Patents by Inventor Gernot Horlbeck
Gernot Horlbeck has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4891406Abstract: The production of high impact strength molding compositions obtained by thermal treatment of synthetic resin mixtures containing predominantly polyalkylene terephthalate, in the solid form, characterized in that the synthetic resin mixture containsA. 70-95% or 60-97% by weight of polyalkylene terephthalate andB. when A is 70-95%, 5-30% by weight of a conventional, elasticizing acrylate graft copolymer, a conventional .alpha.-olefin copolymer or a conventional polyether amide, or when A is 60-97%, 3-40% of a conventional polyether ester amide,and that the synthetic resin mixture is treated at temperatures of 15.degree.-60.degree. C. below the melting point of the pure component A in an inert gas atmosphere.Type: GrantFiled: July 9, 1987Date of Patent: January 2, 1990Assignee: Huels AktiengesellschaftInventors: Josef Bittscheidt, Gernot Horlbeck, Salih Mumcu
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Patent number: 4588785Abstract: Block copolyester amides having improved properties are applied as thermoplastic adhesives to textiles. Their melting points are between 80.degree. and 135.degree. C. and the block copolyester amides are prepared by polycondensing:(A) 60 to 95% by weight of a block polyester having terminal hydroxy groups and consisting of at least 50 molar % of the acid proportion of terephthalic acid and 40 to 90 molar percent of an alcohol proportion of 1.4-butanediol and 60 to 10 molar percent of 1.6-hexanediol, wherein up to 10 molar percent referred to 1,6-hexanediol can be replaced by aliphatic diols with longer chains; and(B) 40 to 5% by weight of a block polyamide dicarboxylic acid having a mean molecular weight M.sub.n between 1,000 and 8,000 and obtained from omega-amino-carboxylic acids or lactams having 6 to 12 carbon atoms or their mixtures with aromatic or aliphatic dicarboxylic acids.Type: GrantFiled: July 3, 1985Date of Patent: May 13, 1986Assignee: Chemische Werke Huls AktiengesellschaftInventors: Hanns-Jorg Bax, Gernot Horlbeck, Rainer Feldmann, Salih Mumcu
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Patent number: 4496713Abstract: Molding compositions having high toughness and hot-water resistance, comprise copolyesters based on polybutylene terephthalate and containing as co-component, 5-25 molar percent (based on total diol component) of a linear, long-chain diol. These copolyesters have a viscosity number <120 cc/g.Type: GrantFiled: October 24, 1983Date of Patent: January 29, 1985Assignee: Chemische Werke HuelsInventors: Gernot Horlbeck, Klaus Burzin
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Patent number: 4447573Abstract: A textile hot-melt adhesive comprises a mixture ofA. a linear, saturated, high-molecular weight copolyester (75-95 mole % of terephthalic acid, 5-25 mole % of (iso-)phthalic acid; 40-70 mole % of butanediol and 30-60 mole % of other aliphatic diols;B. 0.05-0.5% by weight of an inorganic powder (particle diameter: 0.5-3 .mu.m);C. 0.01-0.2% by weight of an alkaline earth metal salt of a fatty acid (particle diameter: 40-60 .mu.m; andD. optionally, customary auxiliary agents and additives.Type: GrantFiled: September 22, 1982Date of Patent: May 8, 1984Assignee: Chemische Werke Huels AGInventors: Gernot Horlbeck, Rainer Feldmann
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Patent number: 4434276Abstract: A process for the post condensation of poly(alkylene terephthalate) in the solid phase is carried out in the presence of esters of phosphorous acid at 25.degree.-65.degree. C. below the melting point of the poly(alkylene terephthalate) while passing an inert gas stream through the reaction mixture.Type: GrantFiled: March 31, 1983Date of Patent: February 28, 1984Assignee: Chemische Werke Huels AktiengesellschaftInventors: Gernot Horlbeck, Horst Heuer
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Patent number: 4387213Abstract: A process for condensing a linear polyalkylene terephthalate having a viscosity number of at least 60 cc/g in two stages, at an elevated temperature, in the solid phase, and in the presence of an alkanediol, comprises, in a first stage, treating the polyalkylene terephthalate in an inert gas stream at a reaction temperature 30.degree.-80.degree. C. below its melting point, with 0.2-3.5% by weight, based on the weight of the polyalkylene terephthalate, of an alkanediol whose boiling point under normal pressure is 20.degree.-70.degree. C. above the reaction temperature, wherein the amount of inert gas passed through per hour, measured under standard conditions, corresponds to 0.3 to 2 times the gross reactor volume; and, in a second stage, condensing the polyalkylene terephthalate in an inert gas stream at a temperature 5.degree.-25.degree. C. below its melting point, wherein the amount of inert gas passed through per hour, measured under standard conditions, corresponds to 2.Type: GrantFiled: December 22, 1980Date of Patent: June 7, 1983Assignee: Chemische Werke Huels AGInventors: Gernot Horlbeck, Horst Heuer, Hanns-Jorg Bax, Hans Jadamus
