Abstract: Storage-stable crosslinkable RTV-1 compositions comprising at least one tin catalyst obtained by the reaction of at least one organotin compound with at least one monoorthophosphoric acid or mixture of mono and di-orthophosphoric acids, and at least one crosslinkable polysiloxane.

Abstract: The present invention relates to a process for the production of diorganyloxyorganosilyl- or triorganyloxysilyl-terminated poly(di-organosiloxanes) by reaction of .alpha.,.omega.-dihydroxypoly(diorganosiloxanes) with alkoxysilanes in the presence of catalytically active strong alkali metal bases.

Abstract: Polysiloxane compositions which harden in the presence of moisture by elimination of alcohols, which have high stability in storage while unvulcanized in the absence of moisture, which exhibit good adhesion to substrates, and which are improved by the presence of stabilizing silyl derivations of N-methyl benzamide contain:(A) 100 parts by weight of a polydimethyl siloxane which contains terminal diorganyloxyorganosilyl or triorganyloxylsilyl groups and which has a viscosity of 0.1 to 100 Pas,(B) 0 to 100 parts by weight of an .alpha.,.omega.-bis(trimethylsiloxy)-polydimethyl siloxane which has a viscosity of from 0.04 to 10 Pas,(C) 0 to 5 parts by weight of an alkoxysilane having the formulaR.sup.1.sub.a Si(OR.sup.2).sub.4-a,in whichR.sup.1 is C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 alkenyl or C.sub.5 -C.sub.6 aryl;R.sup.2 is C.sub.1 -C.sub.6 alkyl, and a is 0 or 1,(D) 0.

Abstract: A method of minimizing the adherence of ice on substrates which comprises coating said substrates with a polysiloxane composition which changes into a rubbery elastic material in the presence of water or atmospheric moisture which comprises .alpha.,.omega.-dihydroxy-polydiorganosiloxane having a viscosity of about 500 to 2,000,000 centipoise at 20.degree. C. and a cross-linking agent with or without a hardening catalyst.

Abstract: Improved polyorganosiloxane compositions which can be stored with the exclusion of moisture and harden on access to moisture are disclosed. These compositions contain, 100 parts by weight of an .alpha.,.omega.-dihdyroxypolydimethylsiloxane, 0 to 100 parts by weight of an .alpha.,.omega.-bis(trimethylsiloxy)polydimethylsiloxane plasticizer, 1 to 10 parts by weight of an oximinosilane, 5 to 250 parts by weight of a reinforcing or non-reinforcing filler or a filler mixture, 0.01 to 1 part by weight of a tin catalyst, 0.05 to 2.5 parts by weight of an aminoalkylalkoxysilane and 0.5 to 2.5 parts by weight of an accelerator chosen from alkyl or alkenyl carboxylic acids or silane derivatives of such carboxylic acids.

Abstract: A process for the preparation of triorganooxysilyl- or diorganooxyorganosilyl-terminated poly(diorganosiloxanes) or formulations containing such siloxanes comprising reacting .alpha.,.omega.-dihydroxypoly(diorganosiloxanes) with tetraorganyloxysilanes or triorganyloxyorganosilanes in the presence of an ammonium carbamate catalyst of the formula I ##STR1## wherein, R represents a hydrocarbon radical with 1-20 C atoms or an H atom, and where identical or different R radicals are in the molecule.The products produced by this process can be employed in the preparation of one-component silicone paste which harden into elastomers in the presence of moisture.

Abstract: The present invention relates to intumescent polysiloxane molding compositions containing expandable graphite compounds and, if appropriate, additionally nitrogen-containing phosphates.

Abstract: A silicone composition which is stable in the absence of moisture but which in the presence of water will cure at room temperature to an elastomer, comprising a polyorganosiloxane having reactive end groups, a polyester and a thickening filler.

