Abstract: Provided is method of making a three-dimensional object comprising polyurea, which may include: (a) dispensing a one part (1K) dual cure resin into a stereolithography apparatus, the resin comprising or consisting essentially of a photoinitiator, a reactive blocked polyisocyanate, optionally a catalyst such as a polyurethane blowing catalyst, and optionally a polyepoxide; (b) additively manufacturing from said resin an intermediate object comprising the light polymerization product of said reactive blocked polyisocyanate; (c) optionally cleaning said intermediate object; and (d) reacting said polymerization product in said intermediate with water in the presence of a catalyst such as a polyurethane blowing catalyst (which may be included in the resin, the water, or both) to generate polyamine in situ that sequentially reacts with the remainder of the polymerization product to form urea linkages and thereby produce a three-dimensional object comprising polyurea.

Abstract: An aerosol-generating device includes a vapor generation unit adapted to transform an aerosol forming material into vapor, and a vapor channel extending from the vapor generation unit to a vapor outlet of the aerosol-generating device. The vapor generation unit includes a micro electro-mechanical system (MEMS). The vapor channel is provided with a movable cover having a closed position in which it closes the vapor channel and an open position. The cover is adapted to move from the closed position to the open position under the effect of a suction applied on the aerosol-generating device by the user to vape. The cover has a lower face provided with a layer of an absorbent material adapted to imbibe the aerosol forming material. This protects the vaporisation device from any foreign particles and avoids liquid leakage.

Abstract: An aerosol-generating device includes a vapor generation unit and a reservoir configured to store an aerosolizable material. The aerosol-generation device further includes a printed circuit board and a heater fastened to the printed circuit board, the printed circuit board being disposed such that the aerosolizable material is in contact with the printed circuit board after it derives from the reservoir and before it arrives to the vapor generation unit.

Abstract: An aerosol-generating device includes a vapor generation unit, at least one reservoir configured to store an aerosol forming material, and a filter disposed so as to remove particles from the aerosol forming material passing from the at least one reservoir to the vapor generation unit, the vapor generation unit including a micro electro-mechanical system (MEMS). The aerosol-generating device is configured to heat the filter so as to heat the aerosol forming material passing through it.

Abstract: Provided is method of making a three-dimensional object comprising polyurea, which may include: (a) dispensing a one part (1K) dual cure resin into a stereolithography apparatus, the resin comprising or consisting essentially of a photoinitiator, a reactive blocked polyisocyanate, optionally a catalyst such as a polyurethane blowing catalyst, and optionally a polyepoxide; (b) additively manufacturing from said resin an intermediate object comprising the light polymerization product of said reactive blocked polyisocyanate; (c) optionally cleaning said intermediate object; and (d) reacting said polymerization product in said intermediate with water in the presence of a catalyst such as a polyurethane blowing catalyst (which may be included in the resin, the water, or both) to generate polyamine in situ that sequentially reacts with the remainder of the polymerization product to form urea linkages and thereby produce a three-dimensional object comprising polyurea.

Abstract: A tillage implement has a frame connectable to a towing vehicle and at least two transverse rows of secondary tillage tools mounted on the frame, the at least two transverse rows comprising a row of main rollers mounted on the frame rearward of all other rows of the at least two transverse rows. The implement also has a transverse row of auxiliary rollers mounted rearward of the row of main rollers, the transverse row of auxiliary rollers independently pivotable vertically about a transverse pivot axis. The implement has at least one ground-engaging wheel. Independent pivoting of the row of auxiliary rollers allows an operator to increase tillage/field finish on the go or as needed.

Abstract: Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.

Abstract: Provided herein is a resin product useful for the production of three-dimensional objects by additive manufacturing, and methods using the same. The resin may include a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups; a polyol; a photoinitiator; and at least one organometallic catalyst. A packaged product useful for the production of three-dimensional objects by additive manufacturing, the product comprising a single container having a single chamber and a resin in the chamber with all components mixed together, is also provided.

Abstract: Provided is method of making a three-dimensional object comprising polyurea, which may include: (a) dispensing a one part (1K) dual cure resin into a stereolithography apparatus, the resin comprising or consisting essentially of a photoinitiator, a reactive blocked polyisocyanate, optionally a catalyst such as a polyurethane blowing catalyst, and optionally a polyepoxide; (b) additively manufacturing from said resin an intermediate object comprising the light polymerization product of said reactive blocked polyisocyanate; (c) optionally cleaning said intermediate object; and (d) reacting said polymerization product in said intermediate with water in the presence of a catalyst such as a polyurethane blowing catalyst (which may be included in the resin, the water, or both) to generate polyamine in situ that sequentially reacts with the remainder of the polymerization product to form urea linkages and thereby produce a three-dimensional object comprising polyurea.

