Abstract: An antifouling coating composition comprising a binder comprising a non-volatile amine and rosin or maleinised or fumarised rosin. The non-volatile amine is preferably an amine of the formula I ##STR1## where R.sup.1 is a monovalent hydrocarbon group derived from a diterpene and R.sup.2 and R.sup.3 are hydrogen, alkyl or aryl, preferably present in a proportion by weight of 9:1 to 1:9 relative to the rosin or maleinised or fumarised rosin.

Abstract: Fouling of a ship's hull is inhibited by an amine of the formula ##STR1## where R.sup.1 is a monovalent hydrocarbon group derived from a diterpene and R.sup.2 and R.sup.3 are each independently hydrogen, an alkyl group having 1 to 18 carbon atoms or an aryl group having 6 to 12 carbon atoms. The amine acts as a paint binder and as a marine biocide. An antifouling coating composition may comprise a pigment with the said amine as binder. Alternatively an antifouling coating composition comprises as binder an acid-functional polymer whose acid groups are blocked by a monoamine group which forms an organic-solvent-soluble salt of the polymer.

Abstract: An antifouling paint for ships' hulls, comprising a film-forming copolymer and a pigment component, has the property that a rough film of the paint becomes smoother in relatively moving seawater. The film-forming copolymer contains from more than 50 up to 80 percent by weight of units of at least one triorganotin salt of an olefinically unsaturated carboxylic acid, the balance of the copolymer being units of at least one olefinically unsaturated comonomer. The pigment component comprises a metalliferous pigment capable of reacting with seawater to form a water-soluble metal compound and a pigment which does not react with or dissolve in seawater.

Abstract: A top coat paint for ships' hulls comprisinga. a film-forming copolymer containing from more than 50 up to 80 per cent by weight of units of at least one tri-organo tin salt of an olefinically unsaturated carboxylic acid, the balance of the copolymer being units of at least one olefinically unsaturated comonomer,B. a substantially water insoluble metalliferous pigment capable of reacting with sea-water to form a water-soluble metal compound, andC. a hydrophobic organic retarder for retarding the rate of ion exchange between sea-water and the copolymer (a), which retarderI. has a solubility in sea-water at 25.degree. C. of not more than 5 parts per million by weight and is miscible with the copolymer (a),Ii. has a negligible vapour pressure at 25.degree. C. andIii. is present to the extent of at least 5 per cent by weight based on the weight of the tri-organo tin ion content of the copolymer (a).