Patents by Inventor Hercilio Rivas

Hercilio Rivas has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8647395
    Abstract: A surfactant package for a water-in-hydrocarbon emulsion includes a fatty acid component; a fatty acid salt component; an alcohol component and a salt of carboxylic acid. Emulsions formed using this surfactant package are stable and have ratios of water to surfactant of at least about 3.
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: February 11, 2014
    Assignee: Intevep, S.A.
    Inventors: Xiomara Gutierrez, Hercilio Rivas, Migdalia Carrasquero, Luis Marcano
  • Publication number: 20110209385
    Abstract: A surfactant package for a water-in-hydrocarbon emulsion includes a fatty acid component; a fatty acid salt component; an alcohol component and a salt of carboxylic acid. Emulsions formed using this surfactant package are stable and have ratios of water to surfactant of at least about 3.
    Type: Application
    Filed: August 27, 2010
    Publication date: September 1, 2011
    Applicant: INTEVEP, S.A.
    Inventors: Xiomara Gutiérrez, Hercilio Rivas, Migdalia Carrasquero, Luis Marcano
  • Patent number: 7704288
    Abstract: A water-in-hydrocarbon emulsion includes a water phase, a hydrocarbon phase and a surfactant, wherein the water phase is present in an amount greater than or equal to about 5% vol. with respect to volume of the emulsion, and the water phase and the surfactant are present at a ratio by volume of the water phase to the surfactant of at least about 1. A method for preparing the emulsion is also provided.
    Type: Grant
    Filed: August 28, 2007
    Date of Patent: April 27, 2010
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Xiomara Gutierrez, Manuel A. Gonzalez, Geoffrey McGrath, Migdalia Carrasquero, Francisco Lopez-Linares, Roberto Galiasso
  • Publication number: 20080060258
    Abstract: A water-in-hydrocarbon emulsion includes a water phase, a hydrocarbon phase and a surfactant, wherein the water phase is present in an amount greater than or equal to about 5% vol. with respect to volume of the emulsion, and the water phase and the surfactant are present at a ratio by volume of the water phase to the surfactant of at least about 1. A method for preparing the emulsion is also provided.
    Type: Application
    Filed: August 28, 2007
    Publication date: March 13, 2008
    Applicant: INTEVEP, S.A.
    Inventors: Hercilio Rivas, Xiomara Gutierrez, Manuel Gonzalez, Geoffrey McGrath, Migdalia Carrasquero, Francisco Lopez-Linares, Roberto Galiasso
  • Patent number: 7276093
    Abstract: A water-in-hydrocarbon emulsion includes a water phase, a hydrocarbon phase and a surfactant, wherein the water phase is present in an amount greater than or equal to about 5% vol. with respect to volume of the emulsion, and the water phase and the surfactant are present at a ratio by volume of the water phase to the surfactant of at least about 1. A method for preparing the emulsion is also provided.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: October 2, 2007
    Assignee: Inievep, S.A.
    Inventors: Hercilio Rivas, Xiomara Gutiérrez, Manuel A. González, Geoffrey McGrath, Migdalia Carrasquero, Francisco López-Linares, Roberto Galiasso
  • Patent number: 7037961
    Abstract: A method for preparing an asphalt composition includes the steps of providing asphalt; mixing sulfur with the asphalt at a temperature greater than 200° C. to provide a sulfur-asphalt blend; providing a heavy aromatic oil; and mixing the heavy aromatic oil with the sulfur-asphalt blend to provide the asphalt composition. Polymers can also advantageously be incorporated into the asphalt composition.
    Type: Grant
    Filed: September 9, 2003
    Date of Patent: May 2, 2006
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Pedro Blanco
  • Publication number: 20050051055
    Abstract: A method for preparing an asphalt composition includes the steps of providing asphalt; mixing sulfur with the asphalt at a temperature greater than 200° C. to provide a sulfur-asphalt blend; providing a heavy aromatic oil; and mixing the heavy aromatic oil with the sulfur-asphalt blend to provide the asphalt composition. Polymers can also advantageously be incorporated into the asphalt composition.
    Type: Application
    Filed: September 9, 2003
    Publication date: March 10, 2005
    Inventors: Hercilio Rivas, Pedro Blanco
  • Publication number: 20040229765
    Abstract: A surfactant package for a water-in-hydrocarbon emulsion includes a fatty acid component; a fatty acid salt component; an alcohol component and a salt of carboxylic acid. Emulsions formed using this surfactant package are stable and have ratios of water to surfactant of at least about 3.