Abstract: Provided herein is a dual cure resin useful for the production of an object by additive manufacturing, comprising or consisting essentially of: (a) a photoinitiator; (b) not more than 5, 10 or 20 ppm of a polyurethane catalyst (e.g., tin, tertiary amine, bismuth, zinc, zirconium, or nickel catalysts); (c) a polyol; (d) free (i.e., unblocked) polyisocyanate; and (e) blocked polyisocyanate, the isocyanate groups of which are blocked by reaction with an amine (meth)acrylate blocking agent. Methods of making an object with the resin are also provided.

Abstract: Provided herein are methods of making (meth)acrylate blocked polyurethanes with zirconium catalysts, dual cure resins containing (meth)acrylate blocked polyurethanes and zirconium catalysts, methods of using the same in additive manufacturing, and products made therefrom.

Abstract: Provided herein is an additive manufacturing method of making a three-dimensional object comprising polyurea, comprising: (a) dispensing a one part (1K) dual cure resin into a stereolithography apparatus, the resin comprising or consisting essentially of a photoinitiator, a reactive blocked polyisocyanate, and optionally a polyepoxide, the reactive blocked polyisocyanate comprising the reaction product of a polyisocyanate and an amine or hydroxyl (meth)acrylate or (meth)acrylamide monomer blocking agent; (b) additively manufacturing from said resin an intermediate object comprising the light polymerization product of said reactive blocked polyisocyanate; (c) optionally cleaning said intermediate object; and (d) reacting said polymerization product in said intermediate with water to generate polyamine in situ that sequentially reacts with the remainder of the polymerization product to form urea linkages and hereby produce a three-dimensional object comprising polyurea.

Abstract: Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.

Abstract: A tillage implement for variable tillage has a linkage mechanism disposed longitudinally between two gangs of annular harrow tools, the gangs each having a toolbar that is rotationally mounted on a frame of the implement. The linkage mechanism has a plurality of pivotally connected linkage arms, the toolbars each pivotally connected to at least one of the linkage arms. Operation of the linkage mechanism simultaneously rotates one toolbar about a first vertical rotation axis and the other toolbar about a second vertical rotation axis in an opposite rotational direction as the first toolbar. The implement has at least one wheel mounted on the frame longitudinally forward of both of the gangs or longitudinally rearward of both of the gangs. The tillage implement provides variable tillage while having a shorter frame to facilitate folding wing sections of the frame in a more compact manner for transportation while remaining assembled.

Abstract: Provided herein are methods of making (meth)acrylate blocked polyurethanes with zirconium catalysts, dual cure resins containing (meth)acrylate blocked polyurethanes and zirconium catalysts, methods of using the same in additive manufacturing, and products made therefrom.

Abstract: Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.

Abstract: Provided herein are methods of making (meth)acrylate blocked polyurethanes with zirconium catalysts, dual cure resins containing (meth)acrylate blocked polyurethanes and zirconium catalysts, methods of using the same in additive manufacturing, and products made therefrom.

Abstract: Provided herein according to some embodiments is a dual cure additive manufacturing resin, comprising: (i) a light polymerizable component, (ii) a photoinitiator, (iii) a heat polymerizable component, and (iv) a non-reactive diluent, which resin is useful for the production of three-dimensional objects by additive manufacturing. Methods of using the same are also provided.

Abstract: A tillage implement has a frame connectable to a towing vehicle and at least two transverse rows of secondary tillage tools mounted on the frame, the at least two transverse rows comprising a row of main rollers mounted on the frame rearward of all other rows of the at least two transverse rows. The implement also has a transverse row of auxiliary rollers mounted rearward of the row of main rollers, the transverse row of auxiliary rollers independently pivotable vertically about a transverse pivot axis. The implement has at least one ground-engaging wheel. Independent pivoting of the row of auxiliary rollers allows an operator to increase tillage/field finish on the go or as needed.

Abstract: Provided herein is a resin product useful for the production of three-dimensional objects by additive manufacturing, and methods using the same. The resin may include a reactive blocked prepolymer comprising a prepolymer blocked with reactive blocking groups; a polyol; a photoinitiator; and at least one organometallic catalyst. A packaged product useful for the production of three-dimensional objects by additive manufacturing, the product comprising a single container having a single chamber and a resin in the chamber with all components mixed together, is also provided.