Abstract: Glass compositions include one or more of silica (SiO2), magnesia (MgO) and alumina (Al2O3) as essential components and may optionally include sodium oxide (Na2O), potassium oxide (K2O), zirconia (ZrO2), titania (TiO2), zinc oxide (ZnO), manganese oxide (MnO2), hafnium oxide (HfO2) and other components. The glasses may be characterized by low density at room temperature.

Abstract: In embodiments, a precursor glass composition comprises from about 55 wt. % to about 80 wt. % SiO2; from about 2 wt. % to about 20 wt. % Al2O3; from about 5 wt. % to about 20 wt. % Li2O; greater than 0 wt % to about 3 wt. % Na2O; a non-zero amount of P2O5 less than or equal to 4 wt. %; and from about 0.2 wt. % to about 15 wt. % ZrO2. In embodiments, ZrO2 (wt. %)+P2O5 (wt. %) is greater than 3. When the precursor glass composition is converted to a glass-ceramic article, the glass-ceramic article may include grains having a longest dimension of less than 100 nm.

Abstract: Embodiments of a transparent glass-based material comprising a glass phase and a second phase that is different from and is dispersed in the glass phase are provided. The second phase may comprise a crystalline or a nanocrystalline phase, a fiber, and/or glass particles. In some embodiments, the second phase is crystalline. In one or more embodiments, the glass-based material has a transmittance of at least about 88% over a visible spectrum ranging from about 400 nm to about 700 nm and a fracture toughness of at least about 0.9 MPA·m½, and wherein a surface of the glass-based material, when scratched with a Knoop diamond at a load of at least 5 N to form a scratch having a width w, is free of chips having a size of greater than 3 w.

Abstract: Disclosed herein are glass-ceramic articles including a crystalline phase comprising a jeffbenite crystalline structure. The glass-ceramic articles may include a first surface, a second surface opposite the first surface, and a perimeter defining a shape of the glass-ceramic article. The glass-ceramic articles may further include a phase assemblage comprising one or more crystalline phases and a glass phase. The one or more crystalline phases may include a crystalline phase having the jeffbenite crystalline structure.

Abstract: ZrO2-toughened glass ceramics having high molar fractions of tetragonal ZrO2 and fracture toughness value of greater than 1.8 MPa·m1/2. The glass ceramic may also include also contain other secondary phases, including lithium silicates, that may be beneficial for toughening or for strengthening through an ion exchange process. Additional second phases may also decrease the coefficient of thermal expansion of the glass ceramic. A method of making such glass ceramics is also provided.

Abstract: Embodiments of a transparent glass-based material comprising a glass phase and a second phase that is different from and is dispersed in the glass phase are provided. The second phase may comprise a crystalline or a nanocrystalline phase, a fiber, and/or glass particles. In some embodiments, the second phase is crystalline. In one or more embodiments, the glass-based material has a transmittance of at least about 88% over a visible spectrum ranging from about 400 nm to about 700 nm and a fracture toughness of at least about 0.9 MPa·m1/2, and wherein a surface of the glass-based material, when scratched with a Knoop diamond at a load of at least 5 N to form a scratch having a width w, is free of chips having a size of greater than 3 w.

Abstract: A glass-ceramic comprising, in weight percent on an oxide basis, of 50 to 70% SiO2, 0 to 20% Al2O3, 12 to 23% MgO, 0 to 4% Li2O, 0 to 10% Na2O, 0 to 10% K2O, 0 to 5% ZrO2, and 2 to 12% F, wherein the predominant crystalline phase of said glass-ceramic is a trisilicic mica, a tetrasilicic mica, or a mica solid solution between trisilicic and tetrasilicic, and wherein the total of Na2O+Li2O is at least 2 wt. %; wherein the glass-ceramic can be ion-exchanged.

Abstract: One embodiment of the disclosure relates to a glass-ceramic with a phase assemblage comprising gillespite crystalline phase (BaFeSi4O10). According to some embodiments the glass-ceramic comprises at least one of: (a) barium silicate phase, (b) silica crystalline phase, (c) iron silicate phase.

Abstract: Disclosed herein are glass-ceramic articles including a crystalline phase comprising a jeffbenite crystalline structure. The glass-ceramic articles may include a first surface, a second surface opposite the first surface, and a perimeter defining a shape of the glass-ceramic article. The glass-ceramic articles may further include a phase assemblage comprising one or more crystalline phases and a glass phase. The one or more crystalline phases may include a crystalline phase having the jeffbenite crystalline structure.

Abstract: ZrO2-toughened glass ceramics having high molar fractions of tetragonal ZrO2 and fracture toughness value of greater than 1.8 MPa·m1/2. The glass ceramic may also include also contain other secondary phases, including lithium silicates, that may be beneficial for toughening or for strengthening through an ion exchange process. Additional second phases may also decrease the coefficient of thermal expansion of the glass ceramic. A method of making such glass ceramics is also provided.

