Patents by Inventor Gerard Hillion

Gerard Hillion has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20050113588
    Abstract: A process that employs a heterogeneous catalyst comprising a zinc aluminate mixed oxide and having the following formula: ZnAl2O4, xZnO, yAl2O3 in which x and y each represent a number in the range 0 to 2, and in which the zinc aluminate is more particularly of the spinel type, makes it possible, by means of C1 to C5 monoalcohols, to: transesterify vegetable or animal oils having a natural free acidity, such as unrefined degummed rapeseed, soya, sunflower oils or exotic oils of the African oil, palm nut oil or coconut oil type, which are naturally rich in fatty acids; and simultaneously esterify their free acidity; so as to use phospholipid free and/or degummed unrefined acid oil with an acid number in the range 0.5 to 20, for example 1 to 15 and preferably 2 to 12, to produce esters, for example methyl esters, for use as fuels.
    Type: Application
    Filed: March 17, 2004
    Publication date: May 26, 2005
    Inventors: Gerard Hillion, Dominique Le Pennec
  • Patent number: 6878837
    Abstract: Alkyl esters of fatty acids, and high purity glycerin, are produced using a process comprising a set of transesterification reactions between a vegetable or animal oil and an aliphatic monoalcohol employing a heterogeneous catalyst, for example based on zinc aluminate, the water content in the reaction medium being controlled to a value that is below a given limiting value.
    Type: Grant
    Filed: April 11, 2003
    Date of Patent: April 12, 2005
    Assignee: Institut Francais du Petrole
    Inventors: Laurent Bournay, Gerard Hillion, Pierre Boucot, Jean-Alain Chodorge, Charles Bronner, Alain Forestiere
  • Publication number: 20040234448
    Abstract: The preparation of a crush-resistant transesterification catalyst of the formula:
    Type: Application
    Filed: March 17, 2004
    Publication date: November 25, 2004
    Inventors: Gerard Hillion, Serge Leporq, Dominique Le Pennec, Bruno Delfort
  • Publication number: 20040034244
    Abstract: Alkyl esters of fatty acids, and high purity glycerin, are produced using a process comprising a set of transesterification reactions between a vegetable or animal oil and an aliphatic monoalcohol employing a heterogeneous catalyst, for example based on zinc aluminate, the water content in the reaction medium being controlled to a value that is below a given limiting value.
    Type: Application
    Filed: April 11, 2003
    Publication date: February 19, 2004
    Applicant: Institut Francais du Petrole
    Inventors: Laurent Bournay, Gerard Hillion, Pierre Boucot, Jean-Alain Chodorge, Charles Bronner, Alain Forestiere
  • Patent number: 6492430
    Abstract: A process for preparing a composition comprising a mixture with ester and amine function in the form of ester-amines, amines, salts of amines, monoglycerides and diglycerides all derived from monomeric, dimeric, trimeric, and/or tetrameric fatty acids contained in polymerized polyunsaturated oil comprising: (a) polymerizing a polyunsaturated vegetable or animal oil to form a polymerized oil, (b) treating the polymerized oil with water vapor, and (c) reacting the polymerized oil with an excess of at least one compound containing at least one hydroxyl function and at least one tertiary amine function, optionally in the presence of a catalyst. Said methods further comprise adding the compositions to an oil effluent as dispersing agents for hydrates.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: December 10, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Gérard Hillion, Isabelle Durand, Anne Sinquin, Marie Velly
  • Patent number: 6476081
    Abstract: In order to manufacture a composition mainly containing compounds with ester and amide functions, in particular in the form of ester-amides, as well as compounds with amine functions, such as ester-amines, the salts of amines, monoglycerides and diglycerides, formed from monomeric, dimeric, trimeric and/or tetrameric fatty acids contained in a polymerized polyunsaturated oil, a process is implemented which comprises the following stages: a) use (or preparation) of a polymerized oil by polymerization of a polyunsaturated vegetable or animal oil; b) treatment of said polymerized oil by entrainment with water vapor; and c) reaction of the polymerized oil thus treated with an excess of at least one aminoalcohol, in the presence or not of a catalyst. This composition can be used as an emulsifying and dispersing surfactant, in particular as an additive for dispersing hydrates in oil effluents.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: November 5, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Gérard Hillion, Isabelle Durand, Anne Sinquin, Marie Velly
  • Patent number: 6452029
    Abstract: A nickel catalytic system that makes it possible to obtain branched compounds from fatty substances by reacting simple olefins on polyunsaturated esters, which may or may not be conjugated, is described. The compounds that are obtained may be hydrogenated and used as lubricant bases or may be transformed according to known procedures into compounds of acid, alcohol, amine or amide type, used in varied applications.