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Patent number: 4360661Abstract: A process for the regeneration and further condensation of a linear polyalkylene terephthalate, which is inactive due to recondensation treatment in the solid phase, and which has a viscosity number of at least 60 cc/g, the process being conducted in two stages, at an elevated temperature, in the presence of an alkanediol, comprises, in a first stage, treating the inactive polyalkylene terephthalate at a reaction temperature of 30.degree.-80.degree. C. below its melting point, with 0.3-3.5% by weight, based on the weight of the polyalkylene terephthalate, of an alkanediol whose boiling point under normal pressure is 20.degree.-70.degree. C. above the reaction temperature, in an inert gas stream, wherein the amount of inert gas passed through per hour, measured under standard conditions, corresponds to 0.3-2 times the gross reactor volume; and, in a second stage, condensing the polyalkylene terephthalate at a temperature of 5.degree.-25.degree. C.Type: GrantFiled: December 22, 1980Date of Patent: November 23, 1982Assignee: Chemische Werke Huels AGInventors: Gernot Horlbeck, Horst Heuer, Hanns-Jorg Bax, Hans Jadamus
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Patent number: 4328059Abstract: High molecular weight linear polyesters advantageous for use as hot melt adhesives and powder coating agents, are prepared by a process for preparing a high-molecular weight, linear copolyester by condensing 40-85 molar percent of terephthalic acid optionally in the form of a dialkyl ester, half of which component can optionally be replaced by another dicarboxylic acid also optionally in the dialkyl ester form, and 60-15 molar percent of adipic acid, with an alkanediol of 2-6 carbon atoms in its carbon chain, at an elevated temperature in the presence of a conventional catalyst, in a first condenstation stage which is an interesterification or esterification stage and a second condenstation stage which is a polycondensation stage, whereby a copolyester melt is produce. The process comprises, before or during the first condensation stage, adding 0.005-01 molar percent, based on the total acid component, of a C.sub.6 - aryl or C.sub.Type: GrantFiled: October 9, 1980Date of Patent: May 4, 1982Assignee: Chemische Werke Huels, A.G.Inventors: Gernot Horlbeck, Klaus Burzin
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Patent number: 4309518Abstract: Molding compositions comprisingA. 60-97% by weight, based on the weight of the total composition, of a poly(alkylene terephthalate) andB. 3-40% by weight, based on the weight of the total composition, of a polyether ester amide, component A being the condensation product of(1) 80-100 molar percent of terephthalic acid, and(2) 0-20 molar percent of another hydrocarbonaromatic-,cycloalkane- or alkane-dicarboxylic acid of 6-36 C atoms, with(3) 80-100 molar percent of a 1,n-alkanediol of 2-4 C atoms, wherein n is an integer of 2 to 4, and(4) 0-20 molar percent of another alkane- or cycloalkane-diol of 3-12 C atoms, component B being the condensation product of(1) at least one polaymide-forming .omega.Type: GrantFiled: July 25, 1980Date of Patent: January 5, 1982Assignee: Chemische Werke Huels, AktiengesellschaftInventors: Gernot Horlbeck, Salih Mumcu
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Patent number: 4208527Abstract: In a process for preparing high molecular weight poly-(ethylene terephthalate) in two stages, comprising, in the first stage, reacting a dialkyl ester of terephthalic acid with ethylene glycol in the presence of 35 to 290 ppm of manganese, in the form of a manganese-II salt effective as a catalyst, together with 6 to 95 ppm of cobalt, in the form of a cobalt-II salt effective as a catalyst, at a temperature of 170.degree. to 220.degree. C. to give a low molecular weight precondensate; then adding 45 to 140 ppm of phosphorus in the form of a phosphorus compound effective to minimize discoloration of the product poly-(ethylene terephthalate) due to said transesterification catalysts; and, in the second stage, effecting complete condensation of the precondensate thus obtained, in the presence of catalysts at a temperature of 270.degree.-290.degree. C.Type: GrantFiled: March 12, 1979Date of Patent: June 17, 1980Assignee: Chemische Werke Huls, AktiengesellschaftInventors: Gernot Horlbeck, Klaus Burzin, Roland Feinauer
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Patent number: 4200732Abstract: In a process for preparing very viscous, heat-stable poly(butylene terephthalate) by condensing terephthalic acid, or a lower alkyl ester thereof, with 1,4-butanediol in two stages at an elevated temperature and in the presence of conventional catalysts, an improvement comprises carrying out the condensation in the presence of 0.5 to 15 mole %, relative to the number of moles of terephthalic acid units, of 9,10-dihydro-9,10-[cis-11,12-bis(hydroxymethyl)-ethano]-anthracene.Type: GrantFiled: February 14, 1979Date of Patent: April 29, 1980Assignee: Chemische Werke Huls A.G.Inventors: Gernot Horlbeck, Klaus Burzin