Abstract: A method is provided for synthesizing a core-shell nanoparticle that includes the following steps: providing a polymeric seed (in a solvent) that includes a mono-vinyl monomer cross-linked with a cross-linking agent to form the core of the nanoparticle, the core has an average diameter of from about nanometers to about 10,000 nanometers, and the core has polymer chains with living ends; adding a stabilizer to stabilize the seed and prevent the seed from precipitating out of solution; and grafting a shell species onto the living ends of the core to form the shell of the nanoparticle. A core-first synthesized nanoparticle, along with a rubber composition and tire product are also provided.

Abstract: There is provided an intermediate layer material including a curing type resin composition and a fiber base material, to be used to form an intermediate layer of a composite laminate, wherein a cured material obtained by curing the intermediate layer material at a temperature of 180° C. has such properties as (i) a planar linear expansion coefficient (?1) equal to or lower than 20 ppm/° C., in a range equal to or higher than 25° C. and equal to or lower than a glass transition temperature (Tg); and (ii) a Barcol hardness equal to or more than 40 and equal to or less than 65, at 25° C.

Abstract: Provided is an inner liner for a pneumatic tire including no less than 8 resin-layers, the resin-layer having a layer A constituted with a resin composition containing a resin having gas barrier properties, and a layer B that is adjacent to the layer A and is constituted with a resin composition containing an elastomer, an extensional viscosity ?A of the resin composition of the layer A, and an extensional viscosity ?B of the resin composition of the layer B as determined at a predetermined temperature both being no less than 1,000 Pa·s, and an extensional viscosity ratio ?A/?B being no less than 0.2 and no greater than 10.

Abstract: A pneumatic tire includes: an inner liner having a thermoplastic resin film, a carcass, and an adhesive layer disposed between the inner liner and the carcass, in which the dynamic storage modulus E's at ?20° C. of the thermoplastic resin film, the adhesive layer, and the carcass are defined as E1?, E2?, and E3?, respectively, and the relationship among E1?, E2?, and E3? satisfies E1?>E2?>E3?. This pneumatic tire has excellent anti-crack property in a low-temperature environment of the inner liner.

Abstract: The laminate according to the present invention includes a thermoplastic resin film-containing layer and a rubber layer, in which the rubber layer contains a modified diene polymer, and the rubber layer has a dynamic storage modulus E? at ?20° C. of 1.0×105 to 1.0×108 Pa. This laminate can improve the resistance to the fractures and the cracks of the inner liner.

Abstract: To provide a multilayer structure having high gas barrier property and crack resistance as well as excellent fatigue resistance, an inner liner for a pneumatic tire using such a multilayer structure, and a pneumatic tire comprising the inner liner. According to the present invention, in a multilayer structure 1 including a barrier layer 2 and an elastomer layer 3, a proportion of a thickness of the elastomer layer 3 in the multilayer structure ((U1+U2+ . . . +Un)/T) is 60% or more.

Abstract: To provide a multilayer structure that may adhere to rubber material without the necessity of providing an adhesive layer, an inner liner and a pneumatic tire using the multilayer structure. According to the present invention, a multilayer structure 1 is formed by alternately laminating elastomer layers 3 containing thermoplastic elastomer and barrier layers 2 containing a gas barrier resin, wherein an outermost layer 4 laminated uppermost among layers constituting the multilayer structure 1 contains an elastomer component that may heat-adhere to diene rubber.

Abstract: The present invention provides a copolymer of a conjugated diene compound and a non-conjugated olefin, in which the conjugated diene unit has cis-1,4 bonds and the non-conjugated olefin contains many ethylene structures. In a copolymer of a conjugated diene compound and an unconjugated olefin other than the conjugated diene compound, the conjugated diene unit has a cis-1,4 bond content of 50% or more and the unconjugated olefin is contained in an amount of 20 mol % or more.

Abstract: Disclosed is a method of manufacturing a copolymer of a conjugated diene compound and an olefin other than the conjugated diene compound, where a conjugated diene compound and an olefin other than the conjugated diene compound is copolymerized in the presence of a polymerization catalyst composition containing components: (A) a rare earth element compound or a reactant of the rare earth element compound and a Lewis base; and (B) at least one selected from a group consisting of an ionic compound (B-1) composed of a non-coordinating anion and a cation, an aluminoxane (B-2), and at least one kind of halogen compound (B-3) selected from among a Lewis acid, a complex compound of a metal halide and a Lewis base, and an organic compound containing active halogen (when containing at least one of (B-1) and (B-3), the polymerization catalyst composition further contains component (C): an organometallic compound).

Abstract: In a copolymer of a conjugated diene compound and a non-conjugated olefin, the conjugated diene unit has a cis-1,4 bond content of greater than 70.5% and the non-conjugated olefin is contained in an amount of 10 mol % or more.

