Abstract: A composite oxygen ion transport membrane having a dense layer, a porous support layer, an optional intermediate porous layer located between the porous support layer and the dense layer and an optional surface exchange layer, overlying the dense layer. The dense layer has electronic and ionic phases. The ionic phase is composed of scandia doped, yttrium or cerium stabilized zirconia. The electronic phase is composed of a metallic oxide containing lanthanum, strontium, chromium, manganese and vanadium and optionally cerium. The porous support layer is composed of zirconia partially stabilized with yttrium, scandium, aluminum or cerium or mixtures thereof. The intermediate porous layer, if used, contains the same ionic and electronic phases as the dense layer. The surface exchange layer is formed of an electronic phase of a metallic oxide of lanthanum and strontium that also contains either manganese or iron and an ionic phase of scandia doped zirconia stabilized with yttrium or cerium.

Abstract: A method of forming a current collector layer on electrode layers of an electrochemical air separation element and a current collector. A slurry is prepared that contains electrically conductive particles having surface deposits of a metallic oxide on a metal or metal alloy conductor. The metallic oxide surface deposit constitutes a lower weight percentage of the electrically conductive particles than the metal or metal alloy. The slurry is applied to a structure that contains an electrolyte and electrode layers. The slurry can be applied by dip coating techniques. The resultant coated form is then fired to partly sinter the electrically conductive particles and thereby to obtain porous current collector layers affixed to the electrode layers. The current collector of the present invention is between about 5 microns and about 100 microns thick and preferably has a porosity of between about 10 percent and about 70 percent with pores having a pore size of between about 0.1 microns and about 20 microns.

Abstract: A current collector and method of forming the same in which a slurry is prepared that contains electrically conductive particles having surface deposits of a metallic oxide on a metal or metal alloy conductor that has a lower weight percentage of the electrically conductive particles than the metal or metal alloy. The slurry is applied to a structure that contains an electrolyte and electrode layers. The resultant coated form is then fired to partly sinter the electrically conductive particles and thereby to obtain porous current collector layers affixed to the electrode layers. The current collector of the present invention is between about 5 microns and about 100 microns thick and preferably has a porosity of between about 10 percent and about 70 percent with pores having a pore size of between about 0.1 microns and about 20 microns.

Abstract: A method of generating electrical power in which a synthesis gas stream generated in a gasifier is combusted in an oxygen transport membrane system of a boiler. The combustion generates heat to raise steam to in turn generate electricity by a generator coupled to a steam turbine. The resultant flue gas can be purified to produce a carbon dioxide product.

Abstract: An electrochemical cell assembly in which one or more grounded conduits, that can be an oxygen product tube or simply inlets or outlets, are connected to the electrically driven oxygen separator. In order to prevent the conduit(s) from degrading due to electrochemical reduction due to the electrical potential produced between the electrically driven oxygen separator(s) and the grounded conduit or conduits, a conduit is formed in whole or in part by a ceramic material that is an electric insulator and that is also resistive to electrochemical reduction. The ceramic material comprises distinct phases of magnesia and spinel or magnesia, spinel and yttrium aluminate.

Abstract: A composite oxygen ion transport membrane having a dense layer, a porous support layer, an optional intermediate porous layer located between the porous support layer and the dense layer and an optional surface exchange layer, overlying the dense layer. The dense layer has electronic and ionic phases. The ionic phase is composed of scandia doped, yttrium or cerium stabilized zirconia. The electronic phase is composed of a metallic oxide containing lanthanum, strontium, chromium, manganese and vanadium and optionally cerium. The porous support layer is composed of zirconia partially stabilized with yttrium, scandium, aluminum or cerium or mixtures thereof. The intermediate porous layer, if used, contains the same ionic and electronic phases as the dense layer. The surface exchange layer is formed of an electronic phase of a metallic oxide of lanthanum and strontium that also contains either manganese or iron and an ionic phase of scandia doped zirconia stabilized with yttrium or cerium.

Abstract: A hydrogen storage system and method having a main hydrogen storage site that contains a sufficient amount of hydrogen for a fuel cell employing a polymer membrane to generate power in accordance with a predetermined electrical power requirement. A main storage site is provided to store and supply hydrogen to meet the electrical power requirement for the fuel cell. An auxiliary hydrogen storage site contains a sufficient amount of hydrogen to allow the fuel cell to operate on a scheduled basis that is required to maintain the polymer membrane hydrated. A manifold connects the main and auxiliary hydrogen storage sites and has an outlet to deliver hydrogen to the fuel cell. The manifold allows the auxiliary hydrogen storage site to be renewed independently of the main storage site and has a flow control network to allow the fuel cell to draw hydrogen from the auxiliary hydrogen storage site for maintenance purposes without utilization of the hydrogen from the main hydrogen storage site.

Abstract: A hydrogen storage system and method having a main hydrogen storage site that contains a sufficient amount of hydrogen for a fuel cell employing a polymer membrane to generate power in accordance with a predetermined electrical power requirement. A main storage site is provided to store and supply hydrogen to meet the electrical power requirement for the fuel cell. An auxiliary hydrogen storage site contains a sufficient amount of hydrogen to allow the fuel cell to operate on a scheduled basis that is required to maintain the polymer membrane hydrated. A manifold connects the main and auxiliary hydrogen storage sites and has an outlet to deliver hydrogen to the fuel cell. The manifold allows the auxiliary hydrogen storage site to be renewed independently of the main storage site and has a flow control network to allow the fuel cell to draw hydrogen from the auxiliary hydrogen storage site for maintenance purposes without utilization of the hydrogen from the main hydrogen storage site.