Abstract: A method for the selective detection of liquid phase hydrocarbons in the C.sub.6 -C.sub.16 range includes a matrix comprising a silicone polymer having dispersed therein a conductive carbon black filler of high structure and comprises signaling the presence of hydrocarbon liquid phase when the electrical resistivity of the sensor increases to a preselected threshold level intermediate the vapor and liquid phase resistivities.

Abstract: A reactive gas detection system provides early warning of gas emissions that often occur in developing fire conditions in environments such as telephone system central offices where halogenated substances, for example polyvinyl chloride wire insulation and brominated fire retardant materials, are prevalent. Multiple microbalance detectors (122) comprising quartz crystal oscillators coated with a layer of zinc or zinc compound are distributed about a premises and the rate of change of crystal oscillation frequency is cyclically monitored by a frequency counter (130) under control of a data processor (112). The detectors are specifically reactive to the halogen acid gases emitted during pyrolysis of the noted substances and exhibit a significant differential frequency change in the presence one or more of these gases well in advance of the outbreak of flame, smoke, or other normally detectable combustion products.

Abstract: A variation of Pulsed Coulometric Detection (PCD) is described in which the detection potential is scanned in a cyclic fashion during current integration to achieve automatic and virtual elimination of baseline drift caused by surface roughening and changes in pH. The technique is examined at a Au electrode for flow-injection determination if thiourea which is typical of numerous sulfur compounds whose anodic reactions are catalyzed by formation of surface oxide. The baseline decays quickly to a near-zero equilibrium value following start-up and is unchanged for a pH step of ca. 2 units. The technique is concluded to be compatible with pH-gradient chromatography.