Abstract: A biofuel production method, catalyst and system. The method may include combining a feedstock comprising a carbonaceous material with a consumable catalyst to produce a feedstock/catalyst mixture, and subjecting the feedstock/catalyst mixture to a vacuum pyrolytic gasification and liquefaction process to produce one or more biofuels. The catalyst includes effective amounts of various catalyst constituents, which may include some or all of kaolin, zeolite, amorphous silica, alumina aluminum phosphate and rare earth elements. The system may include apparatus for heating the feedstock/catalyst mixture under selected temperature and vacuum pressure conditions to produce a gaseous effluent comprising one or more hydrocarbon fractions, and additional distillation and condensation apparatus to produce one or more liquid and gaseous fuels.