Abstract: A glass-ceramic article comprises a petalite crystalline phase and a lithium silicate crystalline phase. The weight percentage of each of the petalite crystalline phase and the lithium silicate crystalline phase in the glass-ceramic article are greater than each of the weight percentages of other crystalline phases present in the glass-ceramic article. The glass-ceramic article has a transmittance color coordinate in the CIELAB color space of: L*=from 20 to 90; a*=from ?20 to 40; and b*=from ?60 to 60 for a CIE illuminant F02 under SCI UVC conditions. In some embodiments, the colorant is selected from the group consisting of TiO2, Fe2O3, NiO, Co3O4, MnO2, Cr2O3, CuO, Au, Ag, and V2O5.

Abstract: Embodiments of a transparent glass-based material comprising a glass phase and a second phase that is different from and is dispersed in the glass phase are provided. The second phase may comprise a crystalline or a nanocrystalline phase, a fiber, and/or glass particles. In some embodiments, the second phase is crystalline. In one or more embodiments, the glass-based material has a transmittance of at least about 88% over a visible spectrum ranging from about 400 nm to about 700 nm and a fracture toughness of at least about 0.9 MPa·m½, and wherein a surface of the glass-based material, when scratched with a Knoop diamond at a load of at least 5 N to form a scratch having a width w, is free of chips having a size of greater than 3w.

Abstract: Disclosed herein are glass-ceramic articles including a crystalline phase comprising a jeffbenite crystalline structure. The glass-ceramic articles may include a first surface, a second surface opposite the first surface, and a perimeter defining a shape of the glass-ceramic article. The glass-ceramic articles may further include a phase assemblage comprising one or more crystalline phases and a glass phase. The one or more crystalline phases may include a crystalline phase having the jeffbenite crystalline structure.

Abstract: A group of glass compositions in the Li2O—Al2O3—SiO2—B2O3 family that can be chemically strengthened in single or multiple ion exchange baths containing at least one of NaNO3 and KNO3 for a short time (2-4 hours) to develop a deep depth of layer (DOL). In some instances, the DOL is at least 70 ?m; in others, at least about 100 ?m. The ion exchanged glasses have a high damage resistance (indentation fracture toughness ranging form greater than 10 kgf to greater than 50 kgf) that is better than or at least comparable to that of sodium aluminosilicate glasses.

Abstract: Embodiments of a transparent glass-based material comprising a glass phase and a second phase that is different from and is dispersed in the glass phase are provided. The second phase may comprise a crystalline or a nanocrystalline phase, a fiber, and/or glass particles. In some embodiments, the second phase is crystalline. In one or more embodiments, the glass-based material has a transmittance of at least about 88% over a visible spectrum ranging from about 400 nm to about 700 nm and a fracture toughness of at least about 0.9 MPa·m1/2, and wherein a surface of the glass-based material, when scratched with a Knoop diamond at a load of at least 5 N to form a scratch having a width w, is free of chips having a size of greater than 3w.

Abstract: Glass compositions include one or more of silica (SiO2), magnesia (MgO) and alumina (Al2O3) as essential components and may optionally include sodium oxide (Na2O), potassium oxide (K2O), zirconia (ZrO2), titania (TiO2), zinc oxide (ZnO), manganese oxide (MnO2), hafnium oxide (HfO2) and other components. The glasses may be characterized by low density at room temperature.

Abstract: A group of glass compositions in the Li2O—Al2O3—SiO2—B2O3 family that can be chemically strengthened in single or multiple ion exchange baths containing at least one of NaNO3 and KNO3 for a short time (2-4 hours) to develop a deep depth of layer (DOL). In some instances, the DOL is at least 70 ?m; in others, at least about 100 ?m. The ion exchanged glasses have a high damage resistance (indentation fracture toughness ranging form greater than 10 kgf to greater than 50 kgf) that is better than or at least comparable to that of sodium aluminosilicate glasses.

Abstract: In embodiments, a precursor glass composition comprises from about 55 wt. % to about 80 wt. % SiO2; from about 2 wt. % to about 20 wt. % Al2O3; from about 5 wt. % to about 20 wt. % Li2O; greater than 0 wt % to about 3 wt. % Na2O; a non-zero amount of P2O5 less than or equal to 4 wt. %; and from about 0.2 wt. % to about 15 wt. % ZrO2. In embodiments, ZrO2 (wt. %)+P2O5 (wt. %) is greater than 3. When the precursor glass composition is converted to a glass-ceramic article, the glass-ceramic article may include grains having a longest dimension of less than 100 nm.

Abstract: A transparent ?-quartz glass ceramic is provided. The glass ceramic includes a primary crystal phase including a ?-quartz solid solution, a secondary crystal phase including tetragonal ZrO2, and a lithium aluminosilicate amorphous phase. The glass ceramic may be ion exchanged utilizing molten nitrate salt baths. Methods for producing the glass ceramic are also provided.

Abstract: A transparent ?-spodumene glass-ceramic is provided. The glass-ceramic includes a primary crystal phase including a ?-spodumene solid solution, a secondary crystal phase including tetragonal ZrO2, and an amorphous phase. The glass-ceramic may be ion exchanged utilizing molten alkali nitrate salt baths. Methods for producing the glass-ceramic are also provided.