    Type: Grant
    Filed: July 28, 1999
    Date of Patent: September 17, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Gérard Hillion, Hélène Olivier, Katja Siepen, Dominique Commereuc, Robert Stern
  • Patent number: 6444831
    Abstract: To obtain branched compounds from fatty substances, simple olefins are reacted on polyunsaturated esters, which may or may not be conjugated, in the presence of an iron catalytic system, whereby the products that are obtained, primarily mono-addition compounds, can be hydrogenated and transformed into various compounds that can be used in particular as a base for surfactants, emulsifiers, emollients, lubricants or heavy metal salts.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: September 3, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Ingrid Bach, Gérard Hillion, Héléne Olivier
  • Patent number: 6221920
    Abstract: The following are described herein: a composition that consists of a mixture that comprises at least amides, amines, ester-amides, ester-amines, amine salts and monoglycerides, that are all derived from monomeric, dimeric, trimeric and/or tetrameric fatty acids; a process for the production of said composition which comprises the transamidification reaction of a polyunsaturated vegetable oil that is polymerized thermally, with an excess of at least one amino alcohol, which may or may not be in the presence of a catalyst; and the uses of this composition particularly as an emulsifying agent that allow it, depending on the nature of the oil, to form an oil-in-water or water-in-oil emulsion, as a solid-dispersing agent, or as an agent for the stabilization of foams in a liquid or an emulsion.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: April 24, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Gérard Hillion, Isabelle Durand, Robert Stern, Marie Velly
  • Patent number: 6153772
    Abstract: A cobalt catalytic system that makes it possible to obtain branched compounds from fatty substances by reacting simple olefins on polyunsaturated esters, which may or may not be conjugated, is described.The compounds that are obtained may be hydrogenated and used as lubricant bases.
    Type: Grant
    Filed: July 24, 1998
    Date of Patent: November 28, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Gerard Hillion, Helene Olivier, Katja Siepen, Robert Stern
  • Patent number: 6147196
    Abstract: In order to produce a composition of esters of linear monocarboxylic acids containing 6 to 26 carbon atoms and glycerine simultaneously with high degrees of purity, the following is carried out:a step a) in which a plant or animal oil, which may or may not be acidic, is reacted with an excess of at least one aliphatic mono-alcohol containing 1 to 4 carbon atoms in the presence of a heterogeneous catalyst, eliminating the excess mono-alcohol and separating out glycerine, this step producing a crude ester containing residual mono-glycerides;a step b) in which the crude ester obtained undergoes transesterification or esterification of the residual mono-glycerides to di- and tri-glycerides, in the presence of a heterogeneous catalyst; anda step c) in which the ester composition is evaporated under reduced pressure, recycling the evaporation residue to the starting oil of step a). The ester compositions obtained, which are of high purity, are of particular use as gas oil substitutes.