Abstract: A process for the preparation of a plastic organopolysiloxane composition which can be stored in the absence of water and which is convertable even at room temperature into rubber-elastic compositions by the action of water or atmospheric moisture, comprising mixing a hydroxyl-terminated poly-diorganopolysiloxane with about 0.1-15% by weight of the total mixture of a substance of the formulaR.sub.W RO.sub.Z Si[NR"'R'R.sub.n Si(OR).sub.3-n ].sub.4-mwhereinR is an alkyl radical having 1-4 C atoms,R' is a divalent alkylene radical having 1-6 C atoms or a unit of the formula --(CH.sub.2).sub.3 NH(CH.sub.2).sub.2 -- or --(CH.sub.2).sub.2 --NH(CH.sub.2).sub.2 NH(CH.sub.2).sub.2 --,R"' is an alkyl radical having 1-4 C atoms, R.sub.W RO.sub.2 Si or hydrogen,n is 0, 1 or 2, andm=W+Z=0, 1, 2 or 3,or a partial hydrolysis product thereof as a crosslinking agent.

Abstract: The invention relates to special stable dispersions which crosslink at room temperature upon exposure to moisture in the atmosphere. The dispersions comprise polysiloxanes, vinyl-grafted polysiloxanes and condensation products, e.g. by weight approximately comprisingI. 20-90% of at least one diorganopolysiloxane optionally terminated by OH,II. 5-85% of at least one aliphatic or mixed aliphatic/aromatic polycondensation product or polyaddition product, polyether, or vinyl polymer with a glass temperature T.sub.G of up to 40.degree. C. and/or a vinyl monomer-grafted derivative thereof, andIII. 5-85% of at least one organopolysiloxane modified by grafting with at least one vinyl monomer and comprising(A) 10-90% of a diorganopolysiloxane optionally terminated by OH,(B) 10-90% of polymerized units of at least one vinyl compound, and(C) 0-80% of at least one aliphatic or mixed aliphatic/aromatic polycondensation product or polyaddition product, polyether, or vinyl polymer with a glass temperature T.sub.

Abstract: In a polysiloxane molding composition which in the presence of water crosslinks to an elastomer and which comprises(A) an .alpha.,.omega.-dihydroxyorganopolysiloxane with a viscosity of about 500 to 2,000,000 cP,(B) a crosslinking agent, and(C) a reinforcing filler,the improvement which comprises including therein in about 0.1 to 10% by weight a silicon compound containing at least 3 alkoxy groups and preferably of the formulaR.sub.n Si(Alkoxy).sub.4-nin whichR is alkyl with 1 to 10 carbon atoms,Alkoxy has 1 to 4 carbon atoms, andn is 0 or 1,whereby the elastomer ultimately produced exhibits improved direct adhesion to various substrates.

Abstract: In a plastic organosiloxane molding composition which in the absence of water is capable of being stored and in the presence of moisture is cross-linked to a rubber, the composition comprising a hydroxypolydiorganosiloxane, a nitrogen base and heavy metal compound as cross-linking catalyst, and a cross-linking agent, the improvement which comprises employing as the cross-linking agent a compound of the formula ##STR1## or a partial hydrolysis product thereof, wherein R is an optionally substituted alkyl, alkenyl or aryl group,R.sub.1 is hydrogen or R,R.sub.2 is an acyl, carbalkoxy or carbaroxy group or R.sub.1,a is 1-3, andn is 0, 1 or 2 and a+n.ltoreq.3.Upon curing no unpleasant odors are given off upon decomposition of the cross-linking agent.

Abstract: The present invention relates organopolysiloxane molding compositions which are capable of storage in the absence of moisture and which crosslink to give elastomers after the admission of water or steam, and are based on .alpha.,.omega.-dihydroxyorganopolysiloxanes and substances which produce crosslinking, a short-chain siloxane of the general formula ##STR1## being added, in addition to customary additives.

Abstract: A co-grafted polymer dispersion comprising blocks of an organopolysiloxane with OH functional groups, blocks of an ethylene/vinyl ester copolymer containing about 5 to 99% by weight of incorporated vinyl ester, and blocks of vinyl monomer units polymerized in the presence of mixtures of the organopolysiloxane and ethylene/vinyl ester copolymer, the organopolysiloxane and ethylene/vinyl ester copolymer blocks being linked via vinyl polymer bridges. The dispersions mixed with suitable catalysts, can cure under the influence of atmospheric moisture to elastic tack-free rubbers suitable as sealants.

Abstract: A co-grafted polymer comprising units of organopolysiloxanes with OH functional groups, polyesters and vinyl monomers, polymeric units of the vinyl monomers being linked to the organopolysiloxane and polyester units, is produced by polymerizing a suitable monomer dispersion. The product is suited for replacing all or some of the organopolysiloxane component in room temperature curable compositions containing organopolysiloxanes, silane cross-linking agents and a curing catalyst.

Abstract: A graft copolymer comprising (I) as a first polymeric moiety an organopolysiloxane with OH functional groups, (II) as a second polymeric moiety a polyether, and (III) units of vinyl monomer which have been polymerized in the presence of mixtures of the first and second polymeric moieties which moieties are linked via vinyl polymer bridges, is produced by polymerizing a suitable monomer dispersion. The product is suited for replacing all or some of the organopolysiloxane component in room temperature curable compositions containing organopolysiloxanes, silane cross-linking agents and a curing catalyst.

Abstract: In a plastic organopolysiloxane molding composition which can be stored in the absence of water and which changes into an elastomeric molding or coating under the effect of water or air, obtained by mixing an .alpha.,.omega.-dihydroxy polydiorgano siloxane with a carboxylic acid amidoalkyl alkoxy silicon compound as a crosslinking agent and a complex titanic acid ester and optionally with a filler, pigment and/or heavy metal salt known to accelerate the crosslinking reaction, the improvement which comprises including in the mixture about 0.2 to 15% by weight, based on the mixture as a whole, of a branched and/or cyclic paraffin hydrocarbon containing from 6 to 24 carbon atoms, whereby the resulting material after hardening can form a strongly adherent bond with a lacquer applied thereto.

Abstract: A graft copolymer comprising (I) as a first polymeric moiety an organopolysiloxane with OH functional groups, (II) as a second polymeric moiety a polyester-urethane and, (III) units of vinyl monomers, units of the first and second polymeric moieties being linked via vinyl polymer bridges, all these units having been polymerized in the presence of mixtures of the first and second polymeric moieties, is produced by polymerizing a suitable monomer dispersion. The product is suited for replacing all or some of the organopolysiloxane component in room temperature curable compositions containing organopolysiloxanes, silane cross-linking agents and a curing catalyst.

Abstract: In a process for the production of a plastic organopolysiloxane molding composition which can be stored under pressure and with exclusion of moisture, and which, on release of the pressure and under the action of water or atmospheric moisture, is converted into an elastomeric, fine-pored foam molding or foam coating, which comprises forming a mixture of an .alpha.,.omega.-dihydroxypolydiorganopolysiloxane with a silicon-containing crosslinking agent, introducing the mixture into the inner container of a two-container pack which consists of a rigid outer container and a flexible inner container located within the outer container and provided with a dispensing valve which extends to the exterior, and placing the mixture under pressure.

Abstract: An organopolysiloxane composition having a microbiocidal action comprising an .alpha.,.omega.-dihydroxypolydiorganosiloxane and a benzimidazolyl-alkyl-carbamate of the formula ##STR1## wherein R.sup.1 is an alkyl radical with 1 to 4 carbon atoms, optionally substituted by the radical --OR.sup.3,R.sup.3 is an alkyl radical with 1 to 4 carbon atoms or the phenyl radical, andR.sup.2 is hydrogen, an alkyl radical with 1 to 4 carbon atoms, haolgen or nitro.Advantageously the carbamate is methylbenzimidazolylmethyl-carbamate, N-(fluorodichloromethylthio)-phthalimide, is present as a synergistic fungicide and the composition further comprises a silicon-containing crosslinking agent for the siloxane, a heavy metal salt or amino accellerant for crosslinking and an .alpha.,.omega.-bis-(trimethylsiloxy)-polydimethylsiloxane. Water per se or in atmospheric air cures the composition to a rubber elastic product resistant to microbes.