha.-olefin other than propylene in a gas phase substantially in the presence of said stereoregular polymerization catalyst used in the first polymerization step.
    Type: Grant
    Filed: April 16, 1997
    Date of Patent: January 12, 1999
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Eiji Tanaka, Fumihiko Shimizu
  • Patent number: 5308811
    Abstract: A catalyst for polymerizing an olefin which consists essentially of a product obtained by contacting (A) a metallocene-type transition metal compound, (B) at least one member selected from the group consisting of clay, clay minerals, ion exchanging layered compounds, diatomaceous earth, silicates and zeolites, and (C) an organic aluminum compound.
    Type: Grant
    Filed: May 1, 1992
    Date of Patent: May 3, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yoshinori Suga, Yasuo Maruyama, Eiji Isobe, Toru Suzuki, Fumihiko Shimizu