    Type: Grant
    Filed: December 17, 1998
    Date of Patent: November 14, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Robert Stern, Gerard Hillion, Jean-Jacques Rouxel
  • Patent number: 6013817
    Abstract: For the production of ethyl esters of fatty acids from fatty acid glycerides such as vegetable or animal oil or fat or other mixtures of glycerides, the process comprises the following stages: (a) transesterifying fatty acid glycerides with hydrated ethyl alcohol using an alkaline catalyst to form a medium comprising ethyl esters and excess ethyl alcohol; (b) adding a glycerine phase to said medium, and evaporating the excess ethyl alcohol to produce two immiscible phases, an ester phase and a glycerine phase A, and recycling said excess ethyl alcohol to stage (a); (c) separating said glycerine phase A and said ester phase to obtain the desired ethyl esters; (d) neutralizing said glycerine phase A with acid, and separating resultant "fatty acids+esters" phase and a glycerine phase B, and drying the latter phase; (e) subjecting the "fatty acids+esters" phase to glycerolysis with at least a fraction of the dried glycerine phase B in the presence of an alkaline catalyst to form a mixture of glycerides and esters
    Type: Grant
    Filed: May 7, 1997
    Date of Patent: January 11, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Robert Stern, Gerard Hillion, Mohammed Neguib Eisa
  • Patent number: 5958844
    Abstract: A method of transporting hydrates suspended in a fluid comprising water, a gas and a liquid hydrocarbon is described in which at least one non-ionic amphiphilic composition obtained by reacting at least one polymerized unsaturated vegetable oil with an aminoalcohol is incorporated into the fluid. The non-ionic amphiphilic composition is generally introduced in a concentration of 0.1% to 5% by weight with respect to the water.
    Type: Grant
    Filed: September 25, 1998
    Date of Patent: September 28, 1999
    Assignee: Institut Francais du Petrole
    Inventors: Anne Sinquin, Marie Velly, Gerard Hillion, Jean-Pierre Durand
  • Patent number: 5908946
    Abstract: For the production of linear monocarboxylic acid esters with 6 to 26 carbon atoms vegetable oils or animal oils, which may or may not be neutral, are reacted with monoalcohols having a low molecular weight, for example 1 to 5 carbon atoms, in the presence of a catalyst that is selected from among zinc oxide, mixtures of zinc oxide and aluminum oxide, and the zinc aluminates that correspond to the formula:ZnAl.sub.2 O.sub.4, x ZnO, y Al.sub.2 O.sub.3(with x and y each being in the range of 0-2) and having more particularly a spinel type structure, thereby enabling the direct production in one or more stages, of an ester that can be used as a fuel or combustible and a pure glycerine.
    Type: Grant
    Filed: August 8, 1997
    Date of Patent: June 1, 1999
    Assignee: Institut Francais du Petrole
    Inventors: Robert Stern, Gerard Hillion, Jean-Jacques Rouxel, Serge Leporq
  • Patent number: 5880298
    Abstract: For the oligomerization of a fatty ester or fatty acid containing conjugated double bonds, the reaction uses a catalyst consisting of an activated earth, e.g., montmorillonite, at a temperature of from 100.degree.-180.degree. C., preferably from 130.degree.-160.degree. C. The process can be carried out continuously or in a batch process on a fixed bed and is particularly applicable to conjugated methyl esters obtained by conjugating and transesterifying sunflower seed oil. The oligomerized products obtained are particularly useful as lubricants or polycondensation reactants.
    Type: Grant
    Filed: January 14, 1994
    Date of Patent: March 9, 1999
    Assignees: Institut Francais du Petrole, Onidol
    Inventors: Gerard Hillion, Robert Stern, Odile Le Borgne
  • Patent number: 5756471
    Abstract: The present invention relates to a cosmetic and/or dermatological composition comprising at least one sophorolipid in its crude or acid form or associated with a monovalent or divalent salt. The concentrations of the sophorolipid can be 0.01% to 30% by weight. In particular, the composition is in the form of a water-in-oil emulsion, and oil-in-water emulsion or an oil-in-water microemulsion. The sophorolipid-based compositions of the invention have a free radical formation inhibiting activity, an elastase inhibiting activity, or an anti-inflammatory activity.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: May 26, 1998
    Assignees: Institut Francais du Petrole, Sophor S.A.