Abstract: A multilayered structure having a layer A constituted with a resin composition containing a gas barrier resin, and a layer B being adjacent to the layer A and being constituted with a resin composition containing an elastomer. The total number of the layer A and the layer B is at least 7. The average thickness of the layer A in terms of a single layer is no less than 0.001 ?m and no greater than 10 ?m, and the average thickness of the layer B in terms of a single layer is no less than 0.001 ?m and no greater than 40 ?m. The multilayered structure is formed by irradiating with an active energy ray. Furthermore, an inner liner having the multilayered structure, and a pneumatic tire provided with the inner liner are provided.

Abstract: The present invention provides a photo-curable transfer sheet by which an optical information recording medium (e.g., DVD) having small thickness and high capacity can be advantageously prepared, and which is improved in transferring property of pits and the like and curing property. The photo-curable transfer sheet has a photo-curable transfer layer comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises a polymer having a glass transition temperature of not less than 80° C. and a reactive diluent having a photopolymerizable functional group. The invention also provides a process for the preparation of an optical information recording medium using the sheet, and the optical information recording medium.

Abstract: Disclosed is an inner liner for a pneumatic tire, the inner liner including no less than 8 resin-layers, the resin-layer having a layer A constituted with a resin composition containing a gas barrier resin, and a layer B constituted with a resin composition containing an elastomer, at least one of the resin compositions included in the layer A and the layer B that are adjacent with each other containing a metal salt, the content of the metal salt being no less than 1 ppm and no greater than 10,000 ppm in terms of metal element equivalent, and an interlayer adhesive force between the layer A and the layer B being no less than 500 g/15 mm. The layer A and the layer B are preferably alternately laminated.

Abstract: A method is provided for synthesizing a core-shell nanoparticle that includes the following steps: providing a polymeric seed (in a solvent) that includes a mono-vinyl monomer cross-linked with a cross-linking agent to form the core of the nanoparticle, the core has an average diameter of from about nanometers to about 10,000 nanometers, and the core has polymer chains with living ends; adding a stabilizer to stabilize the seed and prevent the seed from precipitating out of solution; and grafting a shell species onto the living ends of the core to form the shell of the nanoparticle. A core-first synthesized nanoparticle, along with a rubber composition and tire product are also provided.

Abstract: The present invention provides a photo-curable transfer sheet by which an optical information recording medium having small thickness and high capacity can be advantageously prepared, the photo-curable transfer layer of the sheet cured in the production of the optical information recording medium having excellent adhesion to the reflective layer such silver alloy and easy peeling property from the stamper to easily bring about the transfer layer having an uneven surface such as pits, etc accurately formed along an uneven surface of the stamper. The photo-curable transfer sheet has a photo-curable transfer layer comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises a polymer and a reactive diluent having a photopolymerizable functional group, and the reactive diluent has at least one hydroxyl group and an acryloyl group and/or methacryloyl group, the total of acryloyl group and/or methacryloyl group being at least two.

Abstract: A method is provided for making nanoparticles, including the steps of: combining a hydrocarbon solvent and an aprotic, polar co-solvent, a mono-vinyl aromatic monomer, polymerization initiator, a solution stabilizer, and a first charge of a cross-linking agent. Subsequently, a second charge of cross-linking agent is added. The nanoparticles have an average diameter of 5 nanometers to about 10,000 nanometers. Spherical nanoparticles are also provided that include a cross-linking agent comprising 30% to 60% by weight of the combined weight of a mono-vinyl aromatic species and the cross-linking agent. The spherical nanoparticles also meet the following equation: 0.90?(D1/D2)?1.1 wherein D1 is a first diameter of a nanoparticle and D2 is a second diameter of the nanoparticle, and D1 and D2 intersect at right angles.

Abstract: Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.

Abstract: A core-first method is provided for making a core-shell nanoparticle that includes the following steps: adding to a solvent, a mono-vinyl monomer cross-linked with a cross-linking agent to form the core of the nanoparticle, the core having an average diameter of 5 nanometers to about 10,000 nanometers, and the core having polymer chains with living ends; adding a charge agent comprising a fixed formal charge group onto the living ends of the core to form the shell of the nanoparticle; controlling the charge of the nanoparticle based on the type of charge agent, the quantity of the charge agent, or both the type of charge agent and the quantity of the charge agent. A core-shell nanoparticle is also provided.

Abstract: A photo-curable transfer sheet having a photo-curable layer comprising a photo-curable composition, the photo-curable composition being deformable by application of pressure and containing a reactive polymer having a photopolymerizable functional group. The photo-curable transfer sheet preferably has a light transmittance of not less than 70% in a wavelength rang of 380 to 420 nm. An optical information recording substrate and medium prepared by the sheet. The sheet easily and precisely enables transfer of unevenness of the surface of a stamper by pressing.

Abstract: The present invention provides a photo-curable transfer sheet by which an optical information recording medium (e.g., DVD) having small thickness and high capacity can be advantageously prepared, and which is improved in transferring property of pits and the like and curing property. The photo-curable transfer sheet has a photo-curable transfer layer comprising a photo-curable composition deformable by application of pressure, wherein the photo-curable composition comprises a polymer having a glass transition temperature of not less than 80° C. and a reactive diluent having a photopolymerizable functional group. The invention also provides a process for the preparation of an optical information recording medium using the sheet, and the optical information recording medium.