    Type: Application
    Filed: May 16, 2003
    Publication date: November 18, 2004
    Inventors: Xiomara Gutierrez, Hercilio Rivas, Migdalia Carrasquero, Luis Marcano
  • Patent number: 5976200
    Abstract: A combustible fuel for diesel engines and a process for forming same in the form of a water in hydrocarbon emulsion wherein the mean water drop diameter is.ltoreq.4 .mu.m with a maximum diameter of.ltoreq.10 .mu.m.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: November 2, 1999
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Gustavo A. Nunez, Tulio Colmenares, Manuel Chirinos
  • Patent number: 5902227
    Abstract: A multiple emulsion includes a continuous water phase; an oil droplet phase dispersed through the continuous water phase; an inner water droplet phase dispersed through the oil droplet phase; and a water insoluble compound suspended in the inner water droplet phase. The multiple emulsion is useful as a transportable and combustible fuel.
    Type: Grant
    Filed: July 17, 1997
    Date of Patent: May 11, 1999
    Assignee: Intevep, S.A.
    Inventor: Hercilio Rivas
  • Patent number: 5792223
    Abstract: A stable hydrocarbon-in-water emulsion includes a hydrocarbon phase containing natural surfactant; a water phase having an electrolyte content greater than about 10 ppm (wt) and less than or equal to about 100 ppm (wt) with respect to the water phase; and a surfactant additive including an amine and an ethoxylated alcohol in amounts effective to activate the natural surfactant and stabilize the emulsion.
    Type: Grant
    Filed: March 21, 1997
    Date of Patent: August 11, 1998
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Xiomara Gutierrez, Antonio E. Cardenas, Amanda Morles
  • Patent number: 5725609
    Abstract: A combustible fuel for diesel engines and a process for forming same in the form of a water in hydrocarbon emulsion wherein the mean water drop diameter is .ltoreq.4 .mu.m with a maximum diameter of .ltoreq.10 .mu.m.
    Type: Grant
    Filed: February 9, 1996
    Date of Patent: March 10, 1998
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Gustavo A. Nunez, Tulio Colmenares, Manuel Chirinos
  • Patent number: 5622920
    Abstract: A method for forming a stable emulsion of a viscous hydrocarbon in an aqueous buffer solution includes the steps of: providing a viscous hydrocarbon containing an inactive natural surfactant and having a salt content by weight of less than or equal to about 15 ppm and having a water content by weight of less than or equal to about 0.1%; forming a solution of a buffer additive in an aqueous solution to provide a basic aqueous buffer solution, the buffer additive being operative to extract and activate the inactive natural surfactant from the viscous hydrocarbon; and mixing the viscous hydrocarbon with the aqueous buffer solution at a rate sufficient to provide an emulsion of the viscous hydrocarbon in the aqueous buffer solution, whereby the buffer additive extracts the inactive natural surfactant from the viscous hydrocarbon into the aqueous buffer solution and activates the inactive natural surfactant so as to stabilize the emulsion. According to the invention, the buffer additive is a water soluble amine.
    Type: Grant
    Filed: March 13, 1995
    Date of Patent: April 22, 1997
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Socrates Acevedo, Xiomara Gutierrez
  • Patent number: 5603864
    Abstract: A method for forming a stable bimodal emulsion comprises admixing a viscous hydrocarbon with an aqueous buffer solution under controlled conditions so as to obtain a first monomodal emulsion having an average hydrocarbon droplet size of less than 5 microns. The monomodal emulsion is thereafter diluted with water and additional viscous hydrocarbon is admixed with the diluted monomodal emulsion under a second mixing energy sufficient to produce a bimodal emulsion wherein the average small hydrocarbon droplet size is less than or equal to 5 microns and the average large hydrocarbon droplet size is less than or equal to about 30 microns.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: February 18, 1997
    Assignee: Intevep, S.A.
    Inventors: Felix Silva, Hercilio Rivas, Gustavo Nunez, Dolores Pazos
  • Patent number: 5556574
    Abstract: A method for forming a stable emulsion of a viscous hydrocarbon in an aqueous buffer solution includes the steps of: providing a viscous hydrocarbon containing an inactive natural surfactant and having a salt content by weight of less than or equal to about 15 ppm and having a water content by weight of less than or equal to about 0.1%; forming a solution of a buffer additive in an aqueous solution to provide a basic aqueous buffer solution, the buffer additive being operative to extract and activate the inactive natural surfactant from the viscous hydrocarbon; and mixing the viscous hydrocarbon with the aqueous buffer solution at a rate sufficient to provide an emulsion of the viscous hydrocarbon in the aqueous buffer solution, whereby the buffer additive extracts the inactive natural surfactant from the viscous hydrocarbon into the aqueous buffer solution and activates the inactive natural surfactant so as to stabilize the emulsion. According to the invention, the buffer additive is a water soluble amine.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 17, 1996
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Socrates Acevedo, Xiomara Gutierrez
  • Patent number: 5505876
    Abstract: A low viscosity, non-aging hydrocarbon in water emulsion formed from a viscous hydrocarbon comprises from about 70 to 80%/wt. oil, from about 20 to 30%/wt. water, from about 0.1 to 5.0%/wt. of an emulsifying agent, and an average oil droplet size of greater than or equal to 15 microns wherein the emulsion is characterized by a viscosity of less or equal to 1500 centipoise at 80.degree. F. and substantial non-aging over time wherein the change in viscosity of the emulsion is less than 100 centipoise per month.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: April 9, 1996
    Assignee: Intevep
    Inventors: Hercilio Rivas, Maria L. Ventresca, Gerardo Sanchez
  • Patent number: 5503772
    Abstract: A stable, low viscosity bimodal oil in water emulsion having an emulsifier, a continuous water phase and a discontinuous oil phase having an oil:water ratio of from about 70:30 to about 85:15 by weight, the discontinuous oil phase being characterized by two distinct oil droplet sizes D.sub.L and D.sub.S wherein D.sub.L is about 10 to 40 microns and D.sub.S is less than or equal to 5 microns, the ratio of D.sub.L /D.sub.S is greater than or equal to 4 and about 45 to 85% by weight of the oil is in oil droplet size D.sub.L.
    Type: Grant
    Filed: March 1, 1995
    Date of Patent: April 2, 1996
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Gustavo Nunez, Gerardo Sanchez
  • Patent number: 5480583
    Abstract: A method for forming a stable emulsion of a viscous hydrocarbon in an aqueous buffer solution includes the steps of: providing a viscous hydrocarbon containing an inactive natural surfactant and having a salt content by weight of less than or equal to about 15 ppm and having a water content by weight of less than or equal to about 0.1%; forming a solution of a buffer additive in an aqueous solution to provide a basic aqueous buffer solution, the buffer additive being operative to extract and activate the inactive natural surfactant from the viscous hydrocarbon; and mixing the viscous hydrocarbon with the aqueous buffer solution at a rate sufficient to provide an emulsion of the viscous hydrocarbon in the aqueous buffer solution, whereby the buffer additive extracts the inactive natural surfactant from the viscous hydrocarbon into the aqueous buffer solution and activates the inactive natural surfactant so as to stabilize the emulsion. According to the invention, the buffer additive is a water soluble amine.
    Type: Grant
    Filed: January 4, 1993
    Date of Patent: January 2, 1996
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Socrates Acevedo, Xiomara Gutierrez
  • Patent number: 5419852
    Abstract: A stable, low viscosity bimodal oil in water emulsion having an emulsifier, a continuous water phase and a discontinuous oil phase having an oil:water ratio of from about 70:30 to about 85:15 by weight, the discontinuous oil phase being characterized by two distinct oil droplet sizes D.sub.L and D.sub.S wherein D.sub.L is about 10 to 40 microns and D.sub.S is less than or equal to 5 microns, the ratio of D.sub.L /D.sub.S is greater than or equal to 4 and about 45 to 85% by weight of the oil is in oil droplet size D.sub.L.
    Type: Grant
    Filed: December 2, 1991
    Date of Patent: May 30, 1995
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Gustavo Nunez, Gerardo Sanchez
  • Patent number: 5354504
    Abstract: A method for the preparation of a hydrocarbon in water emulsion from viscous hydrocarbons wherein aging of the emulsion over time is substantially eliminated comprises forming a concentrated emulsion characterized by a water content of less than or equal to 15%/wt. and an average oil droplet size of less than or equal to 4 microns and thereafter forming a final emulsion by diluting the concentrated hydrocarbon in water emulsion with water so as to obtain a water content of less than or equal to 30%/wt. and stirring said diluted emulsion so as to obtain a final hydrocarbon in water emulsion having an average oil droplet size of greater than or equal to 15 microns.
    Type: Grant
    Filed: August 19, 1991
    Date of Patent: October 11, 1994
    Assignee: Intevep, S.A.
    Inventors: Hercilio Rivas, Maria L. Ventresca, Gerardo Sanchez