    Inventors: Gerard Hillion, Remy Marchal, Corinne Stoltz, Frederique Borzeix
  • Patent number: 5744046
    Abstract: A process is described for the treatment of an aqueous medium which has been polluted with hydrocarbon compounds, termed crude oil, and a demulsifying and dispersing composition. The crude oil is brought into contact with a solution of a mixture of polyglycerol esters in a proportion of at least 50 ppm by weight in order to inhibit formation of a water-in crude oil emulsion or to partially break the emulsion if it has already formed. The polyglycerol esters can be combined with a surfactant, preferably an anionic surfactant, such as a sodium alkylsulphosuccinate.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: April 28, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Christine Dalmazzone, Gerard Hillion
  • Patent number: 5670437
    Abstract: The method of preparation comprises:a step (a) of placing in solution at least one compound of at least one metal A in at least one organic solvent S, and of at least one reducing compound R of at least one metal B in at least one organic solvent S',a step (b) of placing the reducing compound R in contact with the metal A compound,a step (d) of neutralisation of the residual reducing functions of the reducing compound R with at least one oxidizing agent O,and where applicable the addition of a selectivity agent P either during step (a) or during step (c) placed between steps (b) and (d),The catalyst obtained can be used in selective or total hydrogenation.
    Type: Grant
    Filed: January 13, 1995
    Date of Patent: September 23, 1997
    Assignee: Institut Francais du Petrole
    Inventors: Daniel Durand, Gerard Hillion, Patrick Sarrazin
  • Patent number: 5476956
    Abstract: Co dimerization is conducted of at least one monoolefin, for example a monoolefinic hydrocarbon such as ethylene, propylene or 1-butene, a halogenated monoolefin such as vinyl chloride, or an olefinic functional compound such as methyl acrylate, acrylonitrile, allyl acetate or vinyl acetate, with at least one polyolefin containing at least two conjugated or unconjugated ethylene bonds, for example a diene hydrocarbon such as 1,3-butadiene, piperylene, or isoprene or a polyolefin containing a carboxylic function, such as a fatty acid or a fatty acid ester having 14 to 24 carbon atoms in the fatty chain derived, for example, from a natural oil. The reaction is carried out in the presence of a catalytic system having general formula [RhX.sub.4 ][YR.sub.4 ] where X represents a halogen ion or a SO.sub.4.sup.--, SO.sub.3.sup.-, OH.sup.-, OR.sup.- or R.sup.
    Type: Grant
    Filed: April 25, 1994
    Date of Patent: December 19, 1995
    Assignee: Institut Francais Du Petrole
    Inventors: Gerard Hillion, Robert Stern, Abakar Kotoko, Yves Chauvin
  • Patent number: 5434282
    Abstract: A novel family of chemical compounds derived from fatty compounds has two branches of two carbon atoms on the linear chain and general formula C.sub.21 H.sub.39 COOR where R represents a hydrogen atom, a lower alkyl radical or a glyceryl radical. Particular compounds for consideration have the following formulae:(C.sub.2 H.sub.5).sub.2 C.sub.17 H.sub.29 COOR (I)(C.sub.2 H.sub.5)(C.sub.2 H.sub.4)C.sub.17 H.sub.30 COOR (II)and(C.sub.2 H.sub.5)(C.sub.2 H.sub.3)C.sub.17 H.sub.31 COOR (III)also compounds with the following formulae derived from partial or total hydrogenation of the above:(C.sub.2 H.sub.5).sub.2 C.sub.17 H.sub.31 COOR (IV)(C.sub.2 h.sub.5)(C.sub.2 h.sub.4)C.sub.17 H.sub.32 COOR (V)andti (C.sub.2 H.sub.5).sub.2 C.sub.17 H.sub.33 COOR (VI)Compounds with formulae (I), (II) and (III) may be produced by addition of ethylene to compositions comprising mainly diunsaturated C.sub.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: July 18, 1995
    Assignee: Institut Francais du Petrole
    Inventors: Robert Stern, Gerard Hillion, Abakar Kotoko, Yves